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A method for preparing colloidal electrolyte with gum arabic as stabilizer

A technology of colloidal electrolyte and gum arabic, applied in the direction of lead-acid batteries, etc., can solve the problems of short service life, poor low-temperature performance, large self-discharge, etc., and achieve the effect of long gel time, stable performance, and uniform particle distribution

Active Publication Date: 2019-07-09
HENAN CHAOWEI POWER SUPPLY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Lead-acid batteries have been widely used in various fields, especially in the field of telecommunications, backup power, energy storage power and power applications, etc., but traditional lead-acid batteries also have a series of problems such as early capacity decay and short service life.
[0004] At present, the traditional lead-acid battery uses sulfuric acid as the electrolyte, and the sulfation of the plate will occur during the production process. At the same time, the self-discharge is large, the low-temperature performance is poor, and the service life is short.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A kind of method that the present invention prepares colloidal electrolyte with gum arabic as stabilizer, the detailed steps of this preparation method are as follows:

[0023] a, the preparation of silicon dioxide suspension: take by weighing 0.4g silicon dioxide, 0.05g sodium sulfate and 0.05g stannous sulfate, add the three into 24.5g water and carry out shear dispersion, obtain containing sodium sulfate and stannous sulfate Silica suspension 25.0g;

[0024] B, the preparation of gum arabic sulfuric acid solution: take by weighing the sulfuric acid solution 74.3g of mass percent concentration 48.5%, then add gum arabic 0.7g and carry out shear dispersion, obtain gum arabic sulfuric acid solution 75.0g;

[0025] C, carry out shearing and mixing with the silica suspension 25.0g containing sodium sulfate and stannous sulfate obtained in step a and the gum arabic sulfuric acid solution 75.0g obtained in step b, and obtain silica / sulfuric acid colloidal electrolyte 100.0 ...

Embodiment 2

[0028] A kind of method that the present invention prepares colloidal electrolyte with gum arabic as stabilizer, the detailed steps of this preparation method are as follows:

[0029] a, the preparation of silicon dioxide suspension: take by weighing 0.5g silicon dioxide, 0.06g sodium sulfate and 0.06g stannous sulfate, add the three into 24.38g water and carry out shear dispersion, obtain containing sodium sulfate and stannous sulfate Silica suspension 25.0g;

[0030] B, the preparation of gum arabic sulfuric acid solution: take by weighing the sulfuric acid solution 74.5g of mass percent concentration 51.0%, then add gum arabic 0.5g and carry out shear dispersion, obtain gum arabic sulfuric acid solution 75.0g;

[0031] C, carry out shearing and mixing with the silica suspension 25.0g containing sodium sulfate and stannous sulfate obtained in step a and the gum arabic sulfuric acid solution 75.0g obtained in step b, and obtain silica / sulfuric acid colloidal electrolyte 100.0...

Embodiment 3

[0034] A kind of method that the present invention prepares colloidal electrolyte with gum arabic as stabilizer, the detailed steps of this preparation method are as follows:

[0035] a, the preparation of silicon dioxide suspension: take by weighing 0.6g silicon dioxide, 0.075g sodium sulfate and 0.075g stannous sulfate, add the three into 24.25g water and carry out shear dispersion, obtain containing sodium sulfate and stannous sulfate Silica suspension 25.0g;

[0036] B, the preparation of gum arabic sulfuric acid solution: take by weighing the sulfuric acid solution 74.6g of mass percent concentration 53.5%, then add gum arabic 0.4g and carry out shear dispersion, obtain gum arabic sulfuric acid solution 75.0g;

[0037] C, carry out shearing and mixing with the silica suspension 25.0g containing sodium sulfate and stannous sulfate obtained in step a and the gum arabic sulfuric acid solution 75.0g obtained in step b, and obtain silica / sulfuric acid colloidal electrolyte 100...

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PUM

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Abstract

The invention discloses a method for preparation of gel electrolyte with Arabic gum as the stabilizing agent. The method includes: firstly weighing silicon dioxide, sodium sulfate and stannous sulfate, adding the three substances into water and performing shearing dispersion to obtain a silicon dioxide suspension containing sodium sulfate and stannous sulfate; then weighing a sulfuric acid solution, adding Arabic gum to perform shearing dispersion, thus obtaining an Arabic gum sulfuric acid solution; and finally subjecting the obtained silicon dioxide suspension and the Arabic gum sulfuric acid solution to shearing mixing, thus obtaining the silicon dioxide / sulfuric acid gel electrolyte product. The silicon dioxide / sulfuric acid gel electrolyte prepared by the method provided by the invention has the characteristics of stable performance and long gelation time, and is in favor of electrolyte injection.

Description

technical field [0001] The invention relates to the technical field of battery electrolytes, in particular to a method for preparing colloidal electrolytes using gum arabic as a stabilizer. Background technique [0002] Since the lead-acid battery was invented in 1958, it has a history of more than 100 years. Lead-acid batteries have the advantages of simple structure, reliable performance, convenient use, easy access to raw materials and low price. They are widely used in many fields of national economy such as transportation, communication and national defense, and have become indispensable in social production and human life. energy products. [0003] Lead-acid batteries have been widely used in various fields, especially in the field of telecommunications, backup power, energy storage power and power applications, etc., but traditional lead-acid batteries also have a series of problems such as early capacity decay and short service life. [0004] At present, traditiona...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/10
CPCH01M10/10Y02E60/10
Inventor 张雷李松林闫新华范培华
Owner HENAN CHAOWEI POWER SUPPLY
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