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Polyaniline/Ti<3>C<2>T<x>/sulfur composite material

A composite material, polyaniline technology, applied in electrical components, battery electrodes, circuits, etc., can solve problems such as slow migration speed, reduced sulfur active material utilization, lithium-sulfur battery safety issues, etc., to improve lifespan and reduce shuttle effect. Effect

Inactive Publication Date: 2017-07-04
SHENZHEN PEICHENG TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This phenomenon, known as the shuttle effect, reduces the availability of sulfur active species
At the same time insoluble Li 2 S and Li 2 S 2 Deposited on the surface of the lithium negative electrode, which further deteriorates the performance of the lithium-sulfur battery; (3) the final product of the reaction, Li 2 S is also an electronic insulator and will be deposited on the sulfur electrode, while lithium ions migrate slowly in solid lithium sulfide, slowing down the electrochemical reaction kinetics; (4) sulfur and the final product Li 2 The density of S is different. When sulfur is lithiated, the volume expands by about 79%, which easily leads to Li 2 Pulverization of S, causing safety problems in lithium-sulfur batteries
The above deficiencies restrict the development of lithium-sulfur batteries, which is also a key issue that needs to be solved in current research on lithium-sulfur batteries.

Method used

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  • Polyaniline/Ti&lt;3&gt;C&lt;2&gt;T&lt;x&gt;/sulfur composite material
  • Polyaniline/Ti&lt;3&gt;C&lt;2&gt;T&lt;x&gt;/sulfur composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] (1) Put Ti 3 AlC 2 The ceramic powder was corroded in hydrofluoric acid with a mass concentration of 20% for 24 hours. After corrosion, the solution was added to deionized water for centrifugation, and then the precipitate was dried to obtain stacked layered Ti. 3 C 2 T x Powder;

[0018] (2) Add 0.5g Ti 3 C 2 T x Mix the powder with 10g of elemental sulfur evenly, place it in a sealed reaction kettle, heat the reaction to 155°C in a nitrogen atmosphere, keep the temperature for 12h, cool to room temperature after the reaction is completed, and obtain Ti 3 C 2 T x / sulfur composites;

[0019] (3) Ti will be obtained 3 C 2 T x Add the / sulfur composite material into water and stir, then add 0.5g aniline and stir, then add 0.05g initiator azobisisobutyronitrile, stir, stand still, filter, and dry in vacuum to obtain polyaniline / Ti 3 C 2 T x / sulfur composites.

Embodiment 2

[0021] (1) Put Ti 3 AlC 2 The ceramic powder was corroded in hydrofluoric acid with a mass concentration of 50% for 4 hours. After corrosion, the solution was added to deionized water for centrifugation, and then the precipitate was dried to obtain stacked layered Ti. 3 C 2 T x Powder;

[0022] (2) Put 2g Ti 3 C 2 T x The powder was uniformly mixed with 10g of elemental sulfur, placed in a sealed reaction kettle, heated to 165°C in a nitrogen atmosphere, and kept at a constant temperature for 5h. After the reaction was completed, it was cooled to room temperature to obtain Ti 3 C 2 T x / sulfur composites;

[0023] (3) Ti will be obtained 3 C 2 T x Add the / sulfur composite material into water and stir, then add 2g of aniline and stir, then add 0.02g of initiator dibenzoyl peroxide, stir, stand still, filter, and dry in vacuum to obtain polyaniline / Ti 3 C 2 T x / sulfur composites.

Embodiment 3

[0025] (1) Put Ti 3 AlC 2 The ceramic powder was corroded in hydrofluoric acid with a mass concentration of 30% for 20 hours. After corrosion, the solution was added to deionized water for centrifugation, and then the precipitate was dried to obtain stacked layered Ti. 3 C 2 T x Powder;

[0026] (2) Add 1g Ti 3 C 2 T x The powder was uniformly mixed with 10g of elemental sulfur, placed in a sealed reaction kettle, heated to 160°C in a nitrogen atmosphere, and kept at a constant temperature for 10h. After the reaction was completed, it was cooled to room temperature to obtain Ti 3 C 2 T x / sulfur composites;

[0027] (3) Ti will be obtained3 C 2 T x Add the / sulfur composite material into water and stir, then add 1g of aniline and stir, then add 0.05g of initiator ammonium persulfate, stir, stand still, filter, and dry in vacuum to obtain polyaniline / Ti 3 C 2 T x / sulfur composites.

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Abstract

The invention provides a polyaniline / Ti<3>C<2>T<x> / sulfur composite material. The composite material comprises sulfur, sheet-shaped Ti<3>C<2>T<x> and polyaniline; the inner layer is a sulfur and Ti<3>C<2>T<x> composite material; the outer layer is polyaniline for coating the sulfur and Ti<3>C<2>T<x> composite material; and the mass ratio of polyaniline to Ti<3>C<2>T<x> to sulfur is (0.05-0.2) to (0.05-0.2) to 1. In the composite material, the coating layer polyaniline can perform physical protection on the sulfur-based material and can limit polysulfide generated in a charging-discharging process in the polyaniline, so as to lower a shuttle effect; and according to the composite material, the movement of polysulfide is limited from two aspects of physical regional limitation and chemical adsorption, so that the service life of a lithium-sulfur battery is effectively prolonged.

Description

technical field [0001] The invention relates to the synthesis of nanometer materials, in particular to a preparation method of a cathode material of a lithium-sulfur battery. Background technique [0002] A lithium-sulfur battery is a battery system in which metallic lithium is used as the negative electrode and elemental sulfur is used as the positive electrode. Lithium-sulfur batteries have two discharge platforms (about 2.4 V and 2.1 V), but their electrochemical reaction mechanism is relatively complicated. Lithium-sulfur batteries have the advantages of high specific energy (2600 Wh / kg), high specific capacity (1675 mAh / g), and low cost, and are considered to be a promising new generation of batteries. However, at present, there are problems such as low utilization of active materials, low cycle life and poor safety, which seriously restrict the development of lithium-sulfur batteries. The main reasons for the above problems are as follows: (1) elemental sulfur is a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/60H01M4/58H01M4/62
CPCH01M4/362H01M4/366H01M4/58H01M4/5815H01M4/602H01M4/62H01M4/624Y02E60/10
Inventor 钟玲珑
Owner SHENZHEN PEICHENG TECH CO LTD