Metal growth method based on single atomic layer deposition

A single atomic layer and growth method technology, which is applied in the direction of metal material coating process, coating, gaseous chemical plating, etc., can solve problems such as device instability, resistivity increase, work function drift, etc., to improve device reliability properties, the effect of reducing resistivity

Inactive Publication Date: 2017-07-28
INST OF MICROELECTRONICS CHINESE ACAD OF SCI
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Problems solved by technology

However, since ALD is not a high-vacuum reaction process, the control of water and oxygen is technically more difficult
When excess oxygen exists in the ALD

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  • Metal growth method based on single atomic layer deposition
  • Metal growth method based on single atomic layer deposition
  • Metal growth method based on single atomic layer deposition

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[0033] In order to make the purposes, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments It is only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.

[0034] In the prior art, single-layer deposition (ALD) forms a single-layer deposition thin film by alternately passing gas-phase precursors into a reaction chamber and depositing them on a substrate for chemical adsorption. The surface reaction of ALD has chemisorption self-limiting (CS) and sequential reaction sel...

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Abstract

The invention provides a metal growth method based on single atomic layer deposition. The method comprises the steps as follows: single atomic layer deposition equipment is provided; dehumidification and oxygen removal treatment is performed on a single atomic layer deposition reaction chamber in the single atomic layer deposition equipment; first precursor reactants are introduced into the reaction chamber and react on the surface of a substrate; the redundant first precursor reactants and reaction by-products are discharged from the reaction chamber; second precursor reactants are introduced into the reaction chamber and react with the first precursor reactants on the substrate; and the redundant second precursor reactants and reaction by-products are discharged from the reaction chamber. With the metal growth method based on single atomic layer deposition, the water oxygen content in the single atomic layer deposition (ALD) equipment can be reduced, and the method is applicable to control on the oxygen content of metal gate materials in integrated circuits and can also be applied in any film forming fields.

Description

technical field [0001] The invention relates to the technical field of microelectronic device manufacturing, in particular to a metal growth method based on monoatomic layer deposition. Background technique [0002] At present, the size of transistors is shrinking rapidly, and the performance is continuously improving. Integrating more devices on a chip with the same area can make the integrated circuit more powerful and reduce the unit function cost. However, when the size of traditional polysilicon gate transistors is reduced to a certain extent, excessive gate resistance and polysilicon depletion effects will hinder the improvement of transistor performance. After a lot of research, the refractory metal gate is considered to be the most promising alternative technology. Using titanium, tantalum and other alloys as the gate electrode can obtain a very low gate sheet resistance and fundamentally eliminate the depletion effect of the polysilicon gate. Obtain a lower equival...

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Application Information

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IPC IPC(8): C23C16/455C23C16/06
CPCC23C16/45525C23C16/06C23C16/4408
Inventor 项金娟王晓磊杨红王文武赵超
Owner INST OF MICROELECTRONICS CHINESE ACAD OF SCI
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