Composite elemental phosphorus with favorable crystallinity and preparation method and application thereof
A technology of elemental phosphorus and crystallinity, applied in the field of elemental phosphorus, can solve problems such as poor cycle performance and large first-time irreversible specific capacity, and achieve the effects of low cost, controllable synthesis conditions, and easy-to-obtain raw materials
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation example Construction
[0023] The present invention also provides a method for preparing the above-mentioned composite elemental phosphorus with good crystallinity, the preparation method comprising:
[0024] 1) carrying out solvothermal reaction with amorphous red phosphorus and nitrogen-containing compound under airtight conditions;
[0025] 2) The system solution is post-treated to produce complex elemental phosphorus.
[0026] In step 1) of the above-mentioned preparation method, the consumption of material can be selected in a wide range, but in order to make the composite elemental phosphorus obtained have more excellent crystallinity, specific capacity, structural stability and cycle performance; preferably , in step 1), the dosage ratio of amorphous red phosphorus to nitrogen-containing compound is (0.3-2.5g): (30-50mL). More preferably, in step 1), the dosage ratio of amorphous red phosphorus to nitrogen-containing compound is (0.4-0.6g): (30-50mL).
[0027] In step 1) of the above prepar...
Embodiment 1
[0034] Weigh 0.5g of amorphous red phosphorus and put it into the reaction kettle, add 40mL of ethylenediamine to it to make a suspension and seal it; then, react at 200°C for 48 hours; finally, the system solution is centrifuged, washed, The precipitate was dried at 70°C for 15 hours to obtain complex elemental phosphorus A1 (brown-black lumpy particles).
Embodiment 2
[0036] Composite elemental phosphorus A2 (brown black massive particles) was obtained according to the method of Example 1, except that the amount of amorphous red phosphorus was 1.0 g.
PUM
Property | Measurement | Unit |
---|---|---|
particle size | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com