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Polycarbonate-based wear-resistant superhydrophobic coating preparation method

A super-hydrophobic coating, polycarbonate technology, applied in the direction of polycarbonate coatings, coatings, pigmented coatings, etc., can solve the problems of poor wear resistance of super-hydrophobic surfaces, can not be applied under high pressure, etc., to achieve excellent durability Abrasiveness, low cost, and strong wear resistance

Active Publication Date: 2017-09-22
NORTH CHINA ELECTRIC POWER UNIV (BAODING)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The present invention aims to overcome the problem of poor abrasion resistance of superhydrophobic surfaces in the prior art and cannot be applied under high pressure, and provides a method for preparing superabrasive self-cleaning superhydrophobic surfaces

Method used

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  • Polycarbonate-based wear-resistant superhydrophobic coating preparation method

Examples

Experimental program
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Effect test

Embodiment 1

[0026] A method for preparing a wear-resistant superhydrophobic coating based on polycarbonate, carried out according to the following steps:

[0027] (1) 20wt% polycarbonate and 0.2wt% defoamer (BYK 320) were dissolved in tetrahydrofuran to prepare a solution for the middle layer.

[0028] (2) Put 1wt% fatty acid and 1wt% trimethylchlorosilane into acetone, stir magnetically for 12 hours, and set the reaction temperature at 50° to fully dissolve it; then add 4wt% silicon dioxide nanoparticles into the acetone solution Fully mix to make a solution for the surface layer for subsequent use;

[0029] (3) Coating commercially available polycarbonate glue on the substrate, and waiting for 3 minutes to obtain an adhesive layer.

[0030] (4) Coat the solution for the middle layer on the adhesive layer and wait for 2 hours to allow the solvent to fully evaporate to obtain the middle layer bonded by polycarbonate glue.

[0031] (5) Coat the solution for the surface layer on the middl...

Embodiment 2

[0034] A method for preparing a wear-resistant superhydrophobic coating based on polycarbonate, carried out according to the following steps:

[0035] (1) Dissolving 30wt% polycarbonate and 0.3wt% defoamer (BYK 320) in toluene to prepare a solution for the middle layer;

[0036] (2) Put 2wt% hexadecyltrimethoxysilane into acetone, stir magnetically for 12 hours, set the reaction temperature to make it fully dissolve; then add 5wt% titanium dioxide nanoparticles into the acetone solution and mix well to make a surface Layer with solution for standby;

[0037] (3) Coating commercially available polycarbonate glue on the substrate, and waiting for 3 minutes to obtain an adhesive layer.

[0038] (4) Apply the solution for the intermediate layer on the adhesive layer, and wait for 1 hour to allow the solvent to fully evaporate to obtain an intermediate layer bonded by polycarbonate glue.

[0039] (5) Apply the solution for the surface layer on the middle layer, wait for 3 hours, ...

Embodiment 3

[0041] A method for preparing a wear-resistant superhydrophobic coating based on polycarbonate, carried out according to the following steps:

[0042] (1) Dissolving 25wt% polycarbonate and 0.15wt% defoamer (BYK 320) in benzene to prepare a solution for the middle layer;

[0043] (2) Put 3wt% hexamethyldisilane into acetone, stir magnetically for 12 hours, set the reaction temperature to make it fully dissolved; then add 6wt% zinc oxide nanoparticles into the acetone solution and mix well to make the surface layer The solution is ready for use;

[0044] (3) Coating commercially available polycarbonate glue on the substrate, and waiting for 3 minutes to obtain an adhesive layer.

[0045] (4) Coat the solution for the middle layer on the adhesive layer and wait for 2 hours to allow the solvent to fully evaporate to obtain the middle layer bonded by polycarbonate glue.

[0046](5) Coat the surface layer solution on the middle layer, wait for 3 hours, and after the acetone in th...

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Abstract

The invention discloses a polycarbonate-based wear-resistant superhydrophobic coating preparation method. The method comprises dissolving polycarbonate and an antifoaming agent in a solvent to obtain a solution for an intermediate layer, and then dissolving hydrophobic oxide nanoparticles and a low surface energy material in an acetone solution to obtain a solution for a surface layer. In the construction process, a base is coated with commercially available polycarbonate glue, then the glue is coated with the solution for the intermediate layer, and after the solution for the intermediate layer is dried, the intermediate layer is coated with the solution for a surface layer so that the wear-resistant superhydrophobic coating is obtained after drying. Through interaction between the polycarbonate and the acetone solution, the method cleverly realizes the organic combination of the embedded nanostructure and the hierarchical structure, and the thus the prepared superhydrophobic coating has excellent wear resistance.

Description

technical field [0001] The invention belongs to the field of material preparation, in particular to a method for preparing a polycarbonate-based super wear-resistant self-cleaning surface. Background technique [0002] The scientific community refers to a surface with a contact angle with water greater than 150° and a sliding angle less than 10° as a superhydrophobic surface. Due to the characteristics of waterproof, self-cleaning, anti-corrosion, and anti-icing, superhydrophobic surfaces are receiving more and more attention and attention in theoretical research and industrial applications. [0003] The preparation of superhydrophobic surfaces often needs to meet the two conditions of suitable roughness and low surface free energy at the same time. Based on this theory, scientists at home and abroad have prepared super-hydrophobic surfaces through various methods and technologies such as imprinting, laser ablation, and sol-gel methods. One problem that currently limits th...

Claims

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Application Information

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IPC IPC(8): C09D169/00C09D1/00C09D5/16C09D7/12C08J7/04D21H19/82D21H19/38D21H19/40C08L33/12
CPCC08J7/042C08J2333/12C08J2469/00C09D1/00C09D5/1618C09D5/1681C09D169/00D21H19/385D21H19/40D21H19/82
Inventor 王鹏范孝良孙博
Owner NORTH CHINA ELECTRIC POWER UNIV (BAODING)
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