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Disposable graphene-butadiene-acrylonitrile rubber gloves and preparation method thereof

A graphene and nitrile rubber technology, applied in the field of latex gloves, can solve the problems of easy breeding of a large number of bacteria, inability to essentially eliminate the use of bacteria, and inability to meet performance requirements, etc., to improve the life of gloves and the antibacterial effect. Effect of method optimization, breaking strength and elongation at break improvement

Inactive Publication Date: 2017-09-29
NANTONG QIANGSHENG SAFETY PROTECTION TECHNOLOGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the breaking strength and elongation at break of disposable nitrile gloves are respectively roughly 20MPa and 500%, which still cannot meet the performance requirements during normal use, and further improve the mechanical properties of disposable nitrile gloves, especially in terms of breaking strength and In terms of elongation at break, a disposable high-quality glove with high mechanical properties has been developed to meet the high-efficiency use in various fields
[0005] In addition, disposable nitrile gloves are mostly used in food, hygiene, medical treatment, etc., and are prone to breed a large number of bacteria when exposed to the air for a long time, and cannot essentially eliminate the use of bacteria under special application conditions. A long-lasting antimicrobial disposable high-quality glove

Method used

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  • Disposable graphene-butadiene-acrylonitrile rubber gloves and preparation method thereof
  • Disposable graphene-butadiene-acrylonitrile rubber gloves and preparation method thereof
  • Disposable graphene-butadiene-acrylonitrile rubber gloves and preparation method thereof

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Effect test

Embodiment 1-3

[0043] Embodiment 1-3 provides a kind of graphene-acrylonitrile-butadiene rubber compound shown in table 1 respectively as the technical scheme that raw material carries out disposable graphene-acrylonitrile-butadiene rubber glove preparation, and concrete steps are as follows (please refer to figure 1 ):

[0044] Step 1, prepare raw materials according to the parts by weight described in Table 1; raw materials are added under the condition of its aqueous solution;

[0045] Step 2, adding the alkali into the nitrile latex, carrying out alkalization treatment to the nitrile latex; in this step, the pH of the nitrile latex after the alkali (potassium hydroxide) treatment is more than 9;

[0046] Step 3, adding auxiliary components to the nitrile latex after the alkalization treatment, and grinding; in this step, the number of times of grinding is 2 times;

[0047] Step 4, adding graphene, surfactant, defoamer to carry out pre-crosslinking in the nitrile latex after described gr...

Embodiment 4

[0055] The preparation of embodiment 4 disposable graphene / nitrile composite gloves

[0056] Embodiment 4 provides a kind of graphene-nitrile rubber compound shown in table 2 as raw material to carry out the technical scheme of disposable graphene-nitrile rubber gloves preparation, concrete steps are as follows:

[0057] Step 1, prepare materials according to the parts by weight described in Table 2; raw materials are added in aqueous solution state;

[0058] Step 2, use 1.5 parts of ammonia water to configure a certain proportion of alkali aqueous solution to adjust the pH of the latex;

[0059] Step 3, add auxiliary components, stir evenly, add 2.6 parts of grinding material and grind in a grinder for 3 times;

[0060] Step 4, add 0.01 part of graphene and carboxyl nitrile latex, antifoaming agent to carry out pre-crosslinking reaction, in this step, the condition of pre-crosslinking is 60 degrees Celsius, 12 hours; Simultaneously, add 0.001 part of surfactant;

[0061] St...

Embodiment 5

[0066] The preparation of embodiment 5 disposable graphene-nitrile rubber gloves

[0067] Embodiment 5 provides a kind of graphene-nitrile rubber compound shown in table 2 as raw material to carry out the technical scheme of disposable graphene-nitrile rubber gloves preparation, concrete steps are as follows:

[0068] Step 1, prepare materials according to the parts by weight described in Table 2; raw materials are added in aqueous solution state;

[0069] Step 2, configure the alkali solution of a certain proportion with 1.5 parts of ammoniacal liquor and potassium hydroxide mixed alkali to regulate the pH of latex;

[0070] Step 3, add auxiliary components, add 2.6 parts of grinding material and grind 3 times in the grinder;

[0071] Step 4, add another portion of graphene, surfactant, and defoamer to pre-crosslink for 12 hours at 60 degrees Celsius.

[0072] Step 5: After acid washing, water washing and alkali washing of the hand model in sequence, the hand model is dri...

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Abstract

The invention discloses a disposable graphene-nitrile rubber glove with antibacterial and antistatic functions in the technical field of latex gloves and a preparation method thereof; it includes the following raw materials in parts by weight: 100 parts of nitrile latex, 1.0 to 1.0 parts of alkali 1.5 parts, graphene 0.05-0.5 parts, surfactant 0.001-0.005 parts, defoamer 0.10-0.30 parts, auxiliary components 4.1-6 parts, water 200-250 parts. Compared with the prior art, the invention improves the breaking strength and elongation at break of the gloves obtained by optimizing the raw materials and preparation methods of the disposable gloves, and the service life and antibacterial effect of the gloves are also improved.

Description

technical field [0001] The invention relates to the technical field of latex gloves, in particular to a disposable graphene-nitrile rubber glove with antibacterial and antistatic functions and a preparation method thereof. Background technique [0002] Carboxylated nitrile rubber is formed by terpolymerization of butadiene, acrylonitrile and organic acid (acrylic acid, methacrylic acid, etc.). Abbreviated as XNBR, the relative density is 0.98-0.99. The introduction of carboxyl groups increases the polarity and imparts high strength, which has good adhesion and aging resistance, improves wear resistance and tear strength, and further improves oil resistance. The tensile strength is 25.5-26.5MPa, the elongation at break is 310%-380%, and the tear strength is 51.0-55.9kN / m. Nitrile gloves are made of nitrile material, titanium dioxide, auxiliary materials, and defoamers as the main raw materials through mixing, filtering, coagulation, drying and other processes. They have out...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L9/02C08L39/06C08L29/04C08L83/04C08K3/04C08K5/01C08K3/22A41D19/015B29D99/00
CPCC08L9/02A41D19/0062B29D99/0067C08L2201/04
Inventor 沙嫣沙晓林拜永孝兰会林
Owner NANTONG QIANGSHENG SAFETY PROTECTION TECHNOLOGY CO LTD
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