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A kind of conductive thermal conductive polymer fiber and preparation method thereof

A technology of electric conduction, heat conduction and polymer, which is applied in the manufacture of conductive/antistatic filaments, conjugated synthetic polymer artificial filaments, fiber treatment, etc., can solve the problem that the metal silver layer cannot be bonded with fibers, etc., to increase the metal silver content , increase the roughness, increase the effect of the anchor point

Active Publication Date: 2019-08-06
SHANDONG SHENGQUAN NEW MATERIALS CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

In the patent, strong alkali is used to corrode the fiber surface, which can improve the roughness of the fiber surface to a certain extent, but for fibers with strong alkali resistance such as nylon and polypropylene, the use of strong alkali corrosion cannot form an effective sufficient corrosion resistance on the fiber surface. A large amount of concave-convex anchor points, so that the metallic silver layer cannot be firmly combined with the fiber

Method used

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  • A kind of conductive thermal conductive polymer fiber and preparation method thereof
  • A kind of conductive thermal conductive polymer fiber and preparation method thereof
  • A kind of conductive thermal conductive polymer fiber and preparation method thereof

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preparation example Construction

[0063] Another aspect of the present invention relates to a method for preparing an electrically and thermally conductive polymer fiber, see for details figure 1 The flow chart includes the following steps:

[0064] (a) Graphene masterbatch, calcium carbonate masterbatch and polymer resin are blended as A component, and polymer resin is used as B component, and described A component is used as skin layer, and described B component is used as core layer, both Composite spinning is carried out to obtain bi-component composite fibers after texturing;

[0065] (b) remove the oil agent and impurities on the surface of the two-component composite fiber;

[0066] (c) Hole making and sensitization treatment on the fiber surface;

[0067] (d) plating a conductive metal layer to obtain the conductive and thermally conductive polymer fibers.

[0068] The preparation method of the conductive and heat-conducting polymer fiber provided by the present invention only adds graphene and calc...

Embodiment 1

[0096] Preparation of 75D / 48F Conductive and Thermally Conductive Polyester Fiber

[0097] (1) Preparation of sheath-core bicomponent polyester fiber

[0098] Graphene masterbatch, calcium carbonate masterbatch, and polyester chips are blended in a certain proportion as component A; polyester chips are used as component B. After the components A and B are dried in a vacuum drum drying oven, the two-component composite spinning technology is adopted, in which component A uses a cortical screw and component B uses a core screw. The temperature of the component A screw in the four zones is 270°C, 284°C, 282°C, and 282°C, and the temperature of the component B screw in the four zones is 270°C, 287°C, 285°C, and 285°C.

[0099] The two-component raw materials are melted by a screw, extruded, cooled and solidified, oiled, and wound to obtain a sheath-core type two-component polyester pre-oriented yarn. The volume ratio of the skin layer and the core layer is 1:1.2. Among them, the...

Embodiment 2

[0110] Preparation of 70D / 48F Conductive and Thermally Conductive Polyamide Fiber

[0111] (1) Preparation of sheath-core bicomponent polyamide fiber

[0112] Graphene masterbatch, calcium carbonate masterbatch and polyamide chips are blended in a certain proportion as component A; polyamide chips are used as component B. After the components A and B are dried in a vacuum drum drying oven, the two-component composite spinning technology is adopted, in which component A uses a cortical screw and component B uses a core screw. The temperature of the component A screw in the four zones is 250°C, 264°C, 262°C, and 262°C, and the temperature of the component B screw in the four zones is 250°C, 267°C, 265°C, and 265°C.

[0113] The two-component raw materials are melted by a screw, extruded, cooled and solidified, oiled, and wound to obtain a sheath-core type two-component polyester pre-oriented yarn. The volume ratio of the skin layer and the core layer is 1:1.5. Among them, the ...

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Abstract

The invention relates to the field of fiber materials, in particular to an electric and thermal conductive polymer fiber and a preparation method thereof. The electric and thermal conductive polymer fiber comprises a surface layer and a core layer, wherein the core layer is mainly prepared from a molten polymer resin; the surface layer is mainly prepared from a molten mixture of nano-grade graphene, calcium carbonate and a polymer resin; the outer surface of the surface layer is covered by a conductive metal layer. According to the electric and thermal conductive polymer fiber provided by the invention, graphene and calcium carbonate powder are added into the fiber surface layer, so that the graphene and the calcium carbonate powder protrude from the surface of the fiber, the surface roughness of the fiber is improved, and the anchoring points on the surface of the fiber are increased; as the surface of the surface layer is covered by the conductive metal layer, a metal silver is firmly combined with the surface of the fiber, the content of the metal silver on the surface of the fiber is increased, and furthermore the surface resistivity of the fiber is greatly reduced.

Description

technical field [0001] The invention relates to the field of fiber materials, in particular to a conductive and thermally conductive polymer fiber and a preparation method thereof. Background technique [0002] The effective integration of science and technology and the textile industry has made smart textiles mentioned many times by the textile industry recently. Smart textiles are a new trend in the development of textiles and a research hotspot in the 21st century. According to the evaluation of international research institutions, smart textiles, as a high-tech textile, will have a total industry value of 4.7 billion US dollars by 2020. Given that the total value of smart textiles in 2014 was less than $1 billion, the cumulative annual growth rate will reach 30%. The broad prospects of smart textiles have made companies rush to develop products in this area. [0003] Smart textiles are highly intelligent textiles developed comprehensively by applying textiles, electro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M11/83D06M11/20D01F8/14D01F8/12D01F8/06D01F1/09D01F1/10D01D5/34D06M101/32D06M101/34D06M101/20
CPCD01D5/34D01F1/09D01F1/10D01F8/06D01F8/12D01F8/14D06M11/20D06M11/83D06M2101/20D06M2101/32D06M2101/34
Inventor 唐地源胡兴文吕冬生王双成杨义颖许日鹏宋现芬
Owner SHANDONG SHENGQUAN NEW MATERIALS CO LTD
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