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Polyamide material used for selective laser sintering and preparation method of same

A laser sintering and polyamide technology, applied in the field of additive manufacturing, can solve the problems of high thermal stability of powder, poor toughness of nylon workpiece, and high working temperature, and achieve the effect of improving fluidity, easy implementation and reducing voids

Inactive Publication Date: 2017-10-24
HUNAN FARSOON HIGH TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When using selective laser sintering to prepare workpieces, there is often porosity in the sintered parts because the laser does not completely melt the powder particles, resulting in poor toughness of nylon workpieces, which greatly limits the application of nylon workpieces manufactured by selective laser sintering
In addition, due to the high melting point and high powder thermal stability of the existing nylon materials, the required working temperature is high, resulting in high requirements for equipment

Method used

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  • Polyamide material used for selective laser sintering and preparation method of same
  • Polyamide material used for selective laser sintering and preparation method of same

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preparation example Construction

[0030] The present invention also provides a method for preparing a polyamide material for selective laser sintering, comprising the following steps:

[0031] Step 1. Copolymerize the short carbon chain nylon salt, the first long carbon chain nylon salt, and the second long carbon chain nylon salt of different types to obtain polyamide pellets;

[0032]In this step one, the weight ratio of the short carbon chain nylon salt, the first long carbon chain nylon salt and the second long carbon chain nylon salt can be preferably 1:1:0.2-0.8, which can better ensure that the polyamide The low melting point of the powder, and the high toughness of the sintered parts through the polyamide powder. Further preferably, in order to ensure the beneficial effects of low melting point and high toughness, the short carbon chain nylon salt, the first long carbon chain nylon salt and the second long carbon chain nylon salt are prepared into polyamide pellets by ternary copolymerization.

[0033...

Embodiment 1

[0041] Calculated by weight ratio, prepare materials in the following weight ratios:

[0042] Caprolactam: Nylon 11 salt: Nylon 1010 salt=0.2:1:1

[0043] Put the prepared caprolactam, nylon 11 salt, and nylon 1010 salt into the polymerization kettle, mix well, and then add the following additives for copolymerization:

[0044] Adipic acid, added in an amount of 0.2% of the total weight (the total weight here is the total weight of caprolactam, nylon 11 salt and nylon 1010 salt).

[0045] Hindered phenolic antioxidant, added in an amount of 0.2% of the total weight (the total weight here is the total weight of caprolactam, nylon 11 salt and nylon 1010 salt).

[0046] After evacuating the polymerization kettle containing the reactant, fill it with nitrogen dioxide gas to 0.3-0.4Mpa, then discharge the gas and heat it. When the temperature in the kettle rose to 220°C, the pressure in the kettle reached 1.5Mpa, and the pressure holding time was 1.5 hours. After the temperature...

Embodiment 2

[0050] Calculated by weight ratio, prepare materials in the following weight ratios:

[0051] Caprolactam: Nylon 11 salt: Nylon 1212 salt=0.4:1:1

[0052] Put caprolactam, nylon 11 salt, and nylon 1212 salt into the polymerization kettle, mix well, and then add the following additives for copolymerization:

[0053] Adipic acid, added in an amount of 0.4% of the total weight (the total weight here is the total weight of caprolactam, nylon 11 salt and nylon 1212 salt).

[0054] Hindered phenolic antioxidant, added in an amount of 0.4% of the total weight (the total weight here is the total weight of caprolactam, nylon 11 salt and nylon 1212 salt).

[0055] After evacuating the polymerization kettle containing the reactant, fill it with nitrogen dioxide gas to 0.3-0.4Mpa, then discharge the gas and heat it. When the temperature in the kettle rose to 225°C, the pressure in the kettle reached 1.6Mpa, and the pressure holding time was 2 hours. After the temperature in the kettle ...

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Abstract

A polyamide material used for selective laser sintering and a preparation method of same. The polyamide material includes short-carbon chain nylon salt, and first and second long-carbon chain nylon salts in different types, wherein the short-carbon chain nylon salt, the first and the second long-carbon chain nylon salts are subjected to copolymerization to produce the polyamide material used for selective laser sintering. In the method, the polyamide material is prepared through copolymerization to the short-carbon chain nylon salt, the first and the second long-carbon chain nylon salts, namely, the copolymerized nylon is prepared through the copolymerization of the three nylon salts, so that a high-molecular chain of the polyamide material has low symmetry and regularity and furthermore, the copolymerized nylon is poor in crystallizability and thermostability and is lower in required energy during fusion, so that the polyamide material can be used for the selective laser sintering even work temperature is low, and lower demand on sintering equipment is achieved. In addition, the polyamide material is low in cost and can be widely applied to industrial production.

Description

technical field [0001] The invention belongs to the technical field of additive manufacturing, and in particular relates to a polyamide material for selective laser sintering and a preparation method thereof. Background technique [0002] 3D printing technology is a general term for additive manufacturing technology. It is an advanced manufacturing technology with distinctive features such as digital manufacturing, high flexibility and adaptability, direct CAD model drive, fast speed, and rich and diverse material types. Establish a digital description model based on the combination information of structure, structure and selected materials, and then output this information to the computer-controlled electromechanical integrated manufacturing system for point-by-point, line-by-line, and surface-by-surface three-dimensional stacking to produce three-dimensional entities. Compared with the traditional subtractive manufacturing processing technology, the additive manufacturing ...

Claims

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Application Information

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IPC IPC(8): C08G69/36B33Y70/00
CPCC08G69/36B33Y70/00
Inventor 黄敏文杰斌李中元陈礼
Owner HUNAN FARSOON HIGH TECH CO LTD
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