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Composite hydrate inhibitor composition containing lecithin and its application

A technology of lecithin and hydrate, which is applied in the field of compound hydrate polymerization inhibitor compositions, can solve the problems of large dosage, easy environmental pollution, poor polymerization inhibition performance, etc., and achieves low dosage, good flexibility, and avoidance of pollution. Effect

Active Publication Date: 2019-03-01
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] One of the technical problems to be solved by the present invention is the problems of easy pollution of the environment, poor polymerization inhibitory performance and large dosage in the prior art. A new compound hydrate polymerization inhibitor composition containing lecithin is provided. It has the advantages of environmental protection, excellent polymerization inhibition performance and small dosage

Method used

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  • Composite hydrate inhibitor composition containing lecithin and its application
  • Composite hydrate inhibitor composition containing lecithin and its application
  • Composite hydrate inhibitor composition containing lecithin and its application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] This example provides a kind of complex hydrate polymerization inhibitor containing lecithin, which is obtained by compounding (Span20+Tween60), lecithin and ethanol at a mass ratio of 1:1:1.

[0044] Apply the above compound hydrate inhibitor to the oil-water system with a water content of 10% (calculated based on the sum of the volume of water and oil), and the effect of using the compound hydrate inhibitor in this embodiment For evaluation, this embodiment uses the high-pressure sapphire reactor described in Comparative Example 1 for evaluation, and the specific experimental process is as described in Comparative Example 1.

[0045] In this embodiment, the oil-water system in the reactor is composed of 1.5ml deionized water and 13.5ml of -20# diesel oil, that is, the oil-water system with a water content of 10% (based on the sum of the volumes of water and oil), The addition amount of the polymerization inhibitor of this embodiment is 1.0% of the water amount in the ...

Embodiment 2

[0048] This example provides a compounded hydrate inhibitor containing lecithin, which is obtained by compounding (Span20+Tween60), lecithin and ethanol at a mass ratio of 0.5:1:1.

[0049] In this embodiment, the high-pressure sapphire reactor described in Comparative Example 1 is used for evaluation, and the specific experimental process is as described in Comparative Example 1.

[0050] In this embodiment, the oil-water system in the reactor is composed of 1.5ml deionized water and 13.5ml of -20# diesel oil, that is, the oil-water system with a water content of 10% (based on the sum of the volumes of water and oil), The addition amount of the polymerization inhibitor in this embodiment is 1.0% of the water quality in the system, and the experimental gas composition introduced is shown in Table 1.

[0051] During the whole experimental process of this example, the gas hydrate particles were uniformly dispersed in the oil phase, and no hydrate accumulation, agglomeration and ...

Embodiment 3

[0053] This example provides a compounded hydrate inhibitor containing lecithin, which is obtained by compounding (Span20+Tween60), lecithin and ethanol at a mass ratio of 0.5:1:3.

[0054] In this embodiment, the high-pressure sapphire reactor described in Comparative Example 1 is used for evaluation, and the specific experimental process is as described in Comparative Example 1.

[0055] In this embodiment, the oil-water system in the reactor is composed of 1.5ml deionized water and 13.5ml of -20# diesel oil, that is, the oil-water system with a water content of 10% (based on the sum of the volumes of water and oil), The addition amount of the polymerization inhibitor in this embodiment is 1.0% of the water quality in the system, and the experimental gas composition introduced is shown in Table 1.

[0056] During the whole experimental process of this example, the gas hydrate particles were uniformly dispersed in the oil phase, and no hydrate accumulation, agglomeration and ...

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Abstract

The invention relates to a complex type hydrate polymerization inhibitor composition containing lecithin and its application, which mainly solves the problems of easy pollution of the environment, poor polymerization inhibition performance and large dosage in the prior art. The present invention adopts a compound type hydrate polymerization inhibitor composition containing lecithin, which consists of polyol type nonionic surfactant, lecithin zwitterionic surfactant and compound synergist in a mass ratio of 0.1 to 5 :0.1~10:0.1~10 compounded to obtain and its application The technical scheme solves the above problems well, and can be used in oil and gas transportation.

Description

technical field [0001] The present invention relates to a composite type hydrate polymerization inhibitor composition containing lecithin and its application. Background technique [0002] Some gas small molecules (such as CH 4 , CO 2 and H 2 S, etc.) and water molecules easily form a non-stoichiometric crystal cage under low temperature and high pressure, which is often called combustible ice. In the process of oil and natural gas extraction and gathering and transportation, the low-temperature and high-pressure environment in which the pipeline is located is very conducive to the formation of hydrate particles. In severe cases, these hydrates can block wellbores, pipelines, valves and some key equipment, thereby affecting the production of natural gas. Development efficiency, especially for oil-gas-water multiphase mixed transportation system, the problem of hydrate is more serious. [0003] Traditional methods to solve hydrate blockage are mainly based on the thermody...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): F17D1/16B01F17/14B01F17/08C09K23/08C09K23/14
CPCF17D1/16C09K23/018
Inventor 闫柯乐张红星马明姜鸣李莹李明哲肖安山邹兵
Owner CHINA PETROLEUM & CHEM CORP