Preparation method of semiconductive electromagnetic shielding material
An electromagnetic shielding material and semi-conductive technology, applied in the manufacture of conductive/antistatic filaments, conjugated synthetic polymer artificial filaments, etc., can solve problems such as easy aggregation, poor performance, and poor spinning and forming effects of nano-carbon fibers
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Embodiment 1
[0021] Graphite pretreatment, adding sodium fluoride to the nano-graphite powder, adding a metal catalyst, mixing, heating at 600°C under the protection of an inert gas, and controlling the heating time to 10min, fixing sodium fluoride on the surface of the nano-graphite powder .
[0022] Nano-carbon fiber pretreatment, the nano-carbon fiber is oxidized with concentrated sulfuric acid and potassium permanganate mixed acid, after ultrasonic vigorous stirring, the carboxylated nano-carbon fiber is obtained, the surface treatment agent is added, heat treatment at 150 ° C for 10 minutes, and silver is added. Under the protection of a mixed gas of nitrogen and helium, heat at 400° C. for 30 minutes to uniformly disperse the silver in the carbon nanofibers.
[0023] Put pretreated graphite and pretreated nano-carbon fiber in a container, dissolve with 150 parts of isopropanol, then add dispersant, polyphenylene sulfide, PPS resin, blend with a strong mixer, and then use an ultrasoni...
Embodiment 2
[0034] Graphite pretreatment, adding sodium fluoride to the nano-graphite powder, adding a metal catalyst, mixing, heating at 650°C under the protection of an inert gas, and controlling the heating time for 15 minutes, and fixing sodium fluoride on the surface of the nano-graphite powder .
[0035] Nano-carbon fiber pretreatment, the nano-carbon fiber is oxidized with concentrated sulfuric acid and potassium permanganate mixed acid, after ultrasonic vigorous stirring, to obtain carboxylated nano-carbon fiber, add surface treatment agent, heat treatment at 200 ° C for 15 minutes, add silver, in Under the protection of a mixed gas of nitrogen and helium, heat at 450° C. for 45 minutes to uniformly disperse the silver in the carbon nanofibers.
[0036] Put pretreated graphite and pretreated nano-carbon fiber in a container, dissolve with 250 parts of isopropanol, then add dispersant, polyphenylene sulfide, PPS resin, blend with a strong mixer, and then use an ultrasonic disperser...
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