Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Full-biodegradable heat-resistant polylactic acid foaming material and preparation method thereof

A polylactic acid foaming and all-biological technology, which is applied in the field of fully biodegradable heat-resistant polylactic acid foaming materials and its preparation, can solve the problems of difficult industrial production, high precision foaming process, and being in the experimental stage, and achieve crystallization The effect of fast speed, increased molecular weight and molecular chain length, and wide processing window

Inactive Publication Date: 2017-12-08
HEILONGJIANG XINDA ENTERPRISE GRP
View PDF2 Cites 6 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These technical solutions can improve the foaming performance of PLA to a certain extent, but they are basically still in the experimental stage
U.S. patents US20080262118 and US20110263732 have prepared polylactic acid foamed materials by using composite D-configuration PLA, but the foam size is large, the opening rate is high, the foaming process is high-precision, and the cost is high, so it is difficult to realize industrial production

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Weigh the following raw materials by weight:

[0044] Polylactic acid (U.S. Natureworks4032D) 87.5Kg, PBAT resin (Biocosafe2003, Yifan Xinfu Pharmaceutical Co., Ltd.) 8Kg, chain extender (ADR4370, BASF AG) 1Kg, nucleating agent (EBH, Suzhou Liansheng Chemical Co., Ltd. , 1Kg: talcum powder, 5000 mesh, Dandong Tianci Flame Retardant Material Technology Co., Ltd., 2kg), foaming aid (polyoxyethylene sorbitan fatty acid ester T-80, Shanghai Yanri Pressure Industrial Co., Ltd.) 0.5kg .

[0045] The preparation method of heat-resistant polylactic acid foam material:

[0046] First, add polylactic acid to a high-speed mixing dryer, dry at 105°C for 30 minutes, add other additives after cooling and mix evenly; then put the mixed material into a twin-screw extruder for melt blending (screw temperature is 165 ℃-185℃), after drawing, air-cooling, and pelletizing, a fully biodegradable heat-resistant polylactic acid foam material is obtained. The selected twin-screw extruder has...

Embodiment 2

[0048] Weigh the following raw materials by weight:

[0049]Polylactic acid (Natureworks4032D, USA) 85.5Kg, PBAT resin (Biocosafe2003, Yifan Xinfu Pharmaceutical Co., Ltd.) 10Kg, chain extender (ADR4370, BASF AG) 1.5Kg, nucleating agent (EBH, Suzhou Liansheng Chemical Co., Ltd. Company, 1kg; talcum powder, 5000 mesh, Dandong Tianci Flame Retardant Material Technology Co., Ltd., 1kg), foaming aid (polyoxyethylene sorbitan fatty acid ester T-80, Shanghai Yanwang Industrial Co., Ltd.) 1kg.

[0050] The preparation method is as described in Example 1.

Embodiment 3

[0052] Weigh the following raw materials by weight:

[0053] Polylactic acid (U.S. Natureworks4032D) 86Kg, PBAT resin (Biocosafe2003, Yifan Xinfu Pharmaceutical Co., Ltd.) 9Kg, chain extender (ADR4370, BASF AG) 0.5Kg, nucleating agent (EBH, Suzhou Liansheng Chemical Co., Ltd. 0.5kg; talcum powder, 5000 mesh, Dandong Tianci Flame Retardant Material Technology Co., Ltd., 1kg), foaming aid (polyoxyethylene sorbitan fatty acid ester T-80, Shanghai Yanwang Industrial Co., Ltd.) 3kg.

[0054] The preparation method is as described in Example 1.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a fully biodegradable heat-resistant polylactic acid foaming material and a preparation method thereof, comprising 85-90% by weight of polylactic acid, 1-10% of PBAT resin, 0.1-3% of a chain extender, and 0.1% of a nucleating agent. ~5%, 0.1~5% foaming aid. Continuous foaming technology can be realized by using this foaming material. The prepared foamed product has the advantages of uniform cell size and high closed cell rate, and maintains the advantages of polylactic acid biodegradation, which is fully in line with the development of green, low-carbon and sustainable economy. It has a broad application market in the field of disposable lunch boxes, fast food boxes and hamburger boxes, instant noodle bowls and packaging. The preparation method of the present invention: first dry the polylactic acid, add other components after cooling and mix uniformly; then add it to a twin-screw extruder for melt blending, and then pull strands, air-cool, and pelletize to obtain. The preparation method is simple, easy to control and implement, strong in operability, and easy to industrialized production.

Description

technical field [0001] The invention relates to the technical field of heat-resistant polylactic acid material and its preparation, in particular to a fully biodegradable heat-resistant polylactic acid foam material and a preparation method thereof. Background technique [0002] With the rapid development of the global economy, plastics have penetrated into various fields of the national economy. However, most of the plastics currently used are derived from petroleum, which greatly exacerbates the problem of "shortage of petroleum resources". Polylactic acid is the only biological resource as raw material, which has good biocompatibility, degradability, high tensile strength and compression modulus, so polylactic acid is considered to be a substitute for petroleum-based plastics. Applying it to the field of general-purpose plastics is of great significance for reducing environmental pollution, saving oil resources and alleviating the global warming effect. The shortage of p...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08L67/04C08L67/02C08K5/20C08K3/34C08J9/12
CPCC08L67/04C08J9/0095C08J9/122C08J2203/06C08J2205/052C08J2367/04C08J2467/02C08K2201/003C08L2201/06C08L2201/08C08L2203/14C08L2205/03C08L2205/24
Inventor 于敬阳崔成杰谢众
Owner HEILONGJIANG XINDA ENTERPRISE GRP
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products