Technology for removing residual antibiotics/ pesticides in oil in situ and remediating soil and application

A technology for antibiotics and soil, applied in the field of in-situ elimination and restoration of soil residual antibiotics and pesticides, can solve problems such as high cost, secondary pollution, and incomplete clearing, and achieve the effect of simple method, reduced investment, and simple and easy technology

Inactive Publication Date: 2017-12-22
吴洪生
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0010] These methods have their own advantages and disadvantages, and most of them are used for water pollution control, but not many are us...

Method used

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  • Technology for removing residual antibiotics/ pesticides in oil in situ and remediating soil and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] 1. In any soil contaminated with antibiotics and / or organic pesticides, add 1mol / LFeSO to 1000 kg of antibiotics and / or organic pesticides contaminated soil by mass / volume ratio 4 8 liters of solution, irradiated with a 1 kW UV lamp, sealed with plastic film, tents, or other coverings, and stirred the soil at the same time, paused after 1 hour, stirred the soil, and then added 1mol / L FeSO 4 8 liters of solution, continue to irradiate the soil with a 1 kW UV lamp for 1 hour, and this process can be repeated 4 times according to the degree of soil pollution and specific conditions;

[0023] 2. Add 10 liters of 30% hydrogen peroxide to the soil treated in the above 1, stir the soil immediately, seal and react for 0.5 hours, then add 10 liters of hydrogen peroxide, quickly stir the soil, and repeat this process 4 times according to the specific situation ;

[0024] 3. Add 10 liters of fresh ozone water (new ozone water produced by the ozone water machine) to the soil treat...

Embodiment 2

[0027] 1. In any soil contaminated with antibiotics and / or organic pesticides, add 3mol / LFeSO to 1000 kg of antibiotics and / or organic pesticides contaminated soil by mass / volume ratio 4 5 liters of solution, irradiated with a 3 kW UV lamp, sealed with plastic film, tents or other coverings, and stirred the soil at the same time, paused after 2 hours, stirred the soil, and then added 3mol / LFeSO 4 5 liters of solution, continue to irradiate the soil with a 3 kW UV lamp for 2 hours, and this process can be repeated 5 times according to the degree of soil pollution and specific conditions;

[0028] 2. Add 5 liters of 30% hydrogen peroxide to the soil treated in the above 1, stir the soil immediately, seal and react for 1 hour, then add 5 liters of hydrogen peroxide, quickly stir the soil, and repeat this process 6 times according to the specific situation ;

[0029] 3. Add 5 liters of fresh ozone water (newly produced ozone water by the ozone water machine) to the soil treated i...

Embodiment 3

[0032] 1. In any soil contaminated with antibiotics and / or organic pesticides, add 1mol / LFeSO to 1000 kg of antibiotics and / or organic pesticides contaminated soil by mass / volume ratio 4 The solution is 1 liter, irradiated with an 8 kW UV lamp, sealed with plastic film tents or other coverings, and stirred the soil at the same time, paused after 2 hours, stirred the soil, and then added 1mol / LFeSO 4 With 5 liters of solution, continue to irradiate the soil with an 8 kW UV lamp for 1-3 hours. According to the degree of soil pollution and specific conditions, this process can be repeated 3 times;

[0033] 2. Add 8 liters of 30% hydrogen peroxide to the soil treated in the above 1, stir the soil immediately, seal and react for 1 hour, then add 8 liters of hydrogen peroxide, quickly stir the soil, and repeat this process 3 times according to the specific situation ;

[0034] 3. Add 8 liters of fresh ozone water (new ozone water produced by the ozone water machine) to the soil tre...

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Abstract

The invention provides a technology for removing residual antibiotics/ pesticides in oil in situ and remediating soil and application, and belongs to the field of environmental protection. The technology comprises the following steps: adding FeCl2 to the soil polluted by antibiotics and organic pesticides; irradiating with ultraviolet rays; then adding proper amount of hydrogen peroxide/ ozone water; and stirring to completely oxidize and decompose all antibiotics and/ or organic pesticides. With the adoption of the technology, all antibiotics and/ or organic pesticides are completely oxidized and decomposed, so that secondary pollution is avoided, and the pollution and harm of antibiotics and pesticides to the soil can be removed; the environment and the ecological system can be protected; and the human sustainable development is kept.

Description

technical field [0001] The invention belongs to the field of environmental protection, and particularly relates to an in-situ elimination and restoration technology and application of soil residual antibiotics and pesticides. Background technique [0002] Soil pollution, especially chemical plants, oil refineries, petrochemicals, gas stations, organic waste landfills and other places, organic pollution caused by various petroleum products, organic chemical monomers, intermediate products and end products, as well as papermaking Organic pollution caused by factories, food factories, fine chemical factories, liquefied gas factories, dye factories, pesticide factories, etc. is becoming more and more serious in our country. The main organic pollutants in the soil are pesticides, chloral, polycyclic aromatic hydrocarbons, polychlorinated biphenyls, petroleum, methane, etc., among which pesticides are the most important organic pollutants. [0003] Organic pollutants in soil main...

Claims

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Application Information

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IPC IPC(8): B09C1/08
CPCB09C1/08
Inventor 吴洪生
Owner 吴洪生
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