Light-mass and high-strength aluminum magnesium copper high-entropy alloy and preparation method thereof

A high-entropy alloy and high-strength technology, applied in the field of light-weight high-strength aluminum-magnesium-copper high-entropy alloy and its preparation, can solve the problems of high cost, high energy consumption, and increased energy consumption of alloy smelting, and achieve low cost and low energy consumption. Effect

Active Publication Date: 2018-02-09
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The special working conditions of aerospace materials require the material to have high specific strength, that is, the material is not only required to have high strength but also low density, but the transition metal elements often have a large density, which will inevitably lead to a high density of multi-component high-entropy alloys.
(2) High cost
Obviously, the raw materials of the existing high-entropy alloy components are often expensive, and each component has a high atomic percentage in the high-entropy alloy, which greatly increases the manufacturing cost of the alloy.
(3) High energy consumption, traditional high-entropy alloy components often have a higher melting point, which will inevitably lead to an increase in energy consumption for alloy smelting

Method used

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  • Light-mass and high-strength aluminum magnesium copper high-entropy alloy and preparation method thereof
  • Light-mass and high-strength aluminum magnesium copper high-entropy alloy and preparation method thereof
  • Light-mass and high-strength aluminum magnesium copper high-entropy alloy and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0023] The molecular formula of the lightweight high-strength aluminum-magnesium-copper high-entropy alloy of this example is Al 58.5 Mg 31.5 Cu 4.5 Zn 4.5 Si 1 , the preparation steps are as follows: the raw materials Al, Mg, Cu, Zn, Si with a purity greater than 99.9% are pressed by Al 58.5 Mg 31.5 Cu 4.5 Zn 4.5 Si 1 of ingredients to prepare 100g. Put the prepared raw materials into the graphite crucible in order of melting point from low to high, the element with the lowest melting point is placed at the bottom, and the element with the highest melting point is placed at the top. Put the graphite crucible filled with alloy materials into the spiral induction coil, evacuate to below 20Pa, and then fill with argon to 0.3MPa. Start the high-frequency induction device to control the induction heating current. After the alloy ingot melts, keep the alloy in a molten state for 30 minutes to make the alloy composition uniform. Cast the uniformly smelted alloy liquid into...

Embodiment 2

[0025] The molecular formula of the lightweight high-strength aluminum-magnesium-copper high-entropy alloy of this example is Al 63 Mg 27 Cu 4.5 Zn 4.5 Si 1 , the preparation steps are as follows: the raw materials Al, Mg, Cu, Zn, Si with a purity greater than 99.9% are pressed by Al 63 Mg 27 Cu 4.5 Zn 4.5 Si 1 of ingredients to prepare 100g. Put the prepared raw materials into the graphite crucible in order of melting point from low to high, the element with the lowest melting point is placed at the bottom, and the element with the highest melting point is placed at the top. Put the graphite crucible filled with alloy materials into the spiral induction coil, evacuate to below 20Pa, and then fill with argon to 0.3MPa. Start the high-frequency induction device to control the induction heating current. After the alloy ingot melts, keep the alloy in a molten state for 30 minutes to make the alloy composition uniform. Cast the uniformly smelted alloy liquid into a steel...

Embodiment 3

[0027] The molecular formula of the lightweight high-strength aluminum-magnesium-copper high-entropy alloy of this example is Al 67.5 Mg 22.5 Cu 4.5 Zn 4.5 Si 1 , the preparation steps are as follows: the raw materials Al, Mg, Cu, Zn, Si with a purity greater than 99.9% are pressed by Al 67.5 Mg 22.5 Cu 4.5 Zn 4.5 Si 1 of ingredients to prepare 100g. Put the prepared raw materials into the graphite crucible in order of melting point from low to high, the element with the lowest melting point is placed at the bottom, and the element with the highest melting point is placed at the top. Put the graphite crucible filled with alloy materials into the spiral induction coil, evacuate to below 20Pa, and then fill with argon to 0.3MPa. Start the high-frequency induction device to control the induction heating current. After the alloy ingot melts, keep the alloy in a molten state for 30 minutes to make the alloy composition uniform. Cast the uniformly smelted alloy liquid into...

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Abstract

The invention relates to a light-mass and high-strength aluminum magnesium copper high-entropy alloy and a preparation method thereof. A component atom formula of the designed high-entropy alloy is AlxMgyCuzZnvSiw, wherein x+y+z+v+w=100, x=55-90, y=7-35, z=1-5, v=1-5, and w=0.3-1. A phase structure relating to the alloy uses face center cubic (FCC) solid solution as a main material. The inventionfurther provides the preparation method of the AlxMgyCuzZnvSiw high-entropy alloy; an alloy cast ingot is prepared by vacuum inductive smelting and direct casting; no pollution is generated in the preparation process; the energy consumption is low; the cost is low; and the preparation of the light-mass massive high-entropy alloy becomes possible.

Description

technical field [0001] The invention belongs to the field of metal material preparation, and in particular relates to a light-weight high-strength aluminum-magnesium-copper high-entropy alloy and a preparation method thereof. Background technique [0002] High-entropy alloys break through the traditional design concept and are alloyed according to equiatomic or nearly equiatomic ratios. They generally contain 5 to 13 elements, and cannot distinguish between solvent components and solute components in a solid solution, forming a disordered multi-component super solid solution. The high entropy effect effectively inhibits the precipitation of intermetallic compounds, reduces the alloy brittleness caused by multi-component alloys, and forms a phase structure dominated by solid solutions. [0003] Existing studies have found that the unique solid solution structure of high-entropy alloys often makes them have some excellent properties that cannot be compared with traditional all...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/08C22C1/02
CPCC22C1/026C22C21/08
Inventor 张勇李亚耸邵磊张蔚冉李蕊轩
Owner UNIV OF SCI & TECH BEIJING
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