Fluorosilicone resin/composite modified nano-material hybrid super-amphiphobic coating and preparation technology thereof

A technology of composite modification and fluorosilicone resin, which is applied in coatings, anti-corrosion coatings, etc., can solve the problems of coating film-forming property decline, achieve improved dispersion, improve hydrophilic characteristics, and improve the formation of microscopic rough structures Effect

Active Publication Date: 2018-02-23
ELECTRIC POWER RESEARCH INSTITUTE OF STATE GRID SHANDONG ELECTRIC POWER COMPANY +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, most of the studies on fluorosilicone superhydrophobic coatings are limited to the filling effect of a single nano

Method used

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  • Fluorosilicone resin/composite modified nano-material hybrid super-amphiphobic coating and preparation technology thereof
  • Fluorosilicone resin/composite modified nano-material hybrid super-amphiphobic coating and preparation technology thereof
  • Fluorosilicone resin/composite modified nano-material hybrid super-amphiphobic coating and preparation technology thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0066] A wear-resistant fluorosilicone resin / composite modified nano-SiO 2 -TiO 2 Hybrid super-amphiphobic coating, including the weight percentage of the following components: 30% fluorosilicone resin, 39% dispersion solvent, composite modified nano-SiO 2 -TiO 2 Particles 30%, coupling agent 0.7%, defoamer 0.3%.

[0067] In this embodiment, wear-resistant fluorosilicone resin / composite modified nano-SiO 2 -TiO 2 The preparation process of hybrid super amphiphobic coating comprises the following steps:

[0068] 1. Nano SiO 2 with nano TiO 2 Composite modification treatment to obtain composite modified nano-SiO 2 -TiO 2 .

[0069] (1) Blended ball milled nano-SiO 2 -TiO 2 Preparation of powder: weigh a certain amount of nano-scale SiO 2 , Nanoscale TiO 2 , placed in a mixer and mixed evenly, and then placed in a planetary ball mill for ball milling to obtain a blended ball milled nano-SiO 2 -TiO 2 powder. nano-SiO 2 The particle size is 20~30nm, nano TiO 2 Par...

Embodiment 2

[0081] A wear-resistant fluorosilicone resin / composite modified nano-SiO 2 -TiO 2 Hybrid super-amphiphobic coating, including the weight percentage of the following components: 30% fluorosilicone resin, 49% dispersion solvent, composite modified nano-SiO 2 -TiO 2 Particles 20%, coupling agent 0.7%, defoamer 0.3%. In this embodiment, wear-resistant fluorosilicone resin / composite modified nano-SiO 2 -TiO 2 The preparation process of the hybrid super-amphiphobic coating is the same as in Example 1.

Embodiment 3

[0083] A wear-resistant fluorosilicone resin / composite modified nano-SiO 2 -TiO 2 Hybrid super-amphiphobic coating, including the weight percentage of the following components: 30% fluorosilicone resin, 50% dispersion solvent, composite modified nano-SiO 2 -TiO 2 Particles 19%, coupling agent 0.7%, defoamer 0.3%. In this embodiment, wear-resistant fluorosilicone resin / composite modified nano-SiO 2 -TiO 2 Composite modified nano-SiO in the preparation process of hybrid superamphiphobic coating 2 -TiO 2 The coupling agent used is tridecafluorooctyltriethoxysilane, and other processes are the same as in Example 1.

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Abstract

The invention discloses a fluorosilicone resin/composite modified nano-material hybrid super-amphiphobic coating and a preparation technology thereof. Coating materials used by the coating include fluorosilicone resin, a dispersing solvent, composite modified nano-SiO2-TiO2 particles, a first coupling agent and a defoamer. A preparation method of the composite modified nano-SiO2-TiO2 particles comprises the following steps: carrying out ball milling mixing on nano-SiO2 and nano-TiO2 to obtain mixed nano-powder, adding the mixed nano-powder and a surfactant to a first solvent, performing dispersing to obtain a mixed nano-powder dispersion, adding a second coupling agent to a mixture of a first solvent and water in order to obtain a coupling agent hydrolysate, dropwise adding the coupling agent hydrolysate to the mixed nano-powder dispersion, and performing stirring, heating and reacting to obtain the composite modified nano-SiO2-TiO2 particles. The composite modification of SiO2-TiO2 nanoparticles can greatly improve the addition amount of the particles without affecting the other properties of the coating, so the fluorosilicone coating has the advantages of real and effective super-amphiphobic property, good wear resistance and simple preparation technology.

Description

technical field [0001] The invention relates to the field of preparation of super-amphiphobic coatings, in particular to a wear-resistant fluorosilicone resin / composite modified nano-SiO 2 -TiO 2 Hybrid superamphiphobic coating and its preparation process. Background technique [0002] Superhydrophobic coating refers to coating one or more layers of superhydrophobic materials on a solid surface to have a high water contact angle (>150°) and a low rolling angle (<10°) to achieve its anti-corrosion, waterproof, Anti-icing and other functions. Due to its excellent hydrophobicity, the super-hydrophobic coating can be coated on the outside of metal components to reduce the surrounding of water vapor and achieve anti-corrosion function; in the case of freezing rain and snowfall, the super-hydrophobic surface remains in a non-icing state or reduces the adhesion of the ice layer , to prevent or delay the icing of transmission lines, and to prepare superhydrophobic coatings ...

Claims

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Application Information

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IPC IPC(8): C09D183/08C09D5/08C09D5/00C09D7/62
CPCC08K3/36C08K9/06C08K2003/2241C08K2201/011C09D5/00C09D5/08C09D183/08
Inventor 吴亚平米春旭李辛庚王晓明宗立君郭凯姜波张振岳闫风洁李文静樊志彬王蝶
Owner ELECTRIC POWER RESEARCH INSTITUTE OF STATE GRID SHANDONG ELECTRIC POWER COMPANY
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