Aluminum alloy oxidation liquid recovery and cooling equipment crystal elimination system and process
A technology of cooling equipment and cleaning system, applied in the field of aluminum product processing, can solve problems such as waste of tap water, and achieve the effects of reducing labor intensity, eliminating the risk of high-level operations, and high recovery rate
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[0068] The technical solutions of the present invention will be further described below in conjunction with the accompanying drawings and specific embodiments.
[0069] 1. Theoretical basis for the recovery of aluminum ions and sulfuric acid in the anodizing solution
[0070] When the aluminum alloy is oxidized, according to formula (3), part of the oxide film is dissolved, and about 4Kg / T (400m2) of aluminum is dissolved into the sulfuric acid oxidation solution. Ammonium sulfate is added to this oxidizing solution, and the following reaction takes place:
[0071] Al 2 (SO 4 ) 3 +(NH 4 ) 2 SO 4 +12H 2 O=2NH 4 Al(SO 4 ) 2 12H 2 O↓ (5)
[0072] Under the conditions of 160-200g / L sulfuric acid, containing aluminum and ammonium ions, ammonium aluminum sulfate NH 4 Al(SO 4 ) 2 12H 2 O crystallizes out, and the amount of residual aluminum ions is related to the crystallization temperature and time.
[0073] 2. Quantitative analysis of experimental results
[0074]...
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