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Method for preparing magnetic activated carbon powder from fly ash through processing

A technology of magnetic activated carbon and fly ash, applied in chemical instruments and methods, alkali metal oxides/hydroxides, inorganic chemistry, etc. Pore ​​volume, outstanding performance

Inactive Publication Date: 2018-05-18
安徽宇瑞环保建设有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the utilization of fly ash is still very basic, and it cannot obtain high-end utilization value

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A method for processing fly ash into magnetic activated carbon powder, comprising the following steps:

[0017] (1) Grind fly ash until the particle size is in the range of 40-60 mesh, add calcium oxide powder with a mass fraction of 0.2%, mix well, add 2 times the volume of water and stir to dissolve, use a concentration of 2 mol / liter Adjust the pH value of the system with hydrochloric acid in the range of 10.5-10.6, add polyaluminum chloride with a mass fraction of 0.15% of the system, place it in a constant temperature water bath at 55°C and stir for 30 minutes, let it stand for cooling for 6 hours, filter, wash, and further dry Dry to constant weight to obtain pretreated fly ash;

[0018] (2) Weigh ferrous sulfate heptahydrate and ferric chloride hexahydrate according to the mass ratio of 2:7, dissolve them in 4 times the volume of deionized water, stir and mix for 20 minutes, and add the prepared in step (1) The amount of pretreated fly ash accounted for 25% of t...

Embodiment 2

[0024] A method for processing fly ash into magnetic activated carbon powder, comprising the following steps:

[0025] (1) Grind fly ash until the particle size is in the range of 40-60 mesh, add calcium oxide powder with a mass fraction of 0.3%, mix well, add 2.5 times the volume of water to stir and dissolve, and use a concentration of 2.5 mol / L Adjust the pH value of the system with hydrochloric acid in the range of 10.5-10.6, add polyaluminum chloride with a mass fraction of 0.18% of the system, place it in a constant temperature water bath at 60°C and stir for 35 minutes, let it stand for cooling for 7 hours, filter, wash, and further dry Dry to constant weight to obtain pretreated fly ash;

[0026] (2) Weigh ferrous sulfate heptahydrate and ferric chloride hexahydrate according to the mass ratio of 2.5:7.5, dissolve them in 4.5 times the volume of deionized water successively, stir and mix for 25 minutes, add the prepared in step (1) The amount of pretreated fly ash acc...

Embodiment 3

[0032] A method for processing fly ash into magnetic activated carbon powder, comprising the following steps:

[0033] (1) Grind fly ash until the particle size is in the range of 40-60 mesh, add calcium oxide powder with a mass fraction of 0.4%, mix well, add 3 times the volume of water to stir and dissolve, and use a concentration of 3 mol / liter Adjust the pH value of the system with hydrochloric acid in the range of 10.5-10.6, add polyaluminum chloride with a mass fraction of 0.20% of the system, place it in a constant temperature water bath at 65°C and stir for 40 minutes, let it stand for cooling for 8 hours, filter, wash, and further dry Dry to constant weight to obtain pretreated fly ash;

[0034] (2) Weigh ferrous sulfate heptahydrate and ferric chloride hexahydrate according to the mass ratio of 3:8, dissolve them in 5 times the volume of deionized water, stir and mix for 30 minutes, and add the prepared in step (1) The amount of pretreated fly ash accounted for 30% ...

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PUM

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Abstract

The invention relates to the technical field of industrial waste treatment engineering and discloses a method for preparing magnetic activated carbon powder from fly ash through processing. Accordingto the method, firstly, the fly ash is pretreated, an obtained fly ash structure tends to be stable, then iron salt is utilized to promote enrichment and development of pores, meanwhile, iron oxide particles are subjected to a reaction in pores in the surface of the fly ash, new holes can be produced, pore volume of activated carbon is increased, the iron particles dispersed in activated carbon are exposed again by the aid of the new holes, magnetic reaction is promoted, and under the synergistic effect of the fly ash and the iron salt, the prepared material has outstanding magnetism and adsorbability, can chemically adsorb non-metal substances such as nitrogen, phosphorus and the like and can physically adsorb metals, thereby having great significance when applied to sewage treatment.

Description

technical field [0001] The invention belongs to the technical field of industrial waste treatment engineering, and in particular relates to a method for processing fly ash into magnetic activated carbon powder. Background technique [0002] Fly ash is the fine ash collected from the flue gas after coal combustion. Fly ash is the main solid waste discharged from coal-fired power plants. The oxide composition of fly ash in thermal power plants in my country is: SiO2, Al2O3 and a small amount of FeO, Fe2O3, CaO, MgO, SO3, TiO2, etc. Among them, the content of SiO2 and Al2O3 can account for more than 60% of the total content. Fly ash is one of the largest industrial wastes in my country. With the development of the power industry, the discharge of fly ash from coal-fired power plants is increasing year by year. If a large amount of fly ash is not treated, it will generate dust and pollute the atmosphere; if it is discharged into the water system, it will cause river silting, a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/20B01J20/28B01J20/30C02F1/28
CPCB01J20/0229B01J20/0288B01J20/041B01J20/08B01J20/103B01J20/20B01J20/28009C02F1/283
Inventor 祁芳
Owner 安徽宇瑞环保建设有限公司