Environment-friendly sealant and preparation method thereof
A caulking agent, an environment-friendly technology, applied in the field of environment-friendly caulking agent and its preparation, can solve problems such as insecurity, cancer induction, structural cracking, etc., and achieve the effect of good pan-alkali resistance, environmental friendliness and excellent performance
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[0056] As a kind of preferred technical scheme of the present invention, the preparation method of described montmorillonite modified ammonium hydrogen maleate-acrylic acid copolymer at least comprises the following steps:
[0057] Dissolve ammonium hydrogen maleate and acrylic acid in deionized water, wherein the volume ratio of acrylic acid and deionized water is 1:300, stir for 15-30min, add organic montmorillonite to it, blow in nitrogen, and put in a water bath at 45°C Stir at low temperature for 30 minutes, and add crosslinking agent and initiator in turn; under nitrogen protection, seal and put it in a 45°C water bath for 3 hours, and then react in a 80°C water bath for 2 hours; take out the product and wash it with ethanol for 3 times, put it in 110 Dry in an oven at ℃ for 24 hours, pulverize, and sieve to obtain the montmorillonite-modified ammonium hydrogen maleate-acrylic acid copolymer with a mesh size of 100 to 200; wherein the mass ratio of initiator, crosslinking...
Embodiment 1
[0085] Embodiment 1 provides an environment-friendly sealant, which includes at least the following components in parts by weight: 25 parts by weight of cement; 5 parts by weight of calcite powder; 10 parts by weight of inorganic filler; 0.1 part by weight of water-retaining agent; redispersible 0.3 parts by weight of latex powder; 5 parts by weight of water glass powder; 0.5 parts by weight of curing agent; 0.1 parts by weight of defoamer; The particle size of the calcite powder is greater than 1000 mesh; the water-retaining agent is a mixture of cellulose ether and montmorillonite modified ammonium hydrogen maleate-acrylic acid copolymer, wherein the cellulose ether and montmorillonite modified cis The mass ratio of ammonium hydrogen butenediolate to acrylic acid copolymer is 3:1.
[0086] The cement is Portland cement, purchased from Zhejiang Hongtu Building Materials Co., Ltd., model P.O 42.5. The inorganic filler is washed sand, which is purchased from Lingshou County Fe...
Embodiment 2
[0095] Embodiment 2 provides an environment-friendly sealant, which at least includes the following components in parts by weight: 45 parts by weight of cement; 20 parts by weight of calcite powder; 60 parts by weight of inorganic filler; 0.5 parts by weight of water-retaining agent; redispersible 2 parts by weight of latex powder; 10 parts by weight of water glass powder; 1 part by weight of curing agent; 0.2 parts by weight of defoamer; 0.5 parts by weight of water repellent; the cement is selected from portland cement or white cement of any label; The particle size of the calcite powder is greater than 1000 mesh; the water-retaining agent is a mixture of cellulose ether and montmorillonite modified ammonium hydrogen maleate-acrylic acid copolymer, wherein the cellulose ether and montmorillonite modified cis The mass ratio of ammonium hydrogen butenediolate to acrylic acid copolymer is 3:1.
[0096]The cement is Portland cement, purchased from Zhejiang Hongtu Building Materi...
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Abstract
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