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Separation membrane carrier and application thereof

A separation membrane and carrier technology, applied in the field of membrane separation, can solve the problems of carrier layer transmission resistance, lower separation membrane flux, and lower packing density of components, so as to improve flux and selectivity, facilitate production and maintenance, and increase packing density Effect

Pending Publication Date: 2018-06-01
HYMATER CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in order to ensure sufficient mechanical strength, the wall thickness of the general separation membrane carrier is usually thicker than 2 mm, which will lead to significant carrier layer transmission resistance, resulting in a decrease in the flux of the separation membrane
In addition, the commonly used supports with circular interfaces cannot achieve a close planar arrangement, so the filling area per unit volume of the final membrane module will be reduced.
[0005] Multi-channel support is also a form of support traditionally used. In order to increase the surface area per unit volume, the separation layer is generally grown on the inner surface of the multi-channel, which will increase the difficulty of coating the separation layer. In addition, this type of separation When the membrane is used, the shell side is the permeate side. For separation systems (such as pervaporation and steam permeation) with a vacuum on the permeate side, a large shell side volume needs to be reserved, which will reduce the packing density of the components.

Method used

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  • Separation membrane carrier and application thereof
  • Separation membrane carrier and application thereof
  • Separation membrane carrier and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] Embodiment 1. Preparation of separation membrane carrier

[0047] The separation membrane carrier is prepared by a conventional extrusion method, and the material is alumina.

[0048] Carrier A: round tube support body, length 100mm; outer diameter 12mm, inner diameter 8mm;

[0049] Carrier B: four-channel circular tube support body, length 100mm; outer diameter 16mm: channel inner diameter 4mm;

[0050]Carrier C: square support body, length 100mm; section 10mmX10mm, with cross support ridge inside, wall thickness 1mm;

[0051] Carrier D: plate support body, length 100mm; section 5mmX30mm, internal 2mm interval support, wall thickness 1mm.

Embodiment 2

[0052] Embodiment 2. The synthesis of composite separation membrane:

[0053] (1) Synthetic method of NaA type molecular sieve membrane: the synthetic solution of synthetic molecular sieve membrane is formed by mixing silica sol, NaOH, aluminum foil and distilled water, and the proportioning ratio (molar ratio) of the synthetic solution finally obtained is: 50Na 2 O: Al 2 o 3 :5SiO2 2 :1000H 2 O. Expose the surface of the carrier to be coated, place it in the reaction kettle, carefully add the synthesis solution and close the lid of the kettle tightly. After reacting at 90° C. for 6 hours, the synthesized molecular sieve membrane was taken out, washed with distilled water, soaked until neutral, and dried overnight in an oven. In order to obtain a molecular sieve membrane with good separation performance, the above steps are repeated once.

[0054] (2) Synthesis of NaX type molecular sieve membrane

[0055] The synthetic liquid for synthesizing molecular sieve membrane i...

Embodiment 3

[0061] Embodiment 3. Composite molecular sieve membrane performance test test

[0062] 1. Test method

[0063] (1) The flexural strength shall be in accordance with the provisions in 5.4 of HY / T064-2002.

[0064] (2) The measuring method of separation performance is: investigate the performance of pervaporation dehydration of molecular sieve membrane, operating temperature is 50 ℃, raw material liquid is ethanol aqueous solution containing 90% ethanol. By analyzing and measuring the composition of the permeate and the quality of the permeate collected per unit time, the water / ethanol separation coefficient and permeate flux are calculated according to the following formula.

[0065] Separation factor: Indicates the ratio of the relative content of two substances in the material before and after the molecular sieve membrane separation operation. It is defined as:

[0066]

[0067] In the formula, i / j represents the separation coefficient of the molecular sieve membrane fo...

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PUM

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Abstract

The invention provides a separation membrane carrier and application thereof. The separation membrane carrier is of a pipe-shaped body; the radial section of the pipe-shaped body is of a sealed polygon shape meeting plane embedding requirements; the outer surface of the pipe-shaped carrier is used for attaching a separation layer. In the application of the separation membrane carrier, the carriermeeting the plane embedding requirements is utilized; when membrane pipe arrangement is carried out in a membrane assembly, the space can be utilized to the greatest extent; a supporting ridge is combined so that the thickness of the carrier can be greatly reduced and the flux and the selectivity are improved; a structure design that the outer surface of a film pipe of the carrier is coated with the separation layer is adopted so that a membrane pipe sleeve is omitted and extremely great convenience is provided for production and maintenance.

Description

technical field [0001] The invention belongs to the technical field of membrane separation, and relates to a separation membrane used for fluid separation. Background technique [0002] The present invention relates to the technical field of separations employing separation elements commonly referred to as membranes. These membranes are generally made of inorganic materials and comprise a porous support and at least one separation layer, the properties and morphology of which are designed to separate molecules or particles contained in the fluid medium to be treated. Membrane separation separates a liquid containing molecules and / or particles into two fractions: a filtrate fraction, which contains molecules or particles that have passed through the filter membrane and thus through the support and the separation layer; and a retentate fraction, which Contains molecules or particles retained by the filter. [0003] Conventionally, a composite separation membrane is defined a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D69/10B01D69/12B01D69/04B01D71/02B01D63/06B01D63/00B01D61/36
CPCB01D61/362B01D63/00B01D63/06B01D63/061B01D63/065B01D69/04B01D69/10B01D69/12B01D71/028
Inventor 李砚硕陈晨吴大鹏
Owner HYMATER CO LTD
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