High hardness nitrile rubber and preparation method thereof

A technology of nitrile rubber and high hardness, which is applied in the field of rubber to achieve high performance and economic benefits, improve tensile strength, increase hardness and bridging density

Inactive Publication Date: 2018-06-01
党亮才
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The present invention provides a high hardness nitrile rubber and a preparation method thereof in order to solve the proble

Method used

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  • High hardness nitrile rubber and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0016] Embodiment 1: a kind of high hardness nitrile rubber is made by the raw material of following weight: nitrile rubber 100g, zinc oxide 3.5g, stearic acid 1g, antioxidant 1.5g, octyl phenolic tackifying resin 2.0g, carbon Black 100g, softener 6g, vulcanizing agent 2.0g, accelerator 1.5g.

[0017] Described antioxidant is made up of 0.5g antioxidant RD and 1.0g antioxidant 4010NA; Described carbon black is made up of 85 parts of carbon black SP5000 and 15 parts of carbon black N990; Described softening agent is made up of 3g DOP and 3g PL- 400 composition; the vulcanizing agent is composed of 0.5g sulfur and 1.5g vulcanizing agent DCP; the accelerator is composed of 1.0g accelerator DM and 0.5g accelerator TMTD.

[0018] Correspondingly, the preparation method of this high hardness nitrile rubber material may further comprise the steps:

[0019] Add nitrile rubber to the internal mixer, masticate for 150 seconds at 45°C, add the above-mentioned parts by weight of zinc oxi...

Embodiment 2

[0020] Embodiment 2: a kind of high hardness nitrile rubber, is made by the raw material of following weight: nitrile rubber 100g, zinc oxide 5g, stearic acid 1g, antioxidant 2.5g, octyl phenolic tackifying resin 3.0g, carbon black 115g, softener 8g, vulcanizing agent 3.5g, accelerator 2.0g.

[0021] Described antioxidant is 2.5 parts of antioxidant RD; Described carbon black is made up of 80 parts of carbon black N220 and 35 parts of carbon black N330; Described softening agent is 8 parts of DOP; Described vulcanizing agent is 3.5 parts of sulfur; The accelerator consisted of 0.9 parts of accelerator DM and 1.1 parts of accelerator CZ. Its preparation method is the same as the preparation method described in Example 1. The performance test results of the prepared high hardness nitrile rubber material are shown in Table 1.

Embodiment 3

[0022] Embodiment 3: a kind of high hardness nitrile butadiene compounded rubber, is made by the raw material of following weight: nitrile butadiene rubber 100g, zinc oxide 7g, stearic acid 1g, anti-aging agent 3.5g, octyl phenolic tackifying resin 4.0g, Carbon black 120g, softener 10g, vulcanizing agent 4.0g, accelerator 3.0g.

[0023] Described antioxidant is 3.5g antioxidant 4010NA; Described carbon black is made up of 90g carbon black N220 and 30g carbon black N550; Described softening agent is 10g PL-400; Described vulcanizing agent is 4.0g vulcanizing agent DCP; The accelerator is composed of 1.5g accelerator CZ and 1.5g accelerator TMTD. Its preparation method is the same as the preparation method described in Example 1. The performance test results of the prepared high hardness nitrile rubber material are shown in Table 2.

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Abstract

The invention belongs to the technical field of rubber and provides high hardness nitrile rubber and a preparation method of the nitrile rubber in order to solve the problem that the existing nitrilerubber sealing material cannot integrate high hardness and wear resistance. The rubber is prepared from nitrile rubber, zinc oxide, stearic acid, an antiager, octyl-phenolic tackifying resin, carbon black, a softener, a valcanizer and an accelerator according to certain proportions. The rubber is reasonable in compounding, gets a comprehensive balance among product serviceability, appropriate processability and cost reduction, fully exerts potentials of the raw materials and assistants, and achieves unification of high-efficiency, low-consumption and high-performance economic and social benefits. The obtained material has the high hardness, good wear resistance, better tensile strength, better tearing strength and a better permanent compression set value. At the same time, processing operability of the rubber is high, a post-treatment procedure of a product is easy, and physical and mechanical properties are best.

Description

technical field [0001] The invention belongs to the technical field of rubber, and in particular relates to a high-hardness nitrile rubber and a preparation method thereof. Background technique [0002] With the increasing application of high-resistance and high-reliability hydraulic supports, the working resistance of hydraulic cylinders (columns, jacks) is increasing, and the requirements for the performance and life of the rubber seal materials are more stringent. During the use of hydraulic reciprocating sealing components, due to the needs of the working environment, in addition to requiring the product to have excellent high pressure resistance, oil resistance and low compression set performance, it is also required to maintain a very good impact resistance under high pressure for a long time and reliable performance. Therefore, the rubber formulation and mixing process is a highly specialized technical work, which must rely on the continuous optimization of the formu...

Claims

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Application Information

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IPC IPC(8): C08L9/02C08L61/06C08K13/02C08K3/04C08K3/06C08K5/12C08K5/103C08K5/40C08K5/14C08K5/47
CPCC08K2201/014C08L9/02C08L61/06C08K13/02C08K3/04C08K3/06C08K5/12C08K5/103C08K5/40C08K5/14C08K5/47
Inventor 党亮才
Owner 党亮才
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