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A quantitative analysis method for fillers in coatings

A quantitative analysis and coating technology, applied in the preparation of material inspection products and test samples, etc., can solve problems such as large errors and inability to quantitative analysis, and achieve the effect of simple operation, accurate testing, and satisfying testing needs.

Active Publication Date: 2020-11-10
上海微谱检测科技集团股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the analysis of fillers in coatings is generally directly applied to the substrate, after it dries, the coating film is scraped off, ground, and directly analyzed by XRD. This detection method is simple to operate, but has large errors and is only applicable to For the detection of paints containing only a single component in the paint, and cannot be quantitatively analyzed

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0077] Embodiment 1 provides a kind of quantitative analysis method of filler in coating, comprises the following steps at least:

[0078] a. Take the paint sample and use the organic solvent to ultrasonically assist extraction twice. During each extraction process, the volume ratio of the paint sample to the organic solvent is 1:0.3. The organic solvent is a mixture of carbon disulfide, ether and methanol, and the volume ratio of the mixture of carbon disulfide, ether and methanol is 3:0.5:1.2.

[0079] b. Add tetrahydrofuran to the insoluble matter A, ultrasonically disperse, and centrifuge to separate the insoluble solid B in it. The volume ratio of insoluble matter A to THF is 1:2;

[0080] c. Put the insoluble solid B into a vacuum drying oven, and dry it under vacuum at 50°C for 12 hours to obtain a mixed filler;

[0081] d. Grind the mixed filler into powder for qualitative and quantitative analysis.

[0082] The quantitative analysis method of filler in described coa...

Embodiment 2

[0096] The specific implementation method of embodiment 2 is the same as that of embodiment 1, and the difference is that the step a of the quantitative analysis method of the filler in the coating is to get the coating sample and use the organic solvent ultrasonic assisted extraction for 5 times, and the coating sample is extracted 5 times during each extraction process. The volume ratio of organic solvent and organic solvent is 1:0.3. The organic solvent is a mixture of carbon disulfide, ether and methanol, and the volume ratio of the mixture of carbon disulfide, ether and methanol is 3:0.5:1.2.

[0097] Concrete test method is the same as embodiment 1, and the content of talcum powder in filler is 20%; The content of calcium carbonate is 21%; The content of rutile type titanium dioxide type is 19%; The content of anatase type titanium dioxide is 19%; The content of beads was 21%.

Embodiment 3

[0099] The specific implementation method of embodiment 3 is the same as that of embodiment 1, and the difference is that the step a of the quantitative analysis method of the filler in the coating is to get the coating sample and use the organic solvent ultrasonic assisted extraction for 3 times, and the coating sample is extracted 3 times during each extraction process. The volume ratio of organic solvent and organic solvent is 1:0.7. The organic solvent is a mixture of carbon disulfide, ether and methanol, and the volume ratio of the mixture of carbon disulfide, ether and methanol is 3:0.4:1.6.

[0100] Concrete test method is the same as embodiment 1, and the content of talcum powder in filler is 20.7%; The content of calcium carbonate is 20.3%; The content of rutile type titanium dioxide type is 18.9%; The content of anatase type titanium dioxide is 18.9%; The content of beads was 21.2%.

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Abstract

The invention relates to the field of coating component analysis, in particular to a method for quantitative analysis of a filler in a coating. The method for quantitative analysis of the filler in the coating comprises at least the following steps: a. taking the coating, and adding an organic solvent thereto for extraction to obtain an insoluble matter A; b. adding tetrahydrofuran to the insoluble matter A, ultrasonically dispersing, and separating an insoluble solid B therein by centrifugation, the volume ratio of insoluble matter A to tetrahydrofuran being 1 to (1 to 3); c. putting the insoluble solid B in a vacuum drying oven, and drying under vacuum at a temperature of 50 DEG C for 12 to 24 hours to obtain a mixed filler; d. grinding the mixed filler into a powder for qualitative andquantitative analysis.

Description

technical field [0001] The invention relates to the field of component analysis of coatings, in particular to a quantitative analysis method for fillers in coatings. Background technique [0002] Coatings, also known as paints in our country, are usually composed of resins, solvents, fillers and additives. They are the most important part of the modern chemical industry system and are widely used in many industries related to the national economy and people's livelihood, such as industry and agriculture. The research and development of new multifunctional coatings has both huge market value and long-term strategic significance. Generally speaking, there are two main approaches to the development and research of coatings: one approach is to develop new coatings based on the structure and principle of coatings; the other approach is to obtain information from advanced coating formulations and develop research on this basis. , and this method requires the separation and analys...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N1/28G01N33/32
CPCG01N1/28G01N33/32
Inventor 叶菲菲秦秋明吴杰贾梦虹胡赏
Owner 上海微谱检测科技集团股份有限公司