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Shape of nano array on surface of anodic alumina film, method for controlling shape growth of nano array on surface of anodic alumina film in nano-confined space, and application of nano array on surface of anodic alumina film

An anodized aluminum, nanoarray technology, applied in nanotechnology for materials and surface science, chemical instruments and methods, processes for producing decorative surface effects, etc. The particle size and its array arrangement are not well controlled, etc., to achieve the effect of great development potential

Inactive Publication Date: 2018-06-19
WENZHOU UNIVERSITY
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Problems solved by technology

[0005] Aiming at the problems in the prior art of modifying the channels of metal-organic framework materials in the nano-confined space, the particle size and array arrangement of nanoparticles are not well controlled, and the monitoring means for the growth process of nano-arrays is complicated, the invention proposes an anodic aluminum oxide film surface The morphology of nano-array and the method and application of controlling its morphology growth in nano-confined space

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  • Shape of nano array on surface of anodic alumina film, method for controlling shape growth of nano array on surface of anodic alumina film in nano-confined space, and application of nano array on surface of anodic alumina film
  • Shape of nano array on surface of anodic alumina film, method for controlling shape growth of nano array on surface of anodic alumina film in nano-confined space, and application of nano array on surface of anodic alumina film
  • Shape of nano array on surface of anodic alumina film, method for controlling shape growth of nano array on surface of anodic alumina film in nano-confined space, and application of nano array on surface of anodic alumina film

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[0034] As used herein, the meanings of the terms "comprising", "comprising", "containing" and "having" are non-limiting, that is, other steps and other components that do not affect the result can be added. The above terms encompass the terms "consisting of" and "consisting essentially of". Unless otherwise specified, materials, equipment, and reagents are commercially available.

[0035] All solvents used in the present invention are commercially available. Zn(NO 3 ) 2 ·6H 2 O (99% purity), 2-methylimidazole (99% purity), and methanol were purchased from Aladdin Chemical Reagent Co., Ltd.; AAO membrane was purchased from Whatman and Puyuan Nano Technology Co., Ltd. (Hefei, China); distilled water was purchased from Made in MilliQ system (resistance = 18.2 MΩ·cm).

[0036] In order to actively explore the potential application of nanopores, the invention controls the growth of MOF materials in the nanometer confinement space. ZIF-8 is grown on the inner wall of the chann...

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Abstract

The invention provides a shape of a nano array on the surface of an anodic alumina film, a method for controlling the shape growth of the nano array on the surface of the anodic alumina film in a nano-confined space, and an application of the nano array on the surface of the anodic alumina film. The shape of the nano array on the surface of the anodic alumina film comprises an alumina film and a nano array on the surface of the alumina film, wherein the nano array is a ZIF-8 nanopore array with uniform structural distribution, the pore depth is 60+ / -5 mum, and the pore depth-to-width ratio is(4.7+ / -3) x 103. The invention further provides the application of the nano array on the surface of the anodic alumina film in biophysics, biochemistry, ion detection, researches in intermolecular interaction, catalysis and separation, energy storage, and other fields. The shape, the method and the application provided by the invention have the advantages that a synthesis method is simple and lowin cost; the shape can be easily observed and detected; and an obtained nanomaterial is stable in structure and physicochemical property, and is recyclable.

Description

technical field [0001] The invention relates to the field of nanomaterials, in particular to the morphology of nano arrays on the surface of anodic aluminum oxide films and a method and application for controlling the growth of the morphology in a nano-confined space. Background technique [0002] Since the conjecture of nanopore DNA sequencing was put forward in the 1990s, solid-state nanopores with stable pore size and good physical and chemical properties have become the research objects of biophysics and biochemistry. Through the internal modification of the channel, the functionalized solid-state nanopore has performed well in biosensing such as studying the interaction between biomacromolecules, disease diagnosis, drug delivery, ion detection, and deciphering the structure and function of biomacromolecules. test performance. In the future, the application of nanopores in life sciences will be broadened, and nanopore technology will definitely have a profound impact on...

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Application Information

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IPC IPC(8): B81B1/00B81C1/00C08G83/00B82Y30/00
CPCB81B1/002B81C1/00031B82Y30/00C08G83/008
Inventor 刘楠楠刘蒙飞徐向菊钱金杰黄少铭
Owner WENZHOU UNIVERSITY
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