Electrode comprising electrode collector with three-dimensional network structure
A technology of network structure and current collector, applied in the direction of electrode carrier/current collector, electrode current collector coating, structural parts, etc., can solve the problem that electronic conductivity and ionic conductivity cannot be obtained, and the miniaturization and thinning of batteries cannot be overcome. , the reduction of electrode strength and other issues, to achieve high output, shorten physical distance, and prevent the increase of internal resistance.
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Embodiment 1
[0106] Preparation of positive electrode
[0107] LiNi as the positive electrode active material 0.55 mn 0.30 co 0.15 o 2 , Denka black as a conductive material and polyvinylidene fluoride as a binder were mixed in a weight ratio of 96:2:2, and N-methylpyrrolidone (NMP) was added to the mixture to prepare a slurry material.
[0108] The slurry was coated on an aluminum felt having an average pore diameter of 20 μm, an aspect ratio of 100, and a thickness of 40 μm to obtain a unit positive electrode. The unit cathode was dried in a vacuum oven at 120 °C, and then two dried unit cathodes were laminated and rolled to prepare a cathode. Here, the thickness of the electrode including the current collector was 75 μm.
[0109] Preparation of lithium secondary battery
[0110] Lithium metal (40 μm) was adhered to a copper (Cu) foil as a counter electrode, a polyolefin separator was inserted between the positive electrode and the counter electrode, and then injected in ethyl...
Embodiment 2~4
[0112] A lithium secondary battery was prepared in the same manner as in Example 1 except that the average diameter of the pores of the current collector was changed as shown in Table 1.
Embodiment 5
[0114] A lithium secondary battery was prepared in the same manner as in Example 1 except that the thickness of the aluminum felt was changed to 55 μm, and the thickness of the electrode including the current collector was adjusted to 102 μm.
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