XPE (crosslinked polyethylene) foaming material and preparation method thereof

A foaming material and foaming agent technology, applied in the field of XPE foaming material and its preparation, can solve the problems of large cells, short service life and high cost, achieve uniform and fine cells, improve compatibility and production efficiency high effect

Inactive Publication Date: 2018-07-24
FUJIAN SANSHENG IND
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The second is to post-process the substance that is produced, and convert the substance with formamide into other harmless substances without compromising the performance of the material. However, the second method is very difficult to operate in reality. difficult and costly
[0005] At present, XPE materials are used in large quantities. In recent years, there have been more XPE production lines in China, but the surface of the produced materials is often rough, and there are generally relatively large cells, and materials without closed cells appear. When tested by SGS authoritative institutions, they often absorb water. The rate is as high as more than 50%, and the service life is too short, which makes it impossible to apply in waterproof engineering

Method used

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  • XPE (crosslinked polyethylene) foaming material and preparation method thereof

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preparation example Construction

[0031] The present invention also provides a kind of preparation method of above-mentioned XPE foam material, comprises the following steps:

[0032] Step 1. Mix the foaming agent OBSH, foaming agent BIH 40, curing agent, compound foaming aid and surface treatment agent in a high-speed mixer for 3 to 5 minutes at a mixing speed of 200r / min to 400r / min. Prepare modified blowing agent;

[0033] Step 2. Adjust the temperature of the internal mixer to 70-110°C, add low-density polyethylene and linear low-density polyethylene to the internal mixer for the first time for internal mixing, add the modified foaming agent obtained in step 1 after complete melting, and continue to close Refining for 3 to 5 minutes, and then granulating the mass of materials after banburying through a twin-screw granulator to obtain foam masterbatch;

[0034] Step 3. Adjust the temperature of the internal mixer to 70-110°C, add low-density polyethylene and linear low-density polyethylene to the internal ...

Embodiment 1

[0042] A kind of XPE foaming material, comprises the raw material of following weight part: Calculate as 100 parts by total weight part, 54 parts of low-density polyethylene, 36 parts of linear low-density polyethylene, 8 parts of modified blowing agent, crosslinking agent 0.65 part, 0.35 part of auxiliary crosslinking agent, 1 part of masterbatch; Said crosslinking agent is di-tert-butyl peroxide, and said auxiliary crosslinking agent is TAIC;

[0043] The modified foaming agent includes foaming agent OBSH (4,4'-oxobisbenzenesulfonyl hydrazide), foaming agent BIH 40, curing agent, compound foaming aid and surface treatment agent, the foaming agent The weight ratio of foaming agent OBSH, foaming agent BIH 40, curing agent, compound foaming aid and surface treatment agent is 12:8:1:2:2; the curing agent is methylsulfate, and the compound Adding foaming aids is urea, stearic acid and sodium hydroxide, the ratio of the three is 5:2:1, the surface treatment agent is paraffin oil a...

Embodiment 2

[0053] A kind of XPE foaming material, comprises the raw material of following weight part: Calculate with total weight part as 100 parts, low density polyethylene 54.6 parts, linear low density polyethylene 27.4 parts, modified foaming agent 15 parts, crosslinking agent 0.66 part, 0.34 part of auxiliary crosslinking agent, 2 parts of color masterbatch; Described crosslinking agent is BIPB, and described auxiliary crosslinking agent is TAIC;

[0054] The modified foaming agent includes foaming agent OBSH (4,4'-oxobisbenzenesulfonyl hydrazide), foaming agent BIH 40, curing agent, compound foaming aid and surface treatment agent, the foaming agent The weight ratio of foaming agent OBSH, foaming agent BIH 40, curing agent, compound foaming aid and surface treatment agent is 60:40:3:5:15; The foaming aid is zinc hydroxide, stearic acid and sodium hydroxide, and the ratio of the three is 4:3:2. The surface treatment agent is paraffin oil and white oil, and the ratio of the two is 7...

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Abstract

The invention belongs to the field of macromolecule foaming materials, and particularly relates to an XPE (crosslinked polyethylene) foaming material and a preparation method thereof. The XPE foamingmaterial is prepared from the following raw materials in parts by weight: 35 to 65 parts of low density polyethylene, 26 to 36 parts of linear low density polyethylene, 5 to 30 parts of modified foaming agent, 0.5 to 1 part of crosslinking agent, 0.1 to 0.5 part of assistant crosslinker, and 1 to 3 parts of master batch, wherein the weight ratio of a foaming agent OBSH to a foaming agent BIH40 toa curing agent to a compound foaming additive to a surfactant in the modified foaming agent is 12:(6 to 10):(0.3 to 1):(0.8 to 2):(1 to 3); the total content of citric acid and carbonate in the foaming agent BIH40 is 50% or above. The invention also provides the preparation method of the XPE foaming material. The XPE foaming material has the advantages that the healthy and environment-friendly effects are realized, and the foam holes are uniform and dense.

Description

technical field [0001] The invention belongs to the field of polymer foam materials, and in particular relates to an XPE foam material and a preparation method thereof. Background technique [0002] XPE (Chemical crosslinked polyethylene foam): chemical crosslinked polyethylene foam material, which is made of low-density polyethylene resin, crosslinking agent, foaming agent and other additives after high temperature foaming High-quality materials with high strength, good stability, oil resistance, low temperature resistance, acid and alkali resistance, and chemical resistance. [0003] In the prior art, the foaming agent generally selects AC (azodicarbonamide), and AC will decompose when it reaches a certain temperature, and after decomposition, a certain amount of gas will be generated to make the material foam, but in the process of decomposition, it is often All of them will produce chemical substances with formamide groups. Formamide is slightly irritating to human skin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L23/08C08K13/02C08K5/09C08K5/21C08K5/14C08K3/22C08K3/16C08J3/22C08J3/24C08J9/10C08J9/08C08J9/16C08J9/228
CPCC08J3/226C08J3/246C08J9/0023C08J9/0061C08J9/0066C08J9/0095C08J9/08C08J9/105C08J9/16C08J9/228C08J2203/02C08J2203/04C08J2203/18C08J2323/06C08J2423/08C08K5/09C08K5/14C08K5/21C08K13/02C08K2003/168C08K2003/2227
Inventor 郑孙兴林贤州张林
Owner FUJIAN SANSHENG IND
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