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A method of converting carbon dioxide into a chemical energy substance

A kind of material and plasma technology, applied in the direction of carbon monoxide, can solve the problems of inactivation of carbon on the surface of the catalyst, the difficulty of enlarging the production capacity, and increasing the environmental load, etc., so as to improve the conversion rate of CO2 and the efficiency of electric energy use, and stabilize CO Production, the effect of high power consumption

Active Publication Date: 2019-12-13
SICHUAN YIJIE TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the two technologies have been industrialized, both rely on the heat generated by burning carbonaceous substances to drive chemical reactions, which not only produce a large amount of CO 2 emissions, increasing the environmental load, and it is impossible to achieve CO 2 The ultimate goal of reducing emissions and converting renewable electrical energy into chemical energy
CO under development 2 Catalytic reforming of methane technology also converts CO 2 , but this process has not been broken through for a long time because it is difficult to overcome the deactivation of carbon on the catalyst surface
Cracking of CO by low-temperature non-equilibrium plasma under development 2 Technologies, such as slip arc plasma and dielectric barrier plasma technology, rely entirely on high-energy electrons colliding with CO 2 If it is cracked, it is difficult for the cracked gas to react with carbon-containing substances, and there are problems such as low reaction conversion rate, large power consumption, and difficulty in expanding production capacity.

Method used

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  • A method of converting carbon dioxide into a chemical energy substance

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] Fill the coke particles in the fixed-bed reactor 8, close the reaction auxiliary gas 3, and gas 1 (Ar) with the flow velocity of 25L / min, gas 2 (CO 2 ) into 4 from 5 and 6 at a flow rate of 25L / min, turn on the plasma power supply 9, which is a DC discharge, adjust the output power to 14kW, and form a stable high-temperature CO in 4 with a temperature of 3100K 2 The plasma jet flows into the fixed-bed reactor 8, and the hot jet flows through the fixed-bed reactor 8 loaded with carbon in advance, and reacts with the carbon to generate CO, which flows out of the fixed bed. After 6 minutes, samples are taken at the gas analysis sampling point 10 for analysis and monitoring of the reaction product , and finally realize the conversion of CO with high efficiency and low energy consumption 2 For CO purposes, CO 2 The conversion rate can reach 95%, and the electric energy consumption for producing CO is 320kJ / mol (CO).

Embodiment 2

[0044] Coke particles are filled in the fixed bed reactor 8, and the gas 1 (N 2 ) at a flow rate of 25L / min, gas 2 (CO 2 ) into 4 from 5 and 6 respectively at a flow rate of 25L / min, turn on the plasma power supply 9, which is DC discharge, adjust the output power to 14kW, and form a stable temperature in 4 that is a high temperature CO of 3100K 2 Plasma jet flow out 4, flow into fixed bed reactor 8, open reaction auxiliary gas 3 (H 2 ), send hydrogen gas into the hot plasma jet at a flow rate of 25L / min and complete the reaction in the fixed bed reactor 8 to generate CO. After 6 minutes, take a sample at the gas analysis sampling point 10 to analyze and monitor the reaction product, and finally realize the high efficiency of electric energy. , low energy consumption to convert CO 2 For CO purposes, CO 2 The conversion rate can reach 60%, and the electricity consumption for producing CO is 900kJ / mol (CO).

Embodiment 3

[0046] Coke particles are filled in the fixed bed reactor 8, and the gas 1 (N 2 ) at a flow rate of 25L / min, gas 2 (CO 2 ) into 4 from 5 and 6 respectively at a flow rate of 25L / min, turn on the plasma power supply 9, which is DC discharge, adjust the output power to 14kW, and form a stable temperature in 4 that is a high temperature CO of 3100K 2 The plasma jet flows out 4, flows into the fixed bed reactor 8, and opens the reaction auxiliary gas 3 (CH 4 ), send methane into the hot plasma jet at a flow rate of 25L / min and complete the reaction in the fixed-bed reactor 8 to generate CO. After 6 minutes, take a sample at the gas analysis sampling point 10 to analyze and monitor the reaction product, and finally realize the high-efficiency electric energy , low energy consumption to convert CO 2 For CO purposes, CO 2 The conversion rate can reach 80%, and the electricity consumption for producing CO can be reduced to 400kJ / mol (CO).

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Abstract

The invention discloses a CO 2 Be converted into the method for chemical energy substance, it comprises the following steps: (1) under electric field effect, CO 2 The gas is broken down and discharged to form high-temperature CO with a temperature of 2000-5000K 2 plasma jet; the CO 2 Plasma includes uncracked CO 2 and CO 2 CO, O, O produced by cracking 2 ; (2) step (1) gained CO 2 Plasma jets further decompose CO in a fixed-bed reactor 2 Conversion to CO; the fixed bed reactor is packed with carbonaceous material or alumina particles. Very ingeniously, the present invention utilizes high temperature CO 2 The high-temperature environment of the plasma jet makes the carbon-containing substances quickly devour the oxygen in the cracked gas, and at the same time, the carbon-containing substances and uncracked CO are used 2 The reaction is converted to CO, making full use of CO 2 The thermal energy carried by the plasma jet quickly reduces the temperature, which effectively avoids the reverse reaction from the two opposite sides of lowering the temperature and reducing the oxygen element, realizes stable CO production, and greatly improves the CO production. 2 Conversion rate and power usage efficiency.

Description

technical field [0001] The present invention relates to a CO 2 A method of converting into chemical energy substances. Background technique [0002] With the continuous use of fossil energy (oil, natural gas and coal), it inevitably brings two serious problems. One is the energy crisis caused by the gradual reduction of reserves of fossil energy due to the non-renewability of fossil energy, and the other is that the extensive use of fossil energy leads to the increasing concentration of carbon dioxide in the atmosphere and causes the greenhouse effect. Therefore, sustainable energy, such as solar energy, nuclear energy, water energy, wind energy, etc. will become the main energy source in the future. However, this kind of energy is physical energy, which is usually obtained in the form of electric energy, which not only has time and space limitations in supply, but also cannot meet the needs of human society for hydrocarbon chemical raw materials. [0003] In order to sol...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B32/40
CPCC01B32/40
Inventor 印永祥沈俊杨涛刘雪松刘朋
Owner SICHUAN YIJIE TECH CO LTD
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