Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Rhombic reticular coordination polymer based on NiII and preparation method and application thereof

A coordination polymer and network technology, applied in the direction of instruments, analytical materials, measuring devices, etc., can solve the problems of high cost and poor detection effect, and achieve the effect of simple preparation method, good fluorescence activity, and large application prospects

Active Publication Date: 2018-08-17
LIAONING UNIVERSITY
View PDF10 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the detection effect of GC is very poor for some substances that are difficult to gasify and thermally unstable, and most of the aromatic nitro compounds are difficult to gasify and thermally unstable substances; at the same time, the cost of GC method and HPLC method is relatively high

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Rhombic reticular coordination polymer based on NiII and preparation method and application thereof
  • Rhombic reticular coordination polymer based on NiII and preparation method and application thereof
  • Rhombic reticular coordination polymer based on NiII and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Example 1 is based on Ni Ⅱ rhombohedral network coordination polymer

[0021] (1) Preparation method:

[0022] 1. Add 0.0143g (0.06mmol) of NiCl 2 ·6H 2 O and 0.0176g (0.06mmol) of organic aromatic diamine ligand 1,3-bis(4-aminophenoxy)benzene (L) are put into 25mL conical flask respectively, add 4mL dehydrated alcohol respectively, heat Stir to dissolve them completely; NiCl 2 Pour the absolute ethanol solution of 1,3-bis(4-aminophenoxy)benzene into the absolute ethanol solution of 1,3-bis(4-aminophenoxy)benzene, and add 5 drops of distilled water to shake and mix well; After 15 days, green small granular crystals were obtained, and then the small granular crystals were washed, filtered and dried to obtain Ni-based Ⅱ The rhombohedral network coordination polymer crude product, the productive rate is 80%.

[0023] 2. Based on Ni Ⅱ 0.02g of the crude product of rhombohedral network coordination polymer was dissolved in 3mL of ethanol solvent to obtain its saturate...

Embodiment 2

[0028] Embodiment 2 utilizes based on Ni Ⅱ Fluorescence Activity of Rhombohedral Network Coordination Polymers for Detection of Aromatic Nitro Compounds

[0029] Method: get the Ni-based Ⅱ 0.01 g of rhombohedral network coordination polymer, and ground. Add 10 mL of acetonitrile to a 10 mL volumetric flask, and then add 0.0075 g of Ni-based Ⅱ The rhombohedral network coordination polymer will contain Ni-based Ⅱ The acetonitrile solution of the rhombohedral network coordination polymer is ultrasonically dispersed to form a suspension. Take 13 parts of the suspension, put them into 13 groups of fluorescence cuvettes respectively, and then add organic solvents dichloromethane (DCM), 1,4-dioxane (Dioxane) to these 13 groups of fluorescence cuvettes respectively. ), diethyl malonate (DM), ethyl acetate (EA), ethanol (EtOH), cyclohexane (He), methanol (MeOH), petroleum ether (PE), benzene (PhH), sec-butanol (2BA), nitrobenzene (NB), 2-nitrotoluene (2NT) and 3-nitrotoluene (3NT)...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to a rhombic reticular coordination polymer based on NiII and a preparation method and application thereof. The adopted technical scheme comprises the following steps: respectively putting NiCl2.6H2O and organic aromatic diamine ligand into conical flasks, respectively adding absolute ethanol, and performing heating and stirring to enable the NiCl2.6H2O and the organic aromatic diamine ligand to be completely dissolved; then, pouring the NiCl2 solution into the organic ligand solution, adding a small amount of distilled water, and performing vibration and uniform mixing;and finally, performing sealing and perforation, standing the solution at room temperature for about 15 days to obtain green small granular crystals, and then, washing, filtering and drying the smallgranular crystals to obtain target products. Green blocky crystals suitable for an X-ray single-crystal diffraction experiment are obtained by diffusion of ethyl ether to the saturated ethanol solution of the small granular crystals. The rhombic reticular coordination polymer based on NiII, prepared by the preparation method provided by the invention, has fluorescent activity and can be used for detecting toxic solvent aromatic nitro compounds.

Description

technical field [0001] The present invention relates to a metal organic framework material, in particular to a Ni-based Ⅱ Rhombohedral network of coordination polymer materials. Background technique [0002] In the field of supramolecular chemistry, coordination polymers, also known as organometallic frameworks (MOFs), have been extensively studied as functionally diverse materials. Due to their large specific surface area, pores, and diverse topological structures, MOFs have been used in many fields, such as: nonlinear optics, superconductivity, catalysis, molecular recognition, biology, adsorption, etc. More importantly, the organic ligands in MOFs are variable, and its structure can be changed through certain group modifications, thereby changing its function. The properties and functions of rhombohedral network coordination polymers have attracted more and more attention from scientific researchers. In order to better apply rhombohedral network coordination polymer ma...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08G83/00G01N21/64
CPCC08G83/008G01N21/6402
Inventor 郭放寇盟
Owner LIAONING UNIVERSITY
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com