MnII-based belt-shaped crossed compound as well as preparation method and application thereof
A cross-fitting and ribbon-shaped technology, which is applied in the field of ribbon-shaped cross-complex materials, can solve the problems of poor detection effect and high cost, and achieve the effects of simple preparation method, good fluorescence activity, and great application prospects
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Embodiment 1
[0022] Embodiment 1 is based on Mn Ⅱ ribbon cross complex
[0023] (1) The preparation method is as follows:
[0024] 1. Mix 0.0060g (0.03mmol) of MnCl 2 4H 2 O and 0.0176g (0.06mmol) of organic aromatic diamine ligand 1,3-bis(4-aminophenoxy)benzene (L) were put into 25mL Erlenmeyer flask respectively, and MnCl 2 Add 5mL of absolute ethanol and 3mL of dichloromethane into 1,3-bis(4-aminophenoxy)benzene, heat and stir to dissolve them completely. MnCl 2 Pour the absolute ethanol solution of 1,3-bis(4-aminophenoxy)benzene into the dichloromethane solution, and add 3 drops of distilled water to shake and mix well; seal the Erlenmeyer flask and leave it at room temperature In 10 days, reddish-brown powdery crystals were obtained, and then the powdery crystals were washed, filtered and dried to obtain Ⅱ The crude product of the ribbon cross-complex, the yield was 88%.
[0025] 2, will get based on Mn Ⅱ 0.03g of the crude product of the ribbon cross-complex was dissolved in ...
Embodiment 2
[0028] Embodiment 2 utilizes based on Mn Ⅱ Fluorescence Activity of Ribboned Cross Complexes for Detection of Aromatic Nitro Compounds
[0029] Method: the Mn-based Mn prepared in Example 1 Ⅱ Ribbon cross-complex grinding. In 10mL of acetonitrile, add 0.0075mg based on Mn Ⅱ The band-shaped cross-complexes can be dispersed evenly by ultrasonic to form a suspension.
[0030] Take 13 suspensions and put them into 13 groups of fluorescence cuvettes respectively, then add organic solvents dichloromethane (DCM), 1,4-dioxane (Diox) to these 13 groups of fluorescence cuvettes respectively , diethyl malonate (DM), ethyl acetate (EA), ethanol (EtOH), cyclohexane (He), methanol (MeOH), petroleum ether (PE), benzene (PhH), sec-butanol ( 2BA), nitrobenzene (NB), 2-nitrotoluene (2NT) and 3-nitrotoluene (3NT), stirred evenly, and detected by fluorescence spectrometer. Under the condition that the excitation light wavelength is 300nm, the emission light wavelength is 366nm for detection....
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