A kind of rhombohedral network coordination polymer based on niii and its preparation method and application
A coordination polymer, mesh technology, applied in fluorescence/phosphorescence, instruments, analytical materials, etc., can solve the problems of high cost and poor detection effect, and achieve the advantages of simple preparation method, good fluorescence activity and great application prospects. Effect
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Embodiment 1
[0020] Example 1 is based on Ni Ⅱ rhombohedral network coordination polymer
[0021] (1) Preparation method:
[0022] 1. Add 0.0143g (0.06mmol) of NiCl 2 ·6H 2 O and 0.0176g (0.06mmol) of organic aromatic diamine ligand 1,3-bis(4-aminophenoxy)benzene (L) are put into 25mL conical flask respectively, add 4mL dehydrated alcohol respectively, heat Stir to dissolve them completely; NiCl 2 Pour the absolute ethanol solution of 1,3-bis(4-aminophenoxy)benzene into the absolute ethanol solution of benzene, and add 5 drops of distilled water to shake and mix well; After 15 days, green small granular crystals were obtained, and then the small granular crystals were washed, filtered and dried to obtain Ni-based Ⅱ The rhombohedral network coordination polymer crude product, the productive rate is 80%.
[0023] 2. Based on Ni Ⅱ 0.02g of the crude product of the diamond-shaped network coordination polymer was dissolved in 3mL of ethanol solvent to obtain its saturated ethanol solutio...
Embodiment 2
[0028] Embodiment 2 utilizes based on Ni Ⅱ Fluorescence Activity of Rhombohedral Network Coordination Polymers for Detection of Aromatic Nitro Compounds
[0029] Method: get the Ni-based Ⅱ 0.01 g of rhombohedral network coordination polymer, and ground. Add 10 mL of acetonitrile to a 10 mL volumetric flask, and then add 0.0075 g of Ni-based Ⅱ The rhombohedral network coordination polymer will contain Ni-based Ⅱ The acetonitrile solution of the rhombohedral network coordination polymer is ultrasonically dispersed to form a suspension. Take 13 parts of the suspension, put them into 13 groups of fluorescence cuvettes respectively, and then add organic solvents dichloromethane (DCM), 1,4-dioxane (Dioxane) to these 13 groups of fluorescence cuvettes respectively. ), diethyl malonate (DM), ethyl acetate (EA), ethanol (EtOH), cyclohexane (He), methanol (MeOH), petroleum ether (PE), benzene (PhH), sec-butanol (2BA), nitrobenzene (NB), 2-nitrotoluene (2NT) and 3-nitrotoluene (3NT)...
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