A kind of antibacterial flame-retardant hips composite material and preparation method thereof
A technology of composite materials and antibacterial agents, applied in the field of polymers, can solve problems such as inability to provide, and achieve the effect of improving the flame retardant effect and not reducing the impact performance
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[0030] A kind of preparation method according to above-mentioned antibacterial flame-retardant HIPS composite material, it is characterized in that, comprises the following steps:
[0031] (1) Put HIPS, PC, antibacterial agent, compound flame retardant, flame retardant synergist, antioxidant, processing aid into the mixer and stir for 1-3 minutes to obtain mixed raw materials;
[0032] (2) Put the mixed raw material of step 2 and the mixing product of step 1 into a twin-screw extruder for reaction, and the material stays in the barrel for 1-2min to obtain a reaction product. The twin-screw extruder The temperature of each zone is as follows: Zone 1 180-200℃, zone 2 200-220℃, zone 3 200-220℃, zone 4 200-220℃, zone 5 200-220℃, zone 6 200-220℃, zone 7 200- 220°C, eighth zone 200-220°C, nine zone 200-220°C, machine head 200-210°C.
[0033] (3) The finished product is obtained after the reaction product is cut into pellets and dried.
Embodiment 1
[0035] An antibacterial flame retardant HIPS composite material is characterized in that, in parts by mass, it includes the following raw materials: 70 parts of HIPS, 15 parts of PC, 3 parts of antibacterial agent, 7.5 parts of composite flame retardant, 4 parts of flame retardant synergist, antibacterial 2 parts of oxygen agent and 2 parts of processing aid; the composite flame retardant is obtained by compounding dibenzothiophene-4-boronic acid, polyphosphate amine, and silicone in a mass ratio of 3:3:6, and the antibacterial agent It is obtained by compounding orpiment concentrate powder and chitosan at a mass ratio of 1:3.
[0036] The antibacterial agent is obtained by adding orpigo concentrate powder into chitosan glacial acetic acid solution, stirring evenly, volatilizing the solvent, and then drying. The flame retardant synergist is antimony trioxide. Described processing aid is stearamide lubricant. The antioxidant is a polybasic hindered phenol antioxidant. The si...
Embodiment 2
[0042]An antibacterial and flame retardant HIPS composite material is characterized in that, in parts by mass, it comprises the following raw materials: 80 parts of HIPS, 10 parts of PC, 4 parts of antibacterial agent, 5 parts of composite flame retardant, 5 parts of flame retardant synergist, antibacterial 1 part of oxygen agent, 3 parts of processing aids; the composite flame retardant is obtained by compounding dibenzothiophene-4-boronic acid, polyphosphate amine, and silicone in a mass ratio of 2:4:4, and the antibacterial agent It is obtained by compounding orpiment concentrate powder and chitosan at a mass ratio of 1:4.
[0043] The antibacterial agent is obtained by adding orpigo concentrate powder into chitosan glacial acetic acid solution, stirring evenly, volatilizing the solvent, and then drying. The flame retardant synergist is antimony trioxide. The processing aid is silicone oil. The antioxidant is a polybasic hindered phenol antioxidant. The silicone is polys...
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