Composite barrier film with water and oxygen barrier function and preparation method thereof

A water-oxygen barrier and barrier film technology, applied in the field of functional polymers, can solve the problems of reducing water-oxygen barrier properties, increasing process complexity and production cost, and insufficient interface bonding force.

Active Publication Date: 2018-08-31
DONGGUAN POWERBOND NEW MATERIALS TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the practice of multiple coating or deposition of organic and inorganic layers greatly increases the complexity of the process and the production cost
In addition, the physical and chemical properties of ordinary organic layer materials and inorganic layer materials are quite different, which will cause insufficient interfacial bonding force, and easily cause some defects during the preparation of the barrier layer or during the long-term use of the device, thereby reducing the water-oxygen barrier performance.

Method used

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  • Composite barrier film with water and oxygen barrier function and preparation method thereof
  • Composite barrier film with water and oxygen barrier function and preparation method thereof
  • Composite barrier film with water and oxygen barrier function and preparation method thereof

Examples

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Effect test

Embodiment 1

[0087] A composite barrier film with a water and oxygen barrier function, comprising a first organic silicon / inorganic silicon hybrid barrier coating, an inorganic coating, a second organic silicon / inorganic silicon hybrid barrier coating and a film substrate sequentially stacked; Wherein the first organosilicon / inorganic silicon hybrid barrier coating and the second organosilicon / inorganic silicon hybrid barrier coating consist of the following components calculated in parts by weight:

[0088]

[0089] The thickness of the first organic silicon / inorganic silicon hybrid barrier coating is 0.6 μm, the thickness of the second organic silicon / inorganic silicon hybrid barrier coating is 0.6 μm, and the inorganic coating is a silicon nitride coating with a thickness of 30 nm. The film substrate is a PET substrate with a thickness of 200 μm.

[0090] The preparation method of the composite barrier film with water and oxygen barrier function comprises the following steps:

[009...

Embodiment 2

[0097] A composite barrier film with water and oxygen barrier function, its composition and preparation method are basically the same as in Example 1, the only difference is that the polyfunctional cage polysilsesquioxane used in Example 2 is B.

Embodiment 3

[0099] A composite barrier film with water and oxygen barrier function, its composition and preparation method are basically the same as in Example 1, the only difference is that the polyfunctional cage polysilsesquioxane used in Example 3 is C.

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Abstract

The invention discloses a composite barrier film with a water and oxygen barrier function and a preparation method thereof. The composite barrier film comprises a first organic silicon / inorganic silicon hybrid barrier coating, an inorganic plating layer, a second organic silicon / inorganic silicon hybrid barrier coating and a film base material which are sequentially stacked, wherein the first organic silicon / inorganic silicon hybrid barrier coating and the second organic silicon / inorganic silicon hybrid barrier coating are prepared from, by weight, 30-70 parts of multifunctional cage type polysilsesquioxane, 25-65 parts of organic silicon resin, 0-15 parts of organic silicon-modified (methyl) acrylic resin, 0.2-5 parts of photoinitiator and 5-15 parts of auxiliaries. The composite barrierfilm has the excellent water steam and oxygen barrier effect and the good bending resistance, the thickness is small, the number of layers is small, the prepared composite barrier film is short in production time and low in cost, and the coating barrier function stability and reliability are high.

Description

technical field [0001] The invention relates to the field of functional polymers, in particular, the invention relates to a composite barrier film with water and oxygen barrier function. Background technique [0002] In recent years, the vigorous development of optoelectronic technology has made organic light-emitting components (OLED), quantum dot displays (QuantumDots), organic solar cells (OPV), flexible liquid crystal screens (flexible LCD), electronic paper (E-paper), etc. will be in the future. The market occupies a considerable market share. In displays, in order to meet the above-mentioned requirements of modern technology for electronic products, it has become a development trend of optoelectronic technology to replace traditional glass substrates with plastic substrates as optoelectronic element substrates. Plastic substrates can not only provide thinner and more flexible features, but also improve the shortcomings of traditional glass substrates that are easy to ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J7/04C08L67/02C08L61/16C08L79/08C08L69/00C09D183/04C09D133/00C09D7/65C09D7/61C09D7/48C23C14/24C23C14/06
CPCC08J2361/16C08J2367/02C08J2369/00C08J2379/08C08J2433/00C08J2483/04C08L2205/025C08L2205/03C09D183/04C23C14/0652C23C14/0676C23C14/24C09D7/48C09D7/61C09D7/65C08J7/0423C08L83/04C08L75/14C08K3/36C08K5/526
Inventor 吴博成浩冠刘兆辉
Owner DONGGUAN POWERBOND NEW MATERIALS TECH DEV
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