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Anti-layering gel electrolyte for lead-acid storage battery and manufacturing method thereof

A colloidal electrolyte and lead-acid battery technology, applied in the direction of lead-acid batteries, can solve the problems of lead-acid battery capacity decline, end, hard top and soft battery life, etc., to reduce growth, inhibit passivation, and prolong service life Effect

Inactive Publication Date: 2018-09-04
TIANNENG GRP HENAN ENERGY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] During the circulation process of the electrolyte provided by the above disclosed patents, the metal oxides of the positive and negative electrodes become different in hardness and softness as the electrolyte changes in temperature and pressure. This kind of situation is called plate delamination in the industry. Ultimately, the polar plate is hard and soft at the bottom, which leads to the premature end of battery life; and the stratification of the electrolyte and the difference in density between the upper and lower sides are one of the main reasons for the sharp decline in the capacity of lead-acid batteries at low temperatures

Method used

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  • Anti-layering gel electrolyte for lead-acid storage battery and manufacturing method thereof
  • Anti-layering gel electrolyte for lead-acid storage battery and manufacturing method thereof
  • Anti-layering gel electrolyte for lead-acid storage battery and manufacturing method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0031] Dissolve 0.55g of polyaspartic acid sodium salt in 5kg of deionized water, the stirring speed is 1200r / min, and the stirring time is 1min to obtain solution A; add 30.5g of lithium sulfate and heat up to 60°C, stop heating, and the stirring speed is 1200r / min, the stirring time is 10min to obtain solution B; add 4.1g methyl cellulose, the temperature is controlled at 50°C; the stirring speed is 4500r / min, the line speed is 15m / s, and the stirring time is 10min, to obtain solution C; add 45kg deionized water, the solution reaches room temperature, the stirring speed is 3500r / min, the linear speed is 15m / s, and the stirring time is 10min to obtain solution D, and 175g fumed silica is added to solution D while stirring, and the stirring speed is 3000r / min. The linear speed is 15m / s, the stirring time is 10min to obtain solution E, continue to stir for 30min after the addition is completed, slowly add 18kg of sulfuric acid to solution E, continue to stir for 30min after the ...

Embodiment 2

[0034] Dissolve 0.7g of polyaspartic acid sodium salt in 5kg of deionized water, the stirring speed is 1700r / min, and the stirring time is 10min to obtain solution A; add 32g of lithium sulfate and raise the temperature to 80°C, stop heating, and the stirring speed is 1700r / min, stirring time is 20min to obtain solution B; add 5.5g methyl cellulose, temperature control 60 ℃; stirring speed is 6000r / min, line speed 30m / s, stirring time is 120min, obtain solution C; add 45kg to Ionized water, the solution reaches room temperature, the stirring speed is 5000r / min, the line speed is 20m / s, and the stirring time is 20min to obtain solution D, and 375g fumed silica is added to solution D while stirring, the stirring speed is 4000r / min, and the line The speed was 20m / s, and the stirring time was 15min to obtain solution E. After the addition was completed, continue to stir for 50min. Slowly add 20.5kg of sulfuric acid to solution E. After the addition was completed, continue to stir ...

Embodiment 3

[0037]Dissolve 0.5g of polyaspartic acid sodium salt in 5kg of deionized water, the stirring speed is 1500r / min, and the stirring time is 8min to obtain solution A; add 31g of lithium sulfate and raise the temperature to 70°C, stop heating, and the stirring speed is 1500r / min, the stirring time is 15min to obtain solution B; add 5g of methyl cellulose, the temperature is controlled at 55°C; the stirring speed is 5000r / min, the line speed is 20m / s, and the stirring time is 15min, to obtain solution C; add 45kg deionized Water, the solution reaches room temperature, the stirring speed is 4000r / min, the line speed is 17m / s, and the stirring time is 15min to obtain solution D, and 300g fumed silica is added to solution D while stirring, the stirring speed is 3500r / min, and the line speed is 17m / s s, the stirring time is 13min to obtain solution E, continue to stir for 40min after the addition is completed, slowly add 38kg of sulfuric acid to solution E, continue to stir for 60min ...

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Abstract

The invention belongs to the technical field of lead-acid storage battery production, and particularly relates to an anti-layering gel electrolyte for a lead-acid storage battery and a manufacturing method thereof. The anti-layering gel electrolyte for the lead-acid storage battery is prepared by the steps of firstly preparing raw materials including 36 percent of sulfuric acid, 0.45 percent of fumed silica, 0.06 to 0.065 percent of lithium sulfate, 0.008 to 0.012 percent of methylcellulose, 0.001 to 0.0015 percent of polyaspartic acid amide sodium salt and the balance of deionized water. Thegel electrolyte provided by the invention can reduce the pole plate softening due to electrolyte layering due to season change; the generation of thick lead sulfate crystals can be inhibited; the poleplate sulfation rate is decelerated; good gel performance and thixotropy are realized; the disposable glue filling can be realized by using the existing industrial vacuum glue filling machine.

Description

technical field [0001] The invention belongs to the technical field of lead-acid storage battery production, and in particular relates to an anti-delamination colloidal electrolyte for a lead-acid storage battery and a manufacturing method thereof. Background technique [0002] Due to its reliability, wide applicability, good performance and low price, lead-acid batteries have always been the mainstream secondary battery products in China and even in the world. The main components of lead-acid batteries include: positive and negative plates, glass fiber separators, battery tanks, battery covers, electrolyte (dilute sulfuric acid), lead-out terminals, safety valves, etc. As the main component of the lead-acid battery, the electrolyte not only maintains the ion transfer in the battery, but also participates in the electrochemical reaction. Its performance has a direct impact on the electrochemical performance and cycle life of the lead-acid battery. [0003] CN1750312A disclo...

Claims

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Application Information

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IPC IPC(8): H01M10/08
CPCH01M10/08Y02E60/10
Inventor 庞明朵欧阳万忠赵兴强常传杰
Owner TIANNENG GRP HENAN ENERGY TECH
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