The invention discloses an aluminum silicate ceramic fiber structural adhesive film; aluminum silicate ceramic fibers are immersed into a macromolecular adhesive solution, and the structural adhesivefilm is obtained through traction, drying, solvent recovery, cutting and crimping processes; the aluminum silicate ceramic fibers are aluminum silicate ceramic fiber paper, aluminum silicate ceramic fiber cloth or aluminum silicate ceramic fibrofelt with the thickness of 0.2 mm-1.5 mm. The aluminum silicate ceramic fiber structural adhesive film has good flexibility, no fragile cracking in any bending, no chromium layer, and no need of isolating paper or isolating film in folding or coiling of the adhesive film, can be curled and preserved, does not adhere at medium and low temperature, is cured at high temperature, has the advantages of convenient storage, good high temperature resistance, good toughness of the cured adhesive film, high peeling strength greater than 90 N/2.5 cm, shear strength on 45# steel more than 45 MPa, and good aging resistance, and can be applied in the bonding manufacturing of structural components of high-end equipment such as aerospace, national defense and military industry.