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Supergravity enhanced extraction-catalysis o 3 / ti 4+ Method and device for treating high-concentration nitrobenzene wastewater

A nitrobenzene wastewater and supergravity technology, applied in the direction of extraction water/sewage treatment, oxidized water/sewage treatment, water/sludge/sewage treatment, etc., can solve the problems of low ozone solubility, limited ozone application, and high treatment costs , to achieve the effects of simple process flow, reduced water treatment cost, and improved treatment efficiency

Active Publication Date: 2021-08-17
ZHONGBEI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

(2) The addition of catalysts improves the degradation efficiency of organic matter, but the rate-controlling step of degrading wastewater is the mass transfer of ozone at the gas-liquid interface, and the solubility of ozone in water is low, which still limits the application of ozone
At the same time, for high-concentration nitrobenzene wastewater, the single use of various methods has problems such as poor treatment effect or high treatment cost.

Method used

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  • Supergravity enhanced extraction-catalysis o  <sub>3</sub> / ti  <sup>4+</sup> Method and device for treating high-concentration nitrobenzene wastewater
  • Supergravity enhanced extraction-catalysis o  <sub>3</sub> / ti  <sup>4+</sup> Method and device for treating high-concentration nitrobenzene wastewater
  • Supergravity enhanced extraction-catalysis o  <sub>3</sub> / ti  <sup>4+</sup> Method and device for treating high-concentration nitrobenzene wastewater

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Example 1: 1 L of nitrobenzene wastewater with a concentration of 1000 mg / L was treated by the extraction method. The configured nitrobenzene waste water and extractant cyclohexane were respectively placed in two storage tanks, compared to (V 环己烷 :V 废水 ) is 1:2, speed N=500r / min, waste water flow Q a =60L / h, pH=5, temperature T=25°C, and two liquids with an impact initial velocity of 9.45m / s to carry out a cross-flow extraction in an impinging flow-rotating packed bed. The results showed that the content of nitrobenzene in the wastewater (raffinate phase) was reduced to 62.49 mg / L, the removal rate of nitrobenzene reached 93.75%, and the extraction efficiency was 98.18%. Under similar experimental conditions, the extraction experiment was carried out in the impinging flow extractor. The removal rate of nitrobenzene was 81.68%, and the extraction stage efficiency was 83.33%, which were respectively reduced by 12.07% and 14.85% compared with the impinging flow-rotating ...

Embodiment 2

[0031] Example 2: 1 L of nitrobenzene wastewater with a concentration of 1500 mg / L was treated by the extraction method. The configured nitrobenzene waste water and extractant cyclohexane were respectively placed in two storage tanks, compared to (V 环己烷 :V 废水 ) is 1:1, speed N=400r / min, waste water flow Q a =50L / h, pH=7, temperature T=25℃, and two liquids with an impact velocity of 7.88 m / s for a cross-flow extraction in an impinging flow-rotating packed bed. The results showed that the content of nitrobenzene in the wastewater (raffinate phase) was reduced to 75.06mg / L, the removal rate of nitrobenzene reached 94.93%, and the extraction efficiency was 99.99%. Under similar experimental conditions, the extraction experiment was carried out in the impinging flow extractor. The removal rate of nitrobenzene was 80.88%, and the extraction efficiency was 82.03%, which were respectively reduced by 14.05% and 17.96% compared with the impinging flow-rotating packed bed. Using RPB-O...

Embodiment 3

[0032] Example 3: 1 L of nitrobenzene wastewater with a concentration of 2000 mg / L was treated by the extraction method. The configured nitrobenzene waste water and extractant cyclohexane were respectively placed in two storage tanks, compared to (V 环己烷 :V 废水 ) is 2:1, speed N=300r / min, waste water flow Q a = 40L / h, pH = 9, temperature T = 25°C, and the two liquids collided at an initial velocity of 6.3m / s to perform a cross-flow extraction in an impinging flow-rotating packed bed. The results showed that the content of nitrobenzene in the wastewater (raffinate phase) was reduced to 125.85 mg / L, the removal rate of nitrobenzene reached 93.71%, and the extraction efficiency was 98.68%. Under similar experimental conditions, the extraction experiment was carried out in the impinging flow extractor. The removal rate of nitrobenzene was 79.43%, and the extraction efficiency was 81.56%, which were respectively reduced by 14.28% and 17.12% compared with the impinging flow-rotating...

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Abstract

The invention belongs to the technical field of nitrobenzene wastewater treatment. In order to solve the deficiencies in the existing methods for treating nitrobenzene wastewater, a kind of supergravity enhanced extraction-catalysis O is proposed. 3 / Ti 4+ A method for treating high-concentration nitrobenzene wastewater. Treat high-concentration nitrobenzene wastewater by extraction to reduce the concentration of nitrobenzene in the wastewater, and then use O 3 / Ti 4+ The nitrobenzene concentration in the high-concentration nitrobenzene wastewater is 1000-2000mg / L, and the extractant used is cyclohexane, compared with V 环己烷 :V 废水 1:2~2:1, pH 5~9, temperature 25°C, liquid flow 40~60L / h. The treatment efficiency is increased by 20%-30%, and the time is shortened by 30%-40%, which greatly reduces the cost of water treatment. The process is simple and easy to operate, and it can be applied to various organic industrial wastewater such as explosive wastewater, phenolic wastewater, dye wastewater, pharmaceutical wastewater, etc.

Description

technical field [0001] The invention belongs to the technical field of nitrobenzene wastewater treatment, and in particular relates to a process method for treating high-concentration nitrobenzene wastewater, which adopts the coupling treatment of supergravity technology, extraction and catalytic ozonation technology. Background technique [0002] Nitrobenzene is often used as an intermediate in organic synthesis and is widely used in chemical, fuel, material, coking and other industries. However, the substituent nitro in nitrobenzene is an electron-withdrawing group, its chemical properties are relatively stable, it is not easy to be biodegraded, and it can stably exist in water. Once it enters the environment, it can cause abnormal symptoms of animal nervous system, anemia, liver disease, etc. It has been listed as one of the 68 key pollutants in my country. [0003] At present, domestic methods for treating such wastewater mainly include physical, chemical and biological...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/04C02F101/38
CPCC02F1/26C02F1/725C02F1/78C02F2101/38C02F2201/002C02F2209/02C02F2209/06C02F2209/08C02F2209/38C02F2209/40
Inventor 焦纬洲刘有智杨鹏飞
Owner ZHONGBEI UNIV