Strategic petroleum reserve tank steel plate based on oxide metallurgy and manufacturing method thereof
A manufacturing method and oxide technology, applied in the field of metallurgy, can solve the problem of difficulty in ensuring the quality and performance requirements of HAZ, and achieve the effects of improving low temperature impact toughness and strength
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Embodiment 1
[0041] Converter-LF-VD-continuous casting process is used to make 260mm continuous casting slab; the chemical composition of continuous casting slab contains C0.07%, Si 0.16%, Mn 1.45%, P 0.010%, S 0.003%, Ni 0.16 in mass percentage %, Cu0.18%, B 0.002%, Cr0.10%, Mo 0.08%, Nb 0.02%, Al 0.01%, N 0.004%, O 0.003%, Ti 0.015%, Mg0.003%, RE 0.001%, Ca 0.003%, the balance is Fe; its carbon equivalent C eq =C+Mn / 6+(Cr+Mo+V) / 5+(Ni+Cu) / 15=0.07+1.45 / 6+(0.1+0.08+0) / 5+(0.16+0.18) / 15=0.37 ; When the molten steel arrives at the LF furnace for refining, the oxide metallurgy process is used to control the oxygen content ≤ 150ppm through silicon and manganese deoxidation, and then Ti, Mg, RE and Ca are added. The interval between the addition of the above components is ≤ 10min, and then the LF furnace Slagging, desulfurization and alloying, when the LF furnace refining is completed, control the slag to contain FeO+MnO≤1.5% by mass percentage;
[0042] After the continuous casting slabs are s...
Embodiment 2
[0054] Method is with embodiment 1, and difference is:
[0055] (1) The composition of the continuous casting billet contains C 0.08%, Si 0.20%, Mn 1.5%, P 0.010%, S0.003%, Ni 0.18%, B 0.002%, Cr 0.05%, Mo 0.1%, Nb by mass percentage 0.03%, Cu 0.08%, Al 0.02%, N 0.007%, O 0.006%, Ti 0.018%, Zr 0.010%, RE 0.001%, Ca 0.003%, the balance is Fe; C eq =C+Mn / 6+(Cr+Mo+V) / 5+(Ni+Cu) / 15=0.08+1.5 / 6+(0.05+0.1+0) / 5+(0.18+0.08) / 15=0.38 ;
[0056] (2) When refining in the LF furnace, add Ti, Zr, RE and Ca after controlling the oxygen content to ≤150ppm;
[0057] (3) The yield strengths of three groups of steel plates for strategic oil storage tanks based on oxide metallurgy are 572MPa, 546MPa and 498MPa, the tensile strengths are 636MPa, 630MPa and 626MPa, the yield ratios are 0.90, 0.87 and 0.81, and the elongation They are 21%, 23% and 23% respectively, and the impact energy at -20°C is 239J, 258J and 189J respectively;
Embodiment 3
[0059] Method is with embodiment 1, and difference is:
[0060] (1) The thickness of the continuous casting slab is 300mm; the composition of the continuous casting slab contains C 0.09%, Si 0.3%, Mn 1.2%, P 0.011%, S 0.006%, Ni 0.20%, B 0.003%, Cr 0.3% by mass percentage %, Mo 0.08%, Nb 0.03%, Cu0.16%, N 0.007%, O 0.001%, Ti 0.022%, Zr 0.010%, Mg 0.003%, Ca 0.002%, Al0.025%; the balance is Fe; C eq =C+Mn / 6+(Cr+Mo+V) / 5+(Ni+Cu) / 15=0.09+1.2 / 6+(0.3+0.08+0) / 5+(0.2+0.16) / 15=0.39 ;
[0061] (2) When refining in the LF furnace, after controlling the oxygen content to ≤150ppm, add Ti, Zr, Mg and Ca;
[0062] (3) The yield strengths of three groups of steel plates for strategic oil storage tanks based on oxide metallurgy are 568MPa, 556MPa and 499MPa, the tensile strengths are 636MPa, 632MPa and 626MPa, the yield ratios are 0.89, 0.88 and 0.80, and the elongations are respectively 21%, 23% and 24%, and the impact energy at -20°C is 219J, 238J and 259J, respectively.
[0063] The st...
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