Method for solving wrinkle of dried separator of lithium ion battery

A lithium-ion battery and diaphragm wrinkle technology, which is applied to secondary batteries, battery pack components, circuits, etc., can solve the problems that affect the large-scale use of dry-process diaphragms, increase the cost of battery production, and cannot eliminate wrinkles in time, and achieve the goal of processing The effect of wide selection of solvents, low investment in equipment, and wide selection of solvents

Inactive Publication Date: 2018-11-06
TIANJIN ENERGIES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the problem of wrinkling of dry-process diaphragms is relatively common, and it also affects the large-scale use of dry-process diaphragms to a certain extent.
The main reason is that the dry-process separator is anisotropic, and the stress release is uneven during the electrolyte infiltration process and cannot be eliminated in time to cause wrinkles
In order to improve the wrinkle problem of the dry-process separator, the separator production plant adopts raw material adjustment, heat treatment, and stretching process optimization to improve the tension problem, but the improvement effect of uneven tension release after the separator contacts the electrolyte is not obvious; each battery factory mainly uses the gel technology to improve the tension problem. The bonding of the diaphragm and the pole piece prevents stress release. Firstly, the polymer coating is introduced, which increases the manufacturing cost of the diaphragm. Second, the hot pressing process with strict temperature control is introduced, which increases the battery manufacturing cost. Finally, the polymer coating increases the internal resistance of the battery. Electrical properties are also adversely affected

Method used

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  • Method for solving wrinkle of dried separator of lithium ion battery
  • Method for solving wrinkle of dried separator of lithium ion battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A method for solving the wrinkles of the lithium-ion battery dry-method diaphragm, including the following steps: pour ethyl methyl carbonate into a treatment tank, the treatment tank has a width of 3m, a length of 8m, and a depth of 3m, and maintains the temperature of the treatment pool at 70°C and the height of the liquid level 2m, the diaphragm is made of PP uniaxially stretched film with a thickness of 16μm; in the solvent treatment process, before the diaphragm is slit, the state of the diaphragm is treated as a parent roll, the diaphragm is immersed in ethyl methyl carbonate, and the diaphragm is passed at a speed of 10m / min In the treatment tank, the total treatment time is 3 minutes, and then it is dried at a drying temperature of 100°C. After the diaphragm is dried and rolled, it is cooled and allowed to stand for 12 hours, and finally cut.

[0037] The battery cathode material selects nickel cobalt lithium manganate ternary cathode material, the conductive agent ...

Embodiment 2

[0040] A method for solving the wrinkles of lithium-ion battery dry-method separators, including the following steps: pour ethyl methyl carbonate and dimethyl carbonate (the mass ratio of ethyl methyl carbonate to dimethyl carbonate is 1:1) The treatment tank has a width of 3m, a length of 8m, and a depth of 3m. The treatment tank is maintained at 70°C and 2m. The membrane is made of PP uniaxially stretched film with a thickness of 16μm. The solvent treatment process is before the separation of the membrane. The processing membrane is in the mother roll. The diaphragm is immersed in ethyl methyl carbonate, and the diaphragm is passed through the treatment tank at a speed of 10m / min for a total treatment time of 3 minutes, and then dried at a drying temperature of 100°C. After the diaphragm is dried and rolled, it is cooled and left for 12 hours. Finally, slitting.

[0041] The formula and preparation method of the positive electrode and the negative electrode of the battery are t...

Embodiment 3

[0043] A method for solving the wrinkles of lithium-ion battery dry-method separators, including the following steps: pour ethyl methyl carbonate and dimethyl carbonate (the mass ratio of ethyl methyl carbonate to dimethyl carbonate is 1:1) Cell, treatment cell width is 0.5m, length is 1m, depth is 1m, and the treatment cell is maintained at 80℃ and the liquid level is 0.5m. The diaphragm is made of PP uniaxially stretched film with a thickness of 16μm. The solvent treatment process is before the battery zigzag laminate , Process the diaphragm as a finished roll, immerse the diaphragm in ethyl methyl carbonate, and make the diaphragm pass through the processing tank at a speed of 40m / min. The total processing time is 45s, and then it is dried at a drying temperature of 90℃, and it is taken out of the oven for Z The font stack is available.

[0044] The formula and preparation method of the positive electrode and the negative electrode of the battery are the same as in Example 1. ...

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Abstract

The invention provides a method for solving wrinkle of a dried separator of a lithium ion battery. The method comprises a first scheme or a second scheme. The first scheme comprises the following steps of pouring a solvent into a processing pool, maintaining constant temperature of the processing pool and constant height of a liquid level, immersing the separator before cutting in the solvent, allowing the separator to pass through the processing pool at a constant speed, performing drying, and obtaining after drying is completed. The second scheme comprises the following steps of pouring thesolvent into the processing pool, maintaining constant temperature of the processing pool and constant height of the liquid level, immersing a battery lamination piece or the separator before windingin the solvent, allowing the separator to pass through the processing pool at the constant speed, performing drying, and obtaining after drying is completed. The solvents in the first scheme and the second scheme are same or different. The method for solving the wrinkle of the dried separator of the lithium ion battery is relatively wide in processing time and temperature control range, the selection surface of the processing solvent is relatively wide, the solvent can be recycled, and the process is simple and is relatively mature.

Description

Technical field [0001] The invention belongs to the field of lithium ion batteries, and in particular relates to a method for solving the wrinkles of lithium ion battery dry-process diaphragms. Background technique [0002] In recent years, with the increasing awareness of global energy conservation and environmental protection, new energy vehicles, which represent the direction of future automobile development, are gradually being accepted by consumers, and the development of the industry has gradually become more formal. In order to ensure that new energy vehicles have long-term market competitiveness, improving quality and reducing costs is still the direction that the entire industry needs to work together. As the core component of new energy vehicles, the cost control of power battery is particularly important. As one of the four main materials, the diaphragm material has a greater impact on the overall price of the battery. Among them, the dry diaphragm has high processing ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M2/14H01M10/0525
CPCH01M10/0525H01M50/403Y02E60/10
Inventor 张敏高秀玲申津婧
Owner TIANJIN ENERGIES
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