Formate compound extracting agent for weathering crust elution-deposited rare earth ore
A weathering crust leaching type, formate salt technology, applied in the direction of improving process efficiency, can solve the problems affecting the rare earth precipitation recovery process, reduce the quality of rare earth products, increase the cost of impurity removal, etc., to achieve high-efficiency and low-impurity leaching, shorten The effect of leaching time and low cost
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Embodiment 1
[0017] For a difficult-permeable weathering crust leaching-type rare earth ore in Guangdong, the average grade of rare earth is 0.17%, using the formate compound leaching agent of the present invention, adopting column leaching to simulate actual production to extract rare earth, the leaching includes the following steps:
[0018] Under the simulated actual production conditions of column leaching weathering crust leaching type rare earth ore, ammonium sulfate solution (concentration 0.1mol / L) and ammonium formate solution (concentration 0.008mol / L) compound leaching agent, with 2.0mol / L dilute sulfuric acid Adjust the pH of the solution to 5.5, inject the leachant solution into the rare earth ore according to the ratio of the mass ratio of the leachant solution to the rare earth ore at 2:1, and obtain the rare earth leachate by leaching.
[0019] The time for rare earth leaching to reach equilibrium is 627 minutes, which is 225 minutes shorter than that of the traditional ammo...
Embodiment 2
[0021] For a difficult-permeable weathering crust leaching-type rare earth ore in Guangdong, the average grade of rare earth is 0.17%, using the formate compound leaching agent of the present invention, adopting column leaching to simulate actual production to extract rare earth, the leaching includes the following steps:
[0022] Under the simulated actual production conditions of column leaching weathering crust leaching type rare earth ore, ammonium sulfate solution (concentration 0.1mol / L) and sodium formate solution (concentration 0.02mol / L) compound leaching agent, adjusted with 2.0mol / L dilute sulfuric acid The pH of the solution is 5.5, and the mass ratio of the leaching agent solution to the rare earth ore is 2:1, inject the leaching agent solution into the rare earth ore, and obtain the rare earth leaching solution by leaching.
[0023] The time for rare earth leaching to reach equilibrium is 585 minutes, which is 267 minutes shorter than that of the traditional ammon...
Embodiment 3
[0025] For a difficult-permeable weathering crust leaching-type rare earth ore in Guangdong, the average grade of rare earth is 0.17%, using the formate compound leaching agent of the present invention, adopting column leaching to simulate actual production to extract rare earth, the leaching includes the following steps:
[0026] Under the simulated actual production conditions of column leaching weathering crust leaching type rare earth ore, ammonium chloride solution (concentration 0.2mol / L) and potassium formate solution (concentration 0.03mol / L) compound leaching agent, dilute with 2.0mol / L Sulfuric acid is used to adjust the pH of the solution to 6, and the leachant solution is injected into the rare earth ore according to the mass ratio of the leaching agent solution to the rare earth ore at a ratio of 2:1, and the rare earth leaching solution is obtained by leaching.
[0027] The time for rare earth leaching to reach equilibrium is 533 minutes, which is 319 minutes shor...
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