Formate compound extracting agent for weathering crust elution-deposited rare earth ore

A weathering crust leaching type, formate salt technology, applied in the direction of improving process efficiency, can solve the problems affecting the rare earth precipitation recovery process, reduce the quality of rare earth products, increase the cost of impurity removal, etc., to achieve high-efficiency and low-impurity leaching, shorten The effect of leaching time and low cost

Inactive Publication Date: 2018-11-16
WUHAN INSTITUTE OF TECHNOLOGY
View PDF6 Cites 5 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The accompanying impurity metal aluminum ions in the leaching solution will increase the cost of impurity removal, directly affect the subsequent precipitation recovery process of rare earth, and reduce the quality of rare earth products

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] For a difficult-permeable weathering crust leaching-type rare earth ore in Guangdong, the average grade of rare earth is 0.17%, using the formate compound leaching agent of the present invention, adopting column leaching to simulate actual production to extract rare earth, the leaching includes the following steps:

[0018] Under the simulated actual production conditions of column leaching weathering crust leaching type rare earth ore, ammonium sulfate solution (concentration 0.1mol / L) and ammonium formate solution (concentration 0.008mol / L) compound leaching agent, with 2.0mol / L dilute sulfuric acid Adjust the pH of the solution to 5.5, inject the leachant solution into the rare earth ore according to the ratio of the mass ratio of the leachant solution to the rare earth ore at 2:1, and obtain the rare earth leachate by leaching.

[0019] The time for rare earth leaching to reach equilibrium is 627 minutes, which is 225 minutes shorter than that of the traditional ammo...

Embodiment 2

[0021] For a difficult-permeable weathering crust leaching-type rare earth ore in Guangdong, the average grade of rare earth is 0.17%, using the formate compound leaching agent of the present invention, adopting column leaching to simulate actual production to extract rare earth, the leaching includes the following steps:

[0022] Under the simulated actual production conditions of column leaching weathering crust leaching type rare earth ore, ammonium sulfate solution (concentration 0.1mol / L) and sodium formate solution (concentration 0.02mol / L) compound leaching agent, adjusted with 2.0mol / L dilute sulfuric acid The pH of the solution is 5.5, and the mass ratio of the leaching agent solution to the rare earth ore is 2:1, inject the leaching agent solution into the rare earth ore, and obtain the rare earth leaching solution by leaching.

[0023] The time for rare earth leaching to reach equilibrium is 585 minutes, which is 267 minutes shorter than that of the traditional ammon...

Embodiment 3

[0025] For a difficult-permeable weathering crust leaching-type rare earth ore in Guangdong, the average grade of rare earth is 0.17%, using the formate compound leaching agent of the present invention, adopting column leaching to simulate actual production to extract rare earth, the leaching includes the following steps:

[0026] Under the simulated actual production conditions of column leaching weathering crust leaching type rare earth ore, ammonium chloride solution (concentration 0.2mol / L) and potassium formate solution (concentration 0.03mol / L) compound leaching agent, dilute with 2.0mol / L Sulfuric acid is used to adjust the pH of the solution to 6, and the leachant solution is injected into the rare earth ore according to the mass ratio of the leaching agent solution to the rare earth ore at a ratio of 2:1, and the rare earth leaching solution is obtained by leaching.

[0027] The time for rare earth leaching to reach equilibrium is 533 minutes, which is 319 minutes shor...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a formate compound extracting agent for weathering crust elution-deposited rare earth ore. The formate compound extracting agent contains formate solution and ammonium salt solution. Compared with the extracting effect of a traditional extracting agent, the formate compound extracting agent is capable of accelerating a seepage velocity of the extracting agent in an ore body, effectively shortening extraction time of rare earth in the preconditions without affecting a rare earth extracting rate, and effectively inhibiting the extracting of impurity aluminum, beneficial to follow-up impurity-removing working procedures of rare earth mother liquor, and capable of realizing the efficient low-impurity extracting of the weathering crust elution-deposited rare earth ore. The formate compound extracting agent is non-toxic in formate raw material, less in addition amount, low in cost, biodegradable, green and environment-friendly.

Description

technical field [0001] The invention belongs to the field of hydrometallurgy, and in particular relates to a formate composite leaching agent for weathering crust leaching type rare earth ores. Background technique [0002] The weathering crust elution-type rare earth ore is rich in medium and heavy rare earths with high commercial value, and has great economic and strategic value. The mining of this mine has been highly valued at home and abroad. Weathering crust leaching type rare earth ores are composed of rare earth-containing granite and volcanic rocks, which are weathered to form kaolinite, halloysite, montmorillonite and illite through biological, chemical and physical actions in a warm and humid climate. At the same time, the easily weathered rare earth minerals in the original rock are weathered and dissociated to form rare earth hydrated ions or hydroxyl hydrated ions adsorbed on the clay minerals, forming a weathered crust leaching type rare earth ore. In industr...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C22B59/00C22B3/16
CPCC22B3/1658C22B59/00Y02P10/20
Inventor 周芳冯健池汝安徐源来余军霞刘琦
Owner WUHAN INSTITUTE OF TECHNOLOGY
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products