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A kind of aramid fiber electrode and preparation method thereof

An aramid fiber and electrode technology, applied in the field of aramid fiber electrode and its preparation, can solve the problems of deterioration, coating layer peeling performance, poor adhesion, etc., and achieve high tensile strength, high energy density, and good flexibility. Effect

Active Publication Date: 2020-02-11
SUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the capacitive material is coated, the polymer fiber does not contribute to the capacitive performance, so the specific capacitance of the polymer fiber electrode and the energy density of the capacitor are generally low
Second, the adhesion between the inorganic coating and the fiber matrix is ​​poor, and the coating may fall off after multiple deformations or electrochemical cycles, resulting in performance degradation, resulting in poor wearability of fiber capacitors.
Third, the mechanical properties of existing polymer fiber capacitors cannot meet the requirements
However, as with other polymer fiber capacitors, the capacitive performance of aramid fiber capacitors and the adhesion to inorganic coatings remain to be resolved.

Method used

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  • A kind of aramid fiber electrode and preparation method thereof
  • A kind of aramid fiber electrode and preparation method thereof
  • A kind of aramid fiber electrode and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0063] (1) Dissolve 0.1g dopamine hydrochloride and 0.05g trishydrochloride in 100mL water to obtain solution A; dissolve 0.1g sodium hydroxide in 100mL water to obtain aqueous sodium hydroxide solution; use sodium hydroxide Adjust the pH value of solution A to 8.5 with an aqueous solution to obtain solution B; immerse 0.1 g of poly-p-phenylene terephthalamide fiber bundles in solution B, and vibrate at room temperature for 5 hours; after the reaction, the fibers are taken out, cleaned and Dried to obtain polydopamine-coated aramid fiber bundles;

[0064] (2) Dissolve 0.5g silver nitrate in 50mL water, add ammonia water drop by drop until the silver ammonia solution is clarified again, add 0.05g polyvinylpyrrolidone to obtain solution C; dissolve 1g glucose in 50mL water to obtain glucose aqueous solution; Add 0.1g polydopamine-coated aramid fiber bundles to the mixture, shake at room temperature, and add glucose aqueous solution dropwise, and continue to shake at room tempera...

Embodiment 2

[0070](1) Dissolve 0.2g of dopamine hydrochloride and 0.16g of trishydrochloride in 100mL of water to obtain solution A; dissolve 2g of sodium hydroxide in 100mL of water to obtain an aqueous solution of sodium hydroxide; Adjust the pH value of solution A to 8.5 to obtain solution B; immerse 0.5 g of poly-p-phenylene terephthalamide fiber bundles in solution B, shake at room temperature for 24 hours; take out the fibers after the reaction, wash and dry , to obtain polydopamine-coated aramid fiber bundles;

[0071] (2) Dissolve 1.5g silver nitrate in 50mL water, add ammonia water drop by drop until the silver ammonia solution is clarified again, add 0.25g polyvinylpyrrolidone to obtain solution C; dissolve 3g glucose in 50mL water to obtain glucose aqueous solution; Add 0.5g polydopamine-coated aramid fiber bundles to the mixture, shake at room temperature, and add glucose aqueous solution dropwise, and continue to shake at room temperature for 30 minutes; after the reaction, t...

Embodiment 3

[0078] (1)~(4) are consistent with embodiment two;

[0079] (5) Dissolve 0.85g of silver nitrate in 50mL of water to obtain an aqueous solution of silver nitrate; add 0.67g of pyrrole to 50mL of water, and then add 0.5g of aramid fiber bundles coated with carbon nanotubes and silver nanoparticles. Shake, while adding silver nitrate aqueous solution drop by drop, continue to shake at room temperature for 24h; After the reaction, the fiber is taken out, washed and dried to obtain aramid fiber bundles coated with polypyrrole, carbon nanotubes and silver nanoparticles. Aramid fiber electrodes.

[0080] (6)-(7) are consistent with the second embodiment, and an aramid fiber electrochemical capacitor is obtained.

[0081] See attached figure 1 , which is the poly-p-phenylene terephthalamide fiber provided in Example 3 of the present invention, polydopamine-coated aramid fiber, silver nanoparticle-coated aramid fiber, carbon nanotube and silver nanoparticle double-layer Scanning el...

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Abstract

The invention discloses an aramid fiber electrode and a preparation method thereof. The preparation method of the aramid fiber electrode is to coat silver nanoparticles, carbon nanotubes, and polypyrrole on the surface of the aramid fiber in sequence by chemical bonding to prepare the aramid fiber electrode. Two bundles of aramid fiber electrodes can be wound with the electrolyte , to obtain an aramid fiber electrochemical capacitor. Compared with the polymer fiber electrochemical capacitor prepared in the prior art, the aramid fiber electrochemical capacitor provided by the present invention has high specific capacitance, high energy density, high mechanical performance, high stability, good flexibility and wearability and other characteristics; the preparation method is controllable and suitable for large-scale applications.

Description

technical field [0001] The invention relates to a fiber electrode, an electrochemical capacitor and a preparation method thereof, in particular to an aramid fiber electrode and a preparation method thereof. Background technique [0002] With the rapid development of wearable smart devices and the urgent need for sustainable energy, high-energy-density fiber electrochemical capacitors have shown great application prospects due to their small size, light weight, flexibility, high efficiency, and easy integration. Fiber electrochemical capacitors are composed of fiber electrodes and electrolytes in a parallel, wound, and coaxial structure, so their performance depends largely on the fiber electrode materials. In order to bring wearable fiber electrochemical capacitors from concept to application, it is urgent to develop high-performance fiber electrodes with good flexibility, wearability and excellent electrochemical performance. [0003] To date, a variety of fibers have been...

Claims

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Application Information

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IPC IPC(8): H01G11/24H01G11/30H01G11/36H01G11/48H01G11/86
CPCH01G11/24H01G11/30H01G11/36H01G11/48H01G11/86Y02E60/13
Inventor 顾嫒娟方浩梁国正袁莉
Owner SUZHOU UNIV
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