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Epoxy graphene oxide film and preparation method thereof

A technology of graphene film and epoxy, which is applied in the field of epoxy graphene oxide film and its preparation, to achieve good heat resistance stability, improve the activity of epoxy group, and improve the effect of mechanical stability and uniformity

Inactive Publication Date: 2018-11-30
王丽鹏
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In recent years, with the continuous development of electronic science and technology, various electronic products have become more and more popular, and the market demand has continued to expand. As a key part of many electronic devices, such as liquid crystal displays and touch screens, transparent conductive films have received more and more attention. Transparent conductive film is a film material with high light transmittance and excellent conductivity in the visible light range. Transparent conductive film is widely used in liquid crystal displays, touch screens, thin-film solar cells, light-emitting devices and electromagnetic shielding devices. Although At present, transparent conductive films based on metal oxides are relatively mature in the market, but there are still many shortcomings. Research on transparent conductive films at home and abroad has gradually become a hot spot. People expect to develop some new production processes, or develop some new types of transparent conductive films. Conductive thin film materials to overcome these disadvantages

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A kind of epoxy graphene oxide film, it is made up of the raw material of following weight part:

[0025] Epoxy emulsion 40, graphene oxide 110, diethylenetriamine 10, aluminum dihydrogen phosphate 4, zinc stearate 1.

[0026] Described epoxy emulsion is made up of the raw material of following weight part:

[0027] Stearic acid 4, glycidol 14, catalyst 0.02, bisphenol A4, palm wax 5, ethylene bisstearamide 2.

[0028] The catalyst is p-toluenesulfonic acid.

[0029] The preparation method of described epoxy emulsion, comprises the following steps:

[0030] (1) Get ethylene bisstearamide, add it to 70 times of its weight in deionized water, stir evenly to obtain amide solution;

[0031] (2) Take palm wax, add it to dimethylformamide which is 7 times its weight, put it into a constant temperature water bath at 80-85°C, keep it warm and stir for 30 minutes, discharge, add bisphenol A, and stir for 2 hours , Dimethylformamide was removed by distillation to obtain modif...

Embodiment 2

[0040] A kind of epoxy graphene oxide film, it is made up of the raw material of following weight part:

[0041] Epoxy emulsion 30, graphene oxide 100, diethylenetriamine 6, aluminum dihydrogen phosphate 2, zinc stearate 0.8.

[0042] Described epoxy emulsion is made up of the raw material of following weight part:

[0043] Stearic acid 3, glycidol 10, catalyst 0.01, bisphenol A3, palm wax 2, ethylene bisstearamide 1.

[0044] The catalyst is p-toluenesulfonic acid.

[0045] The preparation method of described epoxy emulsion, comprises the following steps:

[0046] (1) Get ethylene bisstearamide, add it to 65 times of its weight in deionized water, stir evenly, and get amide solution;

[0047] (2) Take palm wax, add it to dimethylformamide that is 4 times its weight, put it into a constant temperature water bath at 80°C, keep it warm and stir for 10 minutes, discharge, add bisphenol A, stir for 1 hour, and distill Remove dimethylformamide to obtain modified bisphenol A;

...

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PUM

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Abstract

The invention discloses an epoxy graphene oxide film and a preparation method thereof. The epoxy graphene oxide film consists of the following raw materials in parts by weight: 30-40 parts of epoxy emulsion, 100-110 parts of graphene oxide, 6-10 parts of diethylenetriamine, 2-4 parts of aluminium dihydrogen phosphate, 0.8-1 part of zinc stearate. According to the epoxy graphene oxide film, diethylenetriamine is adopted to process the aluminium dihydrogen phosphate so as to be mixed with the dispersion liquid of graphene oxide, amine is used for accelerating environment to open a loop so as toimprove the surface activity of aluminium dihydrogen phosphate and graphene oxide, inter-dimethylformamide dispersion compatibility is further improved, and the mechanical stability and the evenness of a finished product film can be improved.

Description

technical field [0001] The invention belongs to the field of thin films, and in particular relates to an epoxy graphene oxide thin film and a preparation method thereof. Background technique [0002] In recent years, with the continuous development of electronic science and technology, various electronic products have become more and more popular, and the market demand has continued to expand. As a key part of many electronic devices, such as liquid crystal displays and touch screens, transparent conductive films have received more and more attention. Transparent conductive film is a film material with high light transmittance and excellent conductivity in the visible light range. Transparent conductive film is widely used in liquid crystal displays, touch screens, thin-film solar cells, light-emitting devices and electromagnetic shielding devices. Although At present, transparent conductive films based on metal oxides are relatively mature in the market, but there are still...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/00C08K13/06C08K9/04C08K3/04C08K5/098C08K3/32C08J5/18
CPCC08J5/18C08J2363/00C08K3/042C08K3/32C08K5/098C08K9/04C08K13/06
Inventor 王丽鹏
Owner 王丽鹏