Epoxy graphene oxide film and preparation method thereof
A technology of graphene film and epoxy, which is applied in the field of epoxy graphene oxide film and its preparation, to achieve good heat resistance stability, improve the activity of epoxy group, and improve the effect of mechanical stability and uniformity
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Embodiment 1
[0024] A kind of epoxy graphene oxide film, it is made up of the raw material of following weight part:
[0025] Epoxy emulsion 40, graphene oxide 110, diethylenetriamine 10, aluminum dihydrogen phosphate 4, zinc stearate 1.
[0026] Described epoxy emulsion is made up of the raw material of following weight part:
[0027] Stearic acid 4, glycidol 14, catalyst 0.02, bisphenol A4, palm wax 5, ethylene bisstearamide 2.
[0028] The catalyst is p-toluenesulfonic acid.
[0029] The preparation method of described epoxy emulsion, comprises the following steps:
[0030] (1) Get ethylene bisstearamide, add it to 70 times of its weight in deionized water, stir evenly to obtain amide solution;
[0031] (2) Take palm wax, add it to dimethylformamide which is 7 times its weight, put it into a constant temperature water bath at 80-85°C, keep it warm and stir for 30 minutes, discharge, add bisphenol A, and stir for 2 hours , Dimethylformamide was removed by distillation to obtain modif...
Embodiment 2
[0040] A kind of epoxy graphene oxide film, it is made up of the raw material of following weight part:
[0041] Epoxy emulsion 30, graphene oxide 100, diethylenetriamine 6, aluminum dihydrogen phosphate 2, zinc stearate 0.8.
[0042] Described epoxy emulsion is made up of the raw material of following weight part:
[0043] Stearic acid 3, glycidol 10, catalyst 0.01, bisphenol A3, palm wax 2, ethylene bisstearamide 1.
[0044] The catalyst is p-toluenesulfonic acid.
[0045] The preparation method of described epoxy emulsion, comprises the following steps:
[0046] (1) Get ethylene bisstearamide, add it to 65 times of its weight in deionized water, stir evenly, and get amide solution;
[0047] (2) Take palm wax, add it to dimethylformamide that is 4 times its weight, put it into a constant temperature water bath at 80°C, keep it warm and stir for 10 minutes, discharge, add bisphenol A, stir for 1 hour, and distill Remove dimethylformamide to obtain modified bisphenol A;
...
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