Oil-resistant moving-ring sealing ring and preparation method thereof
A technology of sealing ring and static ring, which is applied in the field of oil-resistant static ring sealing ring and its preparation, can solve problems such as the reduction of rubber strength and other mechanical properties.
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[0013] The invention provides a method for preparing an oil-resistant static ring seal ring, comprising:
[0014] 1) Calcining the vermiculite to obtain expanded vermiculite, then soaking the expanded vermiculite in mixed acid, and then washing to obtain modified expanded vermiculite;
[0015] 2) Perform solvothermal reaction of modified expanded vermiculite, ethylene glycol, glycerin, parabens, and sulfuric acid, and then filter the filter cake to obtain oil resistance additives;
[0016] 3) Mix fluorine rubber, EPDM rubber, benzoyl peroxide, zinc dimethacrylate and tetramethylthiuram disulfide for the first time, then add white carbon black, sulfur, nitrile rubber, decane Dioctyl dioic acid and oil-resistant additives are mixed twice, and finally molded to obtain an oil-resistant static ring seal; wherein, the mixed acid is composed of hydrochloric acid solution and hydrocyanic acid solution.
[0017] In step 1) of the present invention, the specific conditions of calcinati...
Embodiment 1
[0028] 1) Calcinate the vermiculite (calcine from 230°C for 1.5h, then raise the temperature to 650°C at a rate of 3.5°C / h and keep it for 1.5h, then raise the temperature to 1050°C at a rate of 1.5°C / h and keep it for 3h, and finally natural cooling) to obtain expanded vermiculite, then expand the vermiculite in mixed acid (the weight ratio of hydrochloric acid solution and hydrogen cyanide solution is 1:0.2, and the concentration of hydrochloric acid solution is 20% by weight, and the concentration of hydrogen cyanide solution is 9% by weight %; the weight ratio of expanded vermiculite and mixed acid is 1:3) for soaking (soaking temperature is 40°C, soaking time is 10h), and then cleaned to obtain modified expanded vermiculite;
[0029] 2) Solvothermal reaction of modified expanded vermiculite, ethylene glycol, glycerin, paraben, and sulfuric acid in a weight ratio of 50:20:30:35:6 (reaction temperature is 150°C, reaction The time is 8h), and then filter the filter cake to o...
Embodiment 2
[0032] 1) Calcinate the vermiculite (calcine from 200°C for 1 hour, then raise the temperature to 600°C at a rate of 3°C / h and hold it for 1 hour, then raise the temperature to 1000°C at a rate of 1°C / h and hold it for 2 hours, and finally cool it naturally ) to obtain expanded vermiculite, then mix expanded vermiculite with mixed acid (the weight ratio of hydrochloric acid solution and hydrocyanic acid solution is 1:0.1, and the concentration of hydrochloric acid solution is 15% by weight, and the concentration of hydrocyanic acid solution is 8% by weight; The weight ratio of expanded vermiculite and mixed acid is 1:2) for soaking (soaking temperature is 35°C, soaking time is 8h), and then cleaned to obtain modified expanded vermiculite;
[0033] 2) Perform solvothermal reaction of modified expanded vermiculite, ethylene glycol, glycerin, paraben, and sulfuric acid in a weight ratio of 50:15:25:30:4 (reaction temperature is 140°C, reaction The time is 6h), and then filter the...
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