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A bulk material with wetting anisotropy and its preparation method

A bulk material, anisotropic technology, used in the preparation/purification of carbon, ceramic products, household appliances, etc., can solve the problems of lack and limitation of three-dimensional materials

Active Publication Date: 2021-09-24
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, surface integration materials with different wettability are often limited to two-dimensional materials, and the development of three-dimensional materials is still lacking.

Method used

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  • A bulk material with wetting anisotropy and its preparation method
  • A bulk material with wetting anisotropy and its preparation method
  • A bulk material with wetting anisotropy and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] In this embodiment, the schematic diagram of the block material structure is as follows figure 1 As shown, it is a three-dimensional cube structure composed of several carbon tubes, each dimension of the cube is 1 cm, and the tube walls of the carbon tubes are gathered together.

[0043] Such as figure 1 As shown, the material of each carbon tube is carbon, and each carbon tube is a hollow columnar structure with an open end. The cross section of each columnar structure is circular. The diameter of each carbon tube is 260 micrometers.

[0044] The bulk material was prepared by the template method, as follows:

[0045] Using 3D printing materials as templates, bulk porous carbon materials with special wetting anisotropy were prepared by template method. The specific process is as follows:

[0046] (1) Polycarbonate (PC) is used as the 3D printing material, and the polymer template is made by 3D printing. The structure of the polymer template is the same as that of ...

Embodiment 2

[0053] In this example, the bulk material such as Figure 6 As shown, it is a three-dimensional cube structure composed of several carbon tubes, each dimension of the cube is 1 cm, and the tube walls of the carbon tubes are gathered together.

[0054] Such as figure 1 As shown, the material of each carbon tube is carbon, and each carbon tube is a hollow columnar structure with an open end. The cross section of each columnar structure is circular. The diameter of each carbon tube is 260 micrometers.

[0055] Such as Figure 6 As shown, the material of each carbon tube is carbon, and each carbon tube is a hollow columnar structure with an open end. Moreover, the tube wall of the outermost carbon tube has an opening structure along the length direction of the tube body, that is, the cross section of the outermost carbon tube perpendicular to the length direction of the carbon tube is an arc. Except for the outermost carbon tubes, the cross-sections of the rest of the carbon ...

Embodiment 3

[0064] In this embodiment, the block material is basically the same as the block structure in Embodiment 2, the difference is as Figure 11 As shown, each tube wall has a number of holes, and the size of each hole is in the range of 2 microns to 50 microns, and these holes form channels connecting the carbon tubes.

[0065] The preparation method of the bulk material is basically the same as that in Example 2, except that in step (1), the tube walls of each tubular structure in the template are set as Figure 11 A number of pores shown in , each pore size ranging from 2 microns to 50 microns, form channels communicating with each tubular structure.

[0066] The wettability test of the block material prepared above is as follows:

[0067] (1) Drop water onto the tube wall side of the aggregated carbon tubes, and the measured contact angle is 113.52°.

[0068] (2) Water drops are dropped onto the end face side of the aggregated carbon tubes, and the contact angle is measured t...

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Abstract

The invention discloses a bulk material with wetting anisotropy. The block material is composed of several carbon tubes, and the tube walls of each carbon tube are aggregated to form a three-dimensional structure; the water droplets are hydrophobic on the tube wall side of the carbon tubes, and hydrophilic on the end face side of the carbon tubes. The present invention adopts the template with the structural characteristics of the block material, soaks the template in the ethanol solution of the phenolic resin, then raises the temperature to volatilize the ethanol, then raises the temperature to solidify the phenolic resin on the inner wall of the template structure, and then further raises the temperature to decompose the template by heat. The phenolic resin is carbonized to obtain the bulk material. Wherein, the dried xylem of woody plants can be used as the template, which has the advantages of simple and easy-to-obtain raw materials and simple preparation.

Description

technical field [0001] The invention belongs to the technical field of functional materials, and relates to a block material with wetting anisotropy and a preparation method. Background technique [0002] Wettability is one of the important properties of solid surfaces, which is mainly affected by two factors: the chemical composition of the solid surface and the morphology of the solid surface. Wettability is often described in the form of contact angle. The contact angle between the solid surface and water is less than 5° for superhydrophilicity, and greater than 90° for hydrophobicity. Integrating surfaces with different wetting functions into one system, such as the integrated system of superhydrophilic / hydrophobic surfaces, has greater advantages than traditional surfaces with only a single wettability, and has the potential to be used in water mist collection, It plays an important role in microfluidics, liquid separation, liquid directional transport, and ocean drag ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B32/05C04B38/06
CPCC04B38/0615C01B32/05
Inventor 汪爱英王舒远张栋孙丽丽陈仁德
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI