Infrared blocking composition, methods of forming, and the infrared layer formed therefrom
A technology of infrared rays and compositions, applied in the direction of synthetic resin layered products, chemical instruments and methods, coatings, etc., can solve problems such as increased heating of internal spaces, increased air conditioning, and reduced comfort of passengers or residents
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Embodiment 1- Embodiment 13
[0070] Example 1-Example 13: Preparation of infrared blocking layer
[0071] Five infrared blocking compositions were prepared by mixing a polymer solution of UVHC5000 (commercially available from Momentive Co.) containing 45 wt% solids with a 20 wt% CTO dispersion. The IR blocking composition was bar coated onto a 0.5mm thick polycarbonate sheet, heated at 80 degrees Celsius (°C) for 30 minutes, and under ambient conditions using a Fusion UV model F300S-6 processor using H lamp, 300W / in, UV curing at 5m / min. The polycarbonate sheet had a haze of 0.1%, a visible light transmission of 90%, and a total solar energy transmission of 86%.
[0072] Adhesion, haze, total solar energy transmittance, and visible light transmittance of the infrared blocking layers of Example 2, Example 3, and Example 5 were measured and shown in Table 1. The transmission (dotted line) and reflection (solid line) spectral data of the infrared blocking layer of Example 5 in the visible IR range were me...
Embodiment 14- Embodiment 16
[0079] Example 14-Example 16: Effect of polymer matrix
[0080] Three infrared blocking layers were prepared using the same coating method as in Example 1-Example 5, except that the curable prepolymer was changed. The curable prepolymer of Example 14 is UV curable silicone based coating UVHC5000, the curable prepolymer of Example 15 is heat curable acrylate D1457, and the curable prepolymer of Example 16 is UV curable Acrylate DM353L, all commercially available from Momentive. Example 14 and Example 16 included the solvent propylene glycol monomethyl ether (PGME).
[0081]
[0082] Table 3 shows that Example 14 has a significantly lower haze of only 4.9% compared to the haze of Examples 15 and 16 at the same CTO loading.
[0083] Embodiments of compositions, layers formed therefrom, layered structures comprising layers, and methods of formation of the present invention are listed below.
Embodiment approach 1
[0084] Embodiment 1: An infrared blocking composition, comprising: based on the total weight of the curable prepolymer and the infrared blocking agent, 60 to 95wt% or 60 to 98wt% of the curable prepolymer; based on the curable prepolymer The total weight of the substance and the infrared blocking agent, 2 to 40wt% or 5 to 40wt% of the infrared blocking agent; wherein the infrared blocking agent contains indium tin oxide, antimony tin oxide, tin oxyfluoride, tungsten oxide or contains the foregoing A combination of at least one of them.
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