A method for preferentially absorbing ruthenium in the process of enriching platinum group metals and gold
A platinum group metal, preferential absorption technology, applied in the direction of improving process efficiency, can solve problems such as endangering the life safety of operators, loss of rare metal ruthenium, etc., to achieve the effect of improving recovery rate, reducing risk, and shortening time
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Embodiment 1
[0042] A method for preferentially absorbing ruthenium in a process for enriching platinum group metals and gold, comprising the following steps:
[0043] (1) Take the cooked coke gem raw material, pulverize it into a coke coke powder with a fineness of 200 mesh for subsequent use; mix and stir concentrated sulfuric acid and water with a mass fraction of 98% at a mass ratio of 0.9:1 to obtain a sulfuric acid solution, and take the molar Concentration is the hydrochloric acid solution of 1mol / L standby;
[0044] (2) Add sodium chloride, sulfuric acid solution and hydrochloric acid solution to the cooked coke gemstone powder, mix evenly by the mass ratio of 4.5:1:4.5:50, obtain mixed material;
[0045] (3) The mixed material obtained above was transferred to a reaction kettle, and reacted at 90° C. for 1 h under 10 kw / h visible light irradiation. A condensing device is used to control the temperature of the gas above the reactor to ≤50°C, and the gas generated during the reacti...
Embodiment 2
[0048] A method for preferentially absorbing ruthenium in a process for enriching platinum group metals and gold, comprising the following steps:
[0049] (1) Take the cooked coke gem raw material, pulverize it into a coke coke powder with a fineness of 200 mesh for subsequent use; mix and stir concentrated sulfuric acid and water with a mass fraction of 98% at a mass ratio of 0.9:1 to obtain a sulfuric acid solution, and take the molar Concentration is the hydrochloric acid solution of 2mol / L standby;
[0050] (2) Add sodium chloride, sulfuric acid solution and hydrochloric acid solution to the cooked coke gemstone powder, mix uniformly by the mass ratio of 5:1:10:70, obtain mixed material;
[0051] (3) The mixed material obtained above was transferred to a reaction kettle, and reacted at 100° C. for 1 h under 10 kw / h visible light irradiation. A condensing device is used to control the temperature of the gas above the reactor to ≤55°C, and the gas generated during the react...
Embodiment 3
[0054] A method for preferentially absorbing ruthenium in a process for enriching platinum group metals and gold, comprising the following steps:
[0055] (1) choose ore raw material, be pulverized into fineness and be that 200 mesh cooked coke gemstone powders are for subsequent use; Be that the concentrated sulfuric acid of 98% and water are mixed and stirred by the mass ratio of 0.9:1 to obtain sulfuric acid solution with mass fraction, get molar concentration as The hydrochloric acid solution of 4mol / L is standby;
[0056] (2) Add sodium chloride, sulfuric acid solution and hydrochloric acid solution to the cooked coke gemstone powder, mix uniformly by the mass ratio of 5.5:1:16.5:60, obtain mixed material;
[0057] (3) Transfer the mixed material obtained above to a reaction kettle, and react at 110° C. for 1 h under 10 kw / h ultraviolet light irradiation. A condensing device is used to control the temperature of the gas above the reactor to ≤60°C, and the gas generated d...
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