A polyamide reverse osmosis membrane and its application in the field of seawater desalination

A technology of reverse osmosis membrane and polyamide, applied in the direction of osmosis/dialysis water/sewage treatment, reverse osmosis, seawater treatment, etc., can solve the problems of poor compatibility, easy to produce membrane defects, reduce membrane separation performance, etc., to prevent agglomeration , Hydrophilic performance and anti-pollution ability improvement, the effect of good hydrophilic ability

Active Publication Date: 2021-10-08
成都硕特科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in practical applications, it is found that the particle size of hydrophilic molecular sieves, especially NaA molecular sieves, is generally larger than 1 μm, and their compatibility with polysulfone polymers is poor, so membrane defects are more likely to occur, thereby reducing the separation performance of the membrane.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0057] (1) Mix in-situ synthesized NaA molecular sieves (average particle size of 1.5 μm) and ethanol at a mass ratio of 1:50, and send them into a zirconia ball mill tank for ball milling. Set the ball milling speed to 450rpm, and the ball milling time for 6h. After the ball milling, the sample was dried and tested to have a particle size of 120nm;

[0058] (2) Evaporate the ball-milled NaA molecular sieve particle suspension to remove part of the ethanol solvent to obtain the ball-milled NaA molecular sieve particle additive solution. At this time, the mass ratio of NaA molecular sieve to ethanol in the additive solution is 1:4;

[0059] (3) Mix 5wt% of the above ball-milled NaA molecular sieve particle addition solution, 40wt% polysulfone and 55% dimethylformamide, mechanically stir for 1 hour, and ultrasonically disperse for 2 hours to prepare a polysulfone casting solution;

[0060] (4) Coat the polysulfone casting solution on the non-woven fabric carrier, scrape the fil...

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PUM

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Abstract

The invention provides a polyamide reverse osmosis membrane material, which improves the hydrophilicity and anti-pollution ability of the polyamide reverse osmosis membrane material by hydrophilically modifying the supporting membrane material of the reverse osmosis membrane material, and can be used in seawater desalination field has great application potential.

Description

technical field [0001] The application relates to an organic membrane, in particular to a hydrophilic polyamide reverse osmosis membrane with large flux and its application in the field of seawater desalination. Background technique [0002] Reverse osmosis composite membranes have excellent separation properties for small organic molecules and inorganic salt ions, and are widely used in seawater brackish water desalination, water purification, sewage reuse and other fields, and are of great significance to the utilization and protection of the earth's limited water resources. At present, the mainstream polyamide reverse osmosis membrane preparation method is the interfacial polymerization method. First, a layer of aqueous phase solution containing a certain proportion of m-phenylenediamine (MPD) is evenly spread on the surface of the supporting membrane as the supporting layer, and the excess aqueous phase is removed. After the solution is poured into the membrane surface, ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D71/56B01D61/02B01D67/00C02F1/44C02F103/08
CPCB01D61/025B01D67/0079B01D71/56B01D2325/36C02F1/441C02F2103/08Y02A20/131
Inventor 黄兴俊倪金元杨敏其他发明人请求不公开姓名
Owner 成都硕特科技股份有限公司
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