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Beta-cyclodextrin cross-linked graphene functional cotton fiber and preparation method thereof

A cyclodextrin, cotton fiber technology, applied in fiber processing, plant fibers, textiles and papermaking, etc., can solve the problems of bond fastness and washing fastness to be improved, lack of bonding effect and other problems

Inactive Publication Date: 2019-03-26
钱景
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But the main deficiency of the finishing method is that there is no effective bonding between cotton fiber and graphene, and its combination fastness and washing fastness need to be improved (Ji Yimin, Chen Guoqiang, Xing Tieling, Tan Jinqi, Cheng Ankang. Functionality Research progress of graphene finishing textiles[J]. Printing and Dyeing, 2017,43(16):49-54)

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0010] (1) After mixing nitric acid and phosphoric acid with a volume ratio of 1:1, add monochloro-s-triazine-β-cyclodextrin with a bath ratio of 1:10, stir well, and quickly add a certain amount of NaNO 2 , the NaNO 2 The mass of chlorotriazine-β-cyclodextrin is 2:1, and it is reacted at 60°C for 30 minutes under dark conditions. After the reaction, it is repeatedly washed with deionized water until neutral, and air-dried at room temperature to obtain oxidized chlorotriazine - beta-cyclodextrin. (2) Immerse the cotton fibers in 1% oxidized monochloro-s-triazine-β-cyclodextrin solution and react at 60°C for 30 minutes with a bath ratio of 1:50. After the reaction, wash repeatedly with deionization and dry After drying, a chloro-s-triazine-β-cyclodextrin grafted cotton fiber is obtained. (3) Immerse the above-mentioned β-cyclodextrin grafted cotton fiber in the ethanol dispersion of aminated graphene with a mass fraction of 1%, the amino group content of the aminated graphene...

Embodiment 2

[0012] (1) After mixing nitric acid and phosphoric acid with a volume ratio of 1:1, add monochlorotriazine-β-cyclodextrin, the bath ratio is 1:15, stir well, and quickly add a certain amount of NaNO 2 , the NaNO 2 The mass of chlorotriazine-β-cyclodextrin is 2:1, and it is reacted at 60°C for 30 minutes under dark conditions. After the reaction, it is repeatedly washed with deionized water until neutral, and air-dried at room temperature to obtain oxidized chlorotriazine - beta-cyclodextrin. (2) Immerse the cotton fibers in 5% oxidized monochloro-s-triazine-β-cyclodextrin solution and react at 70°C for 60 minutes with a bath ratio of 1:50. After drying, a chloro-s-triazine-β-cyclodextrin grafted cotton fiber is obtained. (3) Immerse the above-mentioned β-cyclodextrin grafted cotton fiber in an ethanol dispersion of aminated graphene with a mass fraction of 5%, the amino content of the aminated graphene is 1 wt%, and add a certain amount of glutaraldehyde, The quality of the...

Embodiment 3

[0014] (1) After mixing nitric acid and phosphoric acid with a volume ratio of 2:1, add monochloro-s-triazine-β-cyclodextrin with a bath ratio of 1:20, stir well, and quickly add a certain amount of NaNO 2 , the NaNO 2 The mass of chlorotriazine-β-cyclodextrin is 2:1, and it is reacted at 60°C for 30 minutes under dark conditions. After the reaction, it is repeatedly washed with deionized water until neutral, and air-dried at room temperature to obtain oxidized chlorotriazine - beta-cyclodextrin. (2) Immerse the cotton fibers in 10% oxidized monochloro-s-triazine-β-cyclodextrin solution and react at 80°C for 300 minutes with a bath ratio of 1:50. After drying, a chloro-s-triazine-β-cyclodextrin grafted cotton fiber is obtained. (3) Immerse the above-mentioned β-cyclodextrin grafted cotton fiber in the ethanol dispersion of aminated graphene with a mass fraction of 10%, the amino group content of the aminated graphene is 5wt%, and add a certain amount of glutaraldehyde, The ...

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Abstract

The invention discloses a beta-cyclodextrin cross-linked graphene functional cotton fiber and a preparation method thereof. The preparation method comprises the following steps: dipping a cotton fiberinto an oxidized monochlorotriazine-beta-cyclodextrin solution with a mass friction of 1%-10%, and reacting at 60-80 DEG C for 30-300 minutes, so as to obtain monochlorotriazine-beta-cyclodextrin grafted cotton fiber; and dipping the monochlorotriazine-beta-cyclodextrin grafted cotton fiber into aminated graphene ethanol dispersion liquid with a mass friction of 1%-10%, adding a certain amount ofa cross-linking agent, and stirring at a constant speed at the normal temperature for 60-600 minutes, so as to obtain the beta-cyclodextrin cross-linked graphene functional cotton fiber. By utilizingoxidized monochlorotriazine-beta-cyclodextrin as a cross-linking agent, the cotton fiber can be endowed with certain properties of electric conduction, antibiosis, ultraviolet protection, flame retardance, washing resistance and the like by aminated graphene.

Description

technical field [0001] The invention relates to a β-cyclodextrin cross-linked graphene functional cotton fiber and a preparation method thereof, belonging to the field of textile materials and functional nanometer materials. Background technique [0002] Since the discovery of graphene by two scholars from the University of Manchester in 2004, the research boom of graphene is in the ascendant. Graphene is made of carbon atoms with sp 2 The two-dimensional nanomaterial of the hexagonal honeycomb lattice composed of hybrid orbitals is the basic unit of carbon materials such as zero-dimensional fullerenes, one-dimensional carbon nanotubes, and three-dimensional graphite. Graphene is currently the thinnest two-dimensional material in the world. It has excellent optical, electrical, thermal, and mechanical properties. It has a lot of research and applications in the fields of optoelectronic devices, biomedical materials, and adsorption materials. Graphene has only been discover...

Claims

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Application Information

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IPC IPC(8): D06M11/74D06M15/03D06M101/06
CPCD06M11/74D06M15/03D06M2101/06
Inventor 钱景
Owner 钱景
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