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A method for judging tea grade based on carbon quantum dots

A technology of carbon quantum dots and grades, applied in measuring devices, material excitation analysis, fluorescence/phosphorescence, etc., can solve problems such as lack of comparability, unscientific formulation of sensory indicators, unobjective review and scoring characterization, and achieve discrimination accuracy High, improve stability and accuracy, and objectively judge the effect

Active Publication Date: 2020-02-18
ANHUI AGRICULTURAL UNIVERSITY
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, this method is easily affected by the subjective consciousness and experience of the reviewers. The review scores are not objective, the sensory indicators are not scientifically formulated, and the review results are affected by the review environment (temperature, light, noise, etc.) and review equipment (apparatus, water quality) and the lack of comparability among similar analysis methods, there is an urgent need for an objective, accurate and convenient tea quality and grade evaluation technology

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  • A method for judging tea grade based on carbon quantum dots
  • A method for judging tea grade based on carbon quantum dots
  • A method for judging tea grade based on carbon quantum dots

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Experimental program
Comparison scheme
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Embodiment 1

[0034] The specific process of this embodiment is as follows:

[0035] (1) Preparation of carbon quantum dots by hydration method:

[0036] Take 0.42mmol thiourea, 1.26mmol urea and 0.28mmol sodium citrate dissolved in 30mL ultrapure water, stir for 15min to fully dissolve. The mixed solution was transferred to a polytetrafluoroethylene-lined reaction kettle with a volume of 50 mL, and heated in an oven at a reaction temperature of 185° C. for a reaction time of 6 h. After the reaction is completed, cool to room temperature and pass through a 0.22 μm filter membrane to obtain a yellowish-brown liquid that is the carbon quantum dot solution, which is set aside;

[0037] (2) Weigh 0.2g of 120 samples of Yunnan black tea of ​​different grades (special grade, first grade, second grade, third grade, fourth grade, fifth grade, sixth grade and extra grade) to be tested, add 8mL of 70% ethanol, and conduct ultrasound for 45min For leaching, the ultrasonic temperature is 70°C, and th...

Embodiment 2

[0073] In order to examine the feasibility of this method, cross-validation was carried out on the observed values ​​of the known discrimination results of different grades of Dianhong tea. In cross-validation, each observation is classified according to a function derived from all observations other than that observation, and the classification results are shown in Table 3. The results in Table 3 show that 95% of the cross-validation groups are correctly classified, and the classification accuracy is P 特级 =100%, P 一级 =86.7%, P 二级 =100%, P 三级 =100%, P 四级 =93.3%, P 五级 =86.7%, P 六级 = 93.3% and P 级外 = 100%. It shows that the grade discriminant method of Dianhong based on carbon quantum dot nanomaterials combined with principal component analysis and Bayesian discriminant method is feasible.

[0074] Table 3 Classification and verification results of Bayesian discriminant for different grades of Dianhong tea

[0075]

[0076] The invention judges by detecting the carbo...

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Abstract

The invention discloses a method for discriminating the tea grade based on carbon quantum dots. The method comprises the steps that carbon-nitrogen ratios of tea samples with different raw material grades are detected, a response curve between the carbon-nitrogen differential ratios of the tea samples with the different grades and a carbon quantum dot reaction is established, and fluorescence spectrum response intensity values of the tea samples with the different grades are obtained; based on fluorescence spectrums of the tea samples with the different raw material grades, a carbon quantum dot fluorescence spectrum discrimination model of the tea samples with the different raw material grades is constructed; the representative different-grade tea samples picked in different seasons are selected to verify the established discrimination model, and a carbon quantum dot fluorescence spectrum qualitative forecasting model for the tea verification samples with the different raw material grades is established. According to the method for discriminating the tea grade based on the quantum dots, the problem that the appraisal results lack of consistency due to the influence of subjective factors in the manual appraisal process can be effectively solved; and the discrimination result error between different appraisal personnel can be well eliminated, and the stability and accuracy of thetaste grade appraisal result are improved.

Description

technical field [0001] The invention relates to a method for discriminating tea grades, in particular to a method for discriminating tea grades based on carbon quantum dots. Background technique [0002] Sensory evaluation is a relatively scientific evaluation method, which has the advantages of directness, comprehensiveness, and rapidity. It is widely used in tea quality evaluation and is the main evaluation method for technicians engaged in tea quality control in universities, scientific research institutes and tea enterprises. . However, this method is easily affected by the subjective consciousness and experience of the reviewers. The review scores are not objective, the sensory indicators are not scientifically formulated, and the review results are affected by the review environment (temperature, light, noise, etc.) and review equipment (apparatus, water quality) and the lack of comparability among similar analysis methods, there is an urgent need for an objective, ac...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N21/64
CPCG01N21/643
Inventor 张正竹朱峰源任广鑫宁井铭
Owner ANHUI AGRICULTURAL UNIVERSITY