Waterproof fabric
A technology of waterproof fabrics and fabrics, which is applied in the direction of layered products, synthetic resin layered products, textiles and papermaking, etc. It can solve the problems that the water repellency effect cannot reach the protective clothing, increase the wet weight of fabrics, etc., and achieve excellent waterproof, Special flexibility, enhanced waterproof effect
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Embodiment 1
[0050] A kind of nano-SiO 2 Modified polyurethane emulsion, in parts by mass, consists of 26 parts of nano-SiO 2 Sol, 96 parts of water-based polyurethane prepolymer emulsion, 18 parts of vinyl silicone oil, 15 parts of polymerizable silicone monomer (as shown in formula 1), 15 parts of emulsifier, 1 part of initiator, 370 parts of water through emulsion polymerization become;
[0051] (H 3 c) 3 Si-O-CH 2 CH 2 NH-CH 2 CH=CH 2 Formula 1
[0052] The preparation method comprises the following steps:
[0053] 1. Nano SiO 2 Sol preparation method
[0054] 25 parts of γ-methacryloxypropyl trimethoxysilane (silane coupling agent KH-570), 3 parts of sodium lauryl sulfate, 4 parts of alkylphenol polyoxyethylene ether (OP-10) Add it into 300 parts of water, stir and disperse, then add 9 parts of ammonia water under stirring, and continue to stir for 4 hours to form nano-SiO containing C=C bonds. 2 Sol;
[0055] 2. Preparation of waterborne polyurethane prepolymer emulsion:...
Embodiment 2
[0064] A kind of nano-SiO 2 Modified polyurethane emulsion, in parts by mass, consists of 21 parts of nano-SiO 2 Sol, 85 parts of water-based polyurethane prepolymer emulsion, 15 parts of vinyl silicone oil, 12 parts of polymerizable silicone monomer (as shown in formula 1), 13 parts of emulsifier, 0.8 part of initiator, 340 parts of water through emulsion polymerization become;
[0065] (H 3 c) 3 Si-O-CH 2 CH 2 NH-CH 2 CH=CH 2 Formula 1
[0066] The preparation method comprises the following steps:
[0067] 1. Nano SiO 2 Sol preparation method
[0068] 25 parts of γ-methacryloxypropyl trimethoxysilane (silane coupling agent KH-570), 3 parts of sodium lauryl sulfate, 4 parts of alkylphenol polyoxyethylene ether (OP-10) Add it into 300 parts of water, stir and disperse, then add 9 parts of ammonia water under stirring, and continue to stir for 4 hours to form nano-SiO containing C=C bonds. 2 Sol;
[0069] 2. Preparation of waterborne polyurethane prepolymer emulsio...
Embodiment 3
[0078] A kind of nano-SiO 2 Modified polyurethane emulsion, in parts by mass, consists of 17 parts of nano-SiO 2 Sol, 72 parts of water-based polyurethane prepolymer emulsion, 12 parts of vinyl silicone oil, 9 parts of polymerizable silicone monomer (as shown in formula 1), 9 parts of emulsifier, 0.6 part of initiator, 290 parts of water through emulsion polymerization become;
[0079] (H 3 c) 3 Si-O-CH 2 CH 2 NH-CH 2 CH=CH 2 Formula 1
[0080] The preparation method comprises the following steps:
[0081] 1. Nano SiO 2 Sol preparation method
[0082] 25 parts of γ-methacryloxypropyl trimethoxysilane (silane coupling agent KH-570), 3 parts of sodium lauryl sulfate, 4 parts of alkylphenol polyoxyethylene ether (OP-10) Add it into 300 parts of water, stir and disperse, then add 9 parts of ammonia water under stirring, and continue to stir for 4 hours to form nano-SiO containing C=C bonds. 2 Sol;
[0083] 2. Preparation of waterborne polyurethane prepolymer emulsion:...
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