Polyolefin material with spray-free metal effect and preparation method and application thereof

A metal effect and polyolefin technology, applied in the field of plastic coloring, can solve problems such as weld lines and flow marks, and achieve the effect of eliminating weld lines, good dispersion, and low price

Inactive Publication Date: 2019-05-21
广东波斯科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to overcome the problems of weld lines and flow marks that occur when plastics are treated with spray-free metal effects in the prior art, and provide a polyolefin material with spray-free metal effects

Method used

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  • Polyolefin material with spray-free metal effect and preparation method and application thereof
  • Polyolefin material with spray-free metal effect and preparation method and application thereof
  • Polyolefin material with spray-free metal effect and preparation method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0059] This embodiment provides a polyolefin material without spraying metal effect, and its preparation method is as follows.

[0060] (1) Preparation of modified glass microspheres

[0061]In parts by weight, weigh 80 parts of glass microspheres (particle size 25-40 microns) and add them to 100 parts of ethanol, then add 20 parts of aminopropyltriethoxysilane, stir and reflux at 90°C for 30 minutes, After cooling to room temperature, filter and dry to obtain modified glass microspheres.

[0062] (2) Preparation of polyolefin material without spraying metal effect

[0063] Put 30 parts of modified glass microspheres, 60 parts of polypropylene (melt index 12g / 10min), 0.5 parts of aluminum powder (particle size 15-25 microns), 0.1 part of antioxidant 1010, and 2 parts of polyethylene wax in a mixer Mix evenly, stirring at a speed of 200 rpm, and stirring for 10 minutes. The homogeneously mixed premixed material is subjected to twin-screw extrusion and granulation at a temper...

Embodiment 2

[0065] This embodiment provides a polyolefin material without spraying metal effect, and its preparation method is as follows.

[0066] (1) Preparation of modified hollow glass microspheres

[0067] In parts by weight, weigh 20 parts of hollow glass microspheres (particle size 25-40 microns) and add them to 100 parts of ethanol, then add 20 parts of aminopropyltriethoxysilane, stir and reflux at 90°C for 30 minutes , cooled to room temperature, filtered and dried to obtain modified hollow glass microspheres.

[0068] (2) Preparation of polyolefin material without spraying metal effect

[0069] Mix 20 parts of modified hollow glass microspheres, 70 parts of polypropylene (melt index 12g / 10min), 0.5 parts of aluminum powder (particle size 15-25 microns), 0.1 part of antioxidant 1010, 2 parts of polyethylene wax, 0.2 parts of blue Color pigments were placed in a mixer and mixed evenly at a stirring speed of 200 rpm for 10 minutes. The homogeneously mixed premixed material is s...

Embodiment 3

[0071] This embodiment provides a polyolefin material without spraying metal effect, and its preparation method is as follows.

[0072] (1) Preparation of modified glass microspheres

[0073] In parts by weight, weigh 80 parts of glass microspheres (particle size 25-40 microns) and add them to 100 parts of ethanol, then add 20 parts of vinyltriethoxysilane, stir and reflux at 90°C for 30 minutes, cool After reaching room temperature, filter and dry to obtain modified glass microspheres.

[0074] (2) Preparation of polyolefin material without spraying metal effect

[0075] Put 30 parts of modified glass microspheres, 60 parts of polypropylene (melt index 12 g / 10min), 0.5 parts of aluminum powder (particle size 15-25 microns), 0.1 part of antioxidant 168, and 2 parts of calcium polystearate in a Mix evenly in a mixer at a stirring speed of 200 rpm for 10 minutes. The homogeneously mixed premixed material is subjected to twin-screw extrusion and granulation at a temperature of...

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Abstract

The invention relates to a polyolefin material with a spray-free metal effect and a preparation method and an application thereof. The polyolefin material with the spray-free metal effect comprises the following components in part by weight: 5-30 parts of modified spherical micro-particles, 50-80 parts of polyolefin polymer, 0.5-10 parts of sheet metal-effect pigment and 0.1-10 parts of auxiliaryagent; the modified spherical micro-particles are spherical micro-particles modified with a surfactant. According to the polyolefin material with the spray-free metal effect and the preparation methodand the application thereof, the spherical micro-particles are modified by using the surfactant to greatly improve the dispersibility of the spherical micro-particles; the modified spherical micro-particles are good in dispersibility; the sheet metal-effect pigment at the melt junction can be inhibited to deflect with the melt flow direction through the steric hindrance effect to achieve the purpose of eliminating the welding mark of the polyolefin material with the spray-free metal effect; the existing process and equipment do not need to be improved, thus the cost is low.

Description

technical field [0001] The invention belongs to the field of plastic coloring, and in particular relates to a polyolefin material without spraying metal effect and its preparation method and application. Background technique [0002] At present, as all walks of life pay more and more attention to environmental protection issues, plastic products without spraying metal effects are gradually gaining people's favor. Spray-free plastics can reduce painting or electroplating production processes and avoid environmental pollution, and spray-free plastics can also achieve diversified metal effects to meet the diverse needs of consumers and have huge market potential. However, there are still deficiencies in the realization of the current spray-free metal effect. Due to the use of flake pigments such as metal flakes or pearl powder, during injection molding production, when the melt flows in the mold, the pigments are oriented in the flow direction. When the melt flow is deflected,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/06C08L23/20C08K9/06C08K9/04C08K7/20C08K7/00C08K5/134C08K7/28C08K5/098C08K5/526C08K7/18C08K5/20
Inventor 许卫民刘鹏雷周桥阮文红黎泽顺卢俊文
Owner 广东波斯科技股份有限公司
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