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A kind of catalytic diesel oil hydrogenation conversion method

A technology for catalytic diesel and hydrogenation conversion, which is applied in hydrotreating process, hydrocarbon oil treatment, petroleum industry, etc. It can solve the problems of poor selectivity of single-ring aromatics, achieve high selectivity of single-ring aromatics, improve hydrogen utilization efficiency, Effect of reducing hydrogen consumption

Active Publication Date: 2021-07-09
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

On the basis of systematically grasping the influence of operating conditions such as reaction pressure and reaction temperature on aromatics saturation, two different hydrofining reaction zones are set up to solve the problem of single-ring aromatics selection in the conventional hydrofining process of high-aromatic diesel feedstock sex problem

Method used

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  • A kind of catalytic diesel oil hydrogenation conversion method
  • A kind of catalytic diesel oil hydrogenation conversion method
  • A kind of catalytic diesel oil hydrogenation conversion method

Examples

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Embodiment 1~3

[0037] Embodiment 1~3 all adopts flow process of the present invention, figure 1 The combined process flow shown. After being heated by the heating furnace, the high-aromatic catalytic diesel oil is mixed with circulating hydrogen and enters the I hydrorefining reaction zone for hydrodesulfurization, polycyclic aromatic hydrocarbons selective hydrogenation saturation and other reactions; the obtained oil is mixed with circulating hydrogen and enters II hydrorefining reaction zone The reaction zone carries out further hydrodesulfurization reaction and aromatics selective reaction; the obtained oil is mixed with circulating hydrogen and enters the hydrocracking reaction area for hydrocarbon hydroconversion reaction; the obtained oil is separated and fractionated to obtain gas, pumice Naphtha, heavy naphtha, diesel fractions. Part of the diesel is recycled back to the II hydrorefining reaction zone, and part of the diesel is sent out of the unit. The gas is recycled through the...

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Abstract

The invention discloses a method for catalytic diesel hydrogenation conversion, which comprises the following steps: (1) high-aromatic catalytic diesel oil is mixed with circulating hydrogen and entered into I hydrorefining reaction zone for reaction; (2) the produced oil obtained in step (1) is mixed with Circulating hydrogen is mixed into II hydrofining reaction zone for further reaction, the reaction temperature is 30~120℃ higher than I hydrofining reaction zone, and the liquid hourly volume space velocity is 0.2~1.5h lower than I hydrofining reaction zone ‑1 ; (3) The generated oil obtained in step (2) is mixed with circulating hydrogen into the hydrocracking reaction zone for hydrocarbon hydroconversion reaction; (4) The generated oil obtained in step (3) is passed through a separation and fractionation system to obtain gas, light Naphtha, heavy naphtha, diesel fraction, part of the diesel is recycled back to the II hydrotreating reaction zone, and part of the diesel is sent out of the unit. The catalytic diesel hydrogenation conversion method provided by the method can effectively increase the production of aromatics.

Description

technical field [0001] The invention relates to the field of petroleum refining. Specifically, it relates to a method for processing catalytic diesel to produce high-quality gasoline and high-quality diesel. Background technique [0002] Catalytic cracking is currently the most important secondary processing process in the petroleum refining industry, and it is also the core process of lightening heavy oil. As the world's oil becomes increasingly heavy, the processing capacity of the FCC unit is also continuously improved. Using various heavy oils as raw materials, high-octane gasoline, the main product, is obtained through catalytic cracking reactions, and a large amount of sulfur, nitrogen, and aromatics are produced at the same time. Catalytic diesel oil with high content, low cetane number or cetane index, and extremely poor stability. Moreover, the requirements of environmental protection regulations are becoming more and more stringent, and the indicators of diesel p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G67/02
Inventor 彭冲杜艳泽曾榕辉吴子明王仲义崔哲隋宝宽
Owner CHINA PETROLEUM & CHEM CORP
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