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Industrialization system of straw-starch modified synthetic low-cost slump-retaining water reducer and preparation method thereof

A starch modification and slump-preserving technology, applied in chemical instruments and methods, chemical industry, climate sustainability, etc., can solve problems such as high cost, non-continuous production, and difficult industrialization

Inactive Publication Date: 2019-06-04
TIANSHUI NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] The purpose of the present invention is to provide an industrialized system for synthesizing low-cost slump-retaining water-reducing agents by modifying straw-starch, and solve the problems of high cost, poor performance, and non-continuous production of water-reducing agents directly prepared by using crop straws. , the problem of not being easy to industrialize

Method used

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  • Industrialization system of straw-starch modified synthetic low-cost slump-retaining water reducer and preparation method thereof
  • Industrialization system of straw-starch modified synthetic low-cost slump-retaining water reducer and preparation method thereof
  • Industrialization system of straw-starch modified synthetic low-cost slump-retaining water reducer and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0174] A method for synthesizing a low-cost slump-retaining water reducer by modifying straw-starch, the specific synthesis steps are as follows:

[0175] S1: Straw raw material pretreatment, the specific process is as follows:

[0176] The first step: primary crushing, fine crushing, cleaning, drying, and fine crushing of straw raw materials:

[0177] (1) Primary crushing of straw: After a certain amount of straw bales 2 to be processed are naturally air-dried, they are manually unpacked and discharged on an operation platform that is flush with the upper V-shaped feed port 302 of the primary straw crushing device 3 . Push the material into the upper cavity 305 of the straw primary crushing chamber (cover the feed port cover plate 301), and be clamped on the left and right sides of the upper cavity 305 by a pair of surfaces driven by a pair of idlers 314, 303. Among the concave and convex V-shaped roller conveyor belts 313 and 304, the main roller group 314 is driven to rota...

Embodiment 2

[0238] A method for synthesizing a low-cost slump-retaining water reducer by modifying straw-starch. The specific synthesis method is as follows:

[0239] S1: Raw material pretreatment of straw A, the specific process is as follows:

[0240] The first step: primary crushing, fine crushing, cleaning, drying, and fine crushing pretreatment of straw raw materials. Process is completely with embodiment 1;

[0241] The second step: straw powder hydrolysis pretreatment and starch mixed acid hydrolysis gelatinization pretreatment. The process is completely the same as in Example 1, the difference is that the hydrolysis catalytic acid C added in the hydrolysis process and its consumption are different, and the starch B added in the later stage and its addition are different, specifically reflected in:

[0242] Described starch B is cornstarch, consumption 8000g;

[0243] The lubricating additive is stearic acid, and the solid-to-solid ratio of straw to stearic acid=1000g:10ml.

[...

Embodiment 3

[0274] A method for synthesizing a slump-retaining concrete water reducer through modification of straw-starch, the specific synthesis steps are as follows:

[0275] S1: Straw raw material pretreatment, the specific process is as follows:

[0276] The first step: primary crushing, fine crushing, cleaning, drying, and fine crushing pretreatment of straw raw materials. Process is completely with embodiment 1;

[0277] The second step: straw powder hydrolysis pretreatment and starch mixed acid hydrolysis gelatinization pretreatment. The process is completely the same as in Example 1, the difference is that the hydrolysis catalytic acid C added in the hydrolysis process and its consumption are different, and the starch B added in the later stage and its addition are different, specifically reflected in:

[0278] Described starch B is potato starch, consumption 15000g;

[0279] The lubricating additive is a mixture of stearic acid and oleic acid each accounting for 50%, and the ...

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Abstract

The invention relates to the technical field of preparation of water reducers for concrete and discloses an industrialization system of a straw-starch modified synthetic low-cost slump-retaining waterreducer and a preparation method thereof. The straw-starch modified slump-retaining water reducer for concrete is synthesized by the following steps: crushing and hydrolysis pretreatment of crop straw materials, oxidation-sulfonation and esterification-hydroxymethylation-etherification-quaternized modification by mixing with common starch, and graft copolymerization modification by using an unsaturated polyether macromonomer, an unsaturated small monomer and a slump-retaining functional monomer. The product has good slump-retaining property and high water-reducing rate. The system of the invention is energy-saving, efficient and easy for industrialization. According to the invention, the industrialization process of the low-cost biomass-based slump-retaining water reducer is further promoted, and the application field is broadened for the combination of recycling of crop straw and common starch.

Description

technical field [0001] The invention relates to the technical field of preparation of concrete water reducers, in particular to an industrialized system and preparation method for synthesizing low-cost slump-retaining water reducers by modifying straw-starch. Background technique [0002] At present, with the increasing shortage of petrochemical raw materials required for the preparation of a new generation of high-performance petroleum-based polycarboxylate water reducers for concrete admixtures, the outstanding problem of rising prices has restricted the new generation of high-performance polycarboxylate water reducers. The rapid development of additives has led to rising production costs, making polycarboxylate superplasticizers that have higher performance advantages than naphthalene-based, aliphatic-based, sulfamate-based, and lignin-based water-reducing agents unable to be used in the market. The vigorous promotion and application of the construction industry. Scholar...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/06C08F251/00C08F289/00C08F220/06C08F222/02C08F228/02C04B24/16B01J19/18B01J19/20B01J4/00B01J4/02C04B103/30
CPCY02P20/10
Inventor 章德玉张惠琴刘流李志锋司长代张建斌王鹏刘岿唐慧安王小芳刘新文雷新有吕玲玲朱元成郭峰左国防赵爱英
Owner TIANSHUI NORMAL UNIV