Lost circulation drilling fluid system and preparation method based on hydrophobic bridging particles
A hydrophobic and granular technology, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of borehole wall expansion and collapse, affecting the effect of plugging, etc., to restore productive reservoirs, improve plugging tightness, Easy to unblock effect
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Embodiment 1
[0032] The embodiment of the present invention provides a plugging drilling fluid system based on hydrophobic bridging particles, which is composed of sodium bentonite, caustic soda, soda ash, thickener, filtrate reducer, hydrophobic heavy calcium carbonate, asphalt, limestone powder, The unidirectional pressure shielding agent and the weighting agent used to adjust the density of the system are mixed with water.
[0033] Among them, the content of the treatment agent: 3.0%-5.0%wt sodium bentonite, 0.2%-0.4wt% caustic soda, 0.1%-0.4%wt soda ash, 0.2%-0.5%wt tackifier, 3.0%-5.0%wt reduction Fluid loss agent, 20.0%~30.0%wt hydrophobic heavy calcium carbonate, 1.0%~3.0%wt asphalt, 2.0%~4.0%wt limestone powder, 1.0%~3.0% unidirectional pressure shielding agent, used to adjust the system density The weighting agent; the balance is water, and the basis of the mass content of each component is the volume of water.
[0034] In the embodiment of the present invention, the indicators of eac...
Embodiment 2
[0040] The hydrophobic heavy calcium carbonate provided by the embodiment of the present invention is obtained by modifying the hydrophilic heavy calcium carbonate with a modifier, wherein the modifier is bis(4-alkoxy-3-benzenesulfonate triethanolamine ) Methane.
[0041] Wherein, the molecular structure of the modifier is:
[0042]
[0043] Wherein, the preparation method of the modifier is:
[0044] Step 1): Add dichloromethane and bisphenol F into the reaction vessel, then add potassium hydroxide and cetyltrimethylammonium bromide while stirring. After heating, add bromooctadecane and stir while stirring. Heat until the reaction is complete, and after the system is cooled, the reaction product is hot filtered to remove salt and purify to obtain the bisether intermediate;
[0045] Step 2): Add dichloromethane to the flask equipped with HCl absorption device, add the bisether intermediate prepared in step 1) while stirring, slowly add chlorine dropwise with a constant pressure dropp...
Embodiment 3
[0051] The embodiment of the present invention provides a preparation method of hydrophobic heavy calcium carbonate, the method is:
[0052] After mixing the hydrophilic heavy calcium carbonate powder and the modifier, they are slowly added to a continuous powder modifier, and modified at a temperature of 100°C to 130°C for 15-25 minutes to obtain hydrophobic heavy calcium carbonate.
[0053] Wherein, the amount of the modifier is 3% of the mass of the hydrophilic heavy calcium carbonate powder. Among them, the continuous powder modifier is an SLG type continuous powder modifier.
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