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3D printing one-time molding water-based zinc-ion battery and its realization method

A zinc-ion battery, 3D printing technology, applied in secondary batteries, battery electrodes, battery pack components and other directions, can solve the problems of high process cost, complex procedures, strict environmental requirements, etc., to achieve simple process, wide application prospects, low cost effect

Inactive Publication Date: 2021-06-18
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the above-mentioned deficiencies in the prior art, the present invention proposes a 3D printing once-formed water-based zinc-ion battery and its realization method, which has simple process, low cost and strong practicability, and can solve the problem of strict environmental requirements and process costs in the traditional battery assembly process Disadvantages such as height and complicated procedures

Method used

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  • 3D printing one-time molding water-based zinc-ion battery and its realization method
  • 3D printing one-time molding water-based zinc-ion battery and its realization method
  • 3D printing one-time molding water-based zinc-ion battery and its realization method

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Embodiment 1

[0022] Such as image 3 As shown, this embodiment includes the following steps:

[0023] Step 1. Weigh 400 mg manganese dioxide, 80 mg nanocellulose, 20 mg graphene oxide, 200 mg acetylene black, 2.3 g zinc sulfate heptahydrate, 67.61 mg manganese sulfate monohydrate and mix with 4 mL deionized water to obtain a positive electrode Material;

[0024] Step 2. Weigh 600 mg zinc powder, 80 mg nanocellulose, 30 mg graphene oxide, 200 mg acetylene black, 2.3 g zinc sulfate heptahydrate, 67.61 mg manganese sulfate monohydrate and mix with 4 mL deionized water to obtain the negative electrode material ;

[0025] Step 3. Weigh 1200 mg polyvinylidene fluoride, 60 mg Pluronic, 80 mg nanocellulose, 30 mg graphene oxide, 2.3 g zinc sulfate heptahydrate, 67.61 mg manganese sulfate monohydrate and mix with 4 mL deionized water to obtain electrolyte Material;

[0026] Step 4. Weigh 1.5 g of nano-alumina and mix with 4 mL of photosensitive resin to obtain the battery case material.

[002...

Embodiment 2

[0031] Such as image 3 As shown, this embodiment includes the following steps:

[0032] Step 1. Weigh 400 mg of vanum pentoxide, 80 mg of nanocellulose, 20 mg of graphene oxide, 200 mg of acetylene black, 2.3 g of zinc sulfate heptahydrate, 67.61 mg of manganese sulfate monohydrate and mix them with 4 mL of deionized water to obtain Cathode material;

[0033] Step 2. Weigh 600 mg zinc powder, 80 mg nanocellulose, 30 mg graphene oxide, 200 mg acetylene black, 2.3 g zinc sulfate heptahydrate, 67.61 mg manganese sulfate monohydrate and mix with 4 mL deionized water to obtain the negative electrode material ;

[0034] Step 3. Weigh 1200 mg polyvinylidene fluoride, 60 mg Pluronic, 80 mg nanocellulose, 30 mg graphene oxide, 2.3 g zinc sulfate heptahydrate, 67.61 mg manganese sulfate monohydrate and mix with 4 mL deionized water to obtain electrolyte Material;

[0035] Step 4. Weigh 1.5 g of nano-alumina and mix with 4 mL of photosensitive resin to obtain the battery case materi...

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Abstract

A 3D printing one-time molding water-based zinc-ion battery and its realization method, respectively use hydrogel as the matrix material of the electrode and electrolyte, and use photosensitive resin as the matrix material of the battery shell, and print out a battery with electrochemical properties by extrusion through a 3D printer. high-performance aqueous zinc-ion batteries. The invention has simple process, low cost and strong practicability, and can solve the disadvantages of strict environmental requirements, high process cost and complicated procedures in the traditional battery assembly process. It has broad application prospects.

Description

technical field [0001] The invention relates to a technology in the field of zinc-lithium ion batteries, in particular to a 3D printing one-time molding water-based zinc-ion battery and its realization method. Background technique [0002] Traditional lithium-ion batteries need to be prepared through procedures such as cutting, coating, drying, liquid injection, and packaging. The process is complicated, the cycle is long, and the cost is high. Lithium-ion batteries currently on the market can be divided into cylindrical, button-type, and square according to their shapes. Lithium-ion batteries of different shapes require different molds and machines, resulting in a lot of waste of resources and space. Moreover, because the organic electrolyte used is volatile, flammable, and reacts with water and oxygen, traditional lithium-ion batteries must strictly control the content of oxygen and water in the environment during assembly, and there are still safety issues after assembly....

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/62H01M50/121H01M10/36H01M10/38
CPCY02E60/10Y02P70/50
Inventor 吴海霞王磊郭守武刘米香
Owner SHANGHAI JIAO TONG UNIV
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